A stable conductive myocardial patch with a negative Poisson's ratio structure is provided. The preparation method includes preparing a myocardial patch substrate with concave polygons as the structural units by weaving or knitting, and then a conductive coating is coated on the surface of the substrate. Alternatively, the yarns can be processed into conductive coated yarns first, and then used as the raw material to weave or knit a stable conductive myocardial patch with a negative Poisson's ratio structure. The prepared myocardial patch has a relative resistance change of less than 5% at 50% tensile strain. When the strain of the structural units is within 50%, the fabric exhibits a negative Poisson's ratio structure, which expands in the perpendicular direction of the tensile load. The fabric exhibits a negative Poisson's ratio effect and anisotropy of Young's modulus, which matches the mechanical behavior of natural myocardium.

A stable conductive myocardial patch with a negative Poisson's ratio structure is provided. The preparation method includes preparing a myocardial patch substrate with concave polygons as the structural units by weaving or knitting, and then a conductive coating is coated on the surface of the substrate. Alternatively, the yarns can be processed into conductive coated yarns first, and then used as the raw material to weave or knit a stable conductive myocardial patch with a negative Poisson's ratio structure. The prepared myocardial patch has a relative resistance change of less than 5% at 50% tensile strain. When the strain of the structural units is within 50%, the fabric exhibits a negative Poisson's ratio structure, which expands in the perpendicular direction of the tensile load. The fabric exhibits a negative Poisson's ratio effect and anisotropy of Young's modulus, which matches the mechanical behavior of natural myocardium.

The present invention relates to photocurable compositions, comprising (A1) a N-vinyloxazolidinone of formula (I), wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently of each other a hydrogen atom or an organic group having not more than 10 carbon atoms, (A2) optionally one, or more second reactive diluents, (B) one, or more oligomers, and (C) a photoinitiator (C), wherein the amount of component (A1) is 5 to 70% by weight based on the amount of components (A1), (A2) and (B), wherein the viscosity of said photocurable composition is in the range 10 to 3000 mPa.Math.s, preferably 10 to 1500 mPa.Math.s at 30° C. The compositions, from which cured three-dimensional shaped articles having balanced mechanical properties combining stiffness with high toughness can be made, are particularly suitable for the production of three-dimensional articles by stereolithography and photopolymer jetting.

##STR00001##

The present invention relates to photocurable compositions, comprising (A1) a N-vinyloxazolidinone of formula (I), wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently of each other a hydrogen atom or an organic group having not more than 10 carbon atoms, (A2) optionally one, or more second reactive diluents, (B) one, or more oligomers, and (C) a photoinitiator (C), wherein the amount of component (A1) is 5 to 70% by weight based on the amount of components (A1), (A2) and (B), wherein the viscosity of said photocurable composition is in the range 10 to 3000 mPa.Math.s, preferably 10 to 1500 mPa.Math.s at 30° C. The compositions, from which cured three-dimensional shaped articles having balanced mechanical properties combining stiffness with high toughness can be made, are particularly suitable for the production of three-dimensional articles by stereolithography and photopolymer jetting.

##STR00001##

A surface treatment liquid capable of forming a hydrophilic resinous coating film adhering well to a surface of an object to be surface-treated and providing a surface treatment effect that does not decrease over time, even when the surface-treated article is exposed to a variety of agents, and a surface treatment method using the surface treatment liquid is provided.

A surface treatment liquid including a polymerizable compound (A), a thermal polymerization initiator (B), and a solvent (S), in which the polymerizable compound (A) includes a betaine monomer (a1) having a group including an ethylenic unsaturated double bond, an anionic group, and a cationic group, an unsaturated group-containing silicon compound (a2) having a group including an ethylenic unsaturated double bond, and a hydrolyzable silyl group, and/or a polar polymerizable compound (a3) having an ethylenic unsaturated double bond, and a polar group selected from amino group, carboxylic group, mercapto group, hydroxy group, and cyano group is used.

A surface treatment liquid capable of forming a hydrophilic resinous coating film adhering well to a surface of an object to be surface-treated and providing a surface treatment effect that does not decrease over time, even when the surface-treated article is exposed to a variety of agents, and a surface treatment method using the surface treatment liquid is provided.

A surface treatment liquid including a polymerizable compound (A), a thermal polymerization initiator (B), and a solvent (S), in which the polymerizable compound (A) includes a betaine monomer (a1) having a group including an ethylenic unsaturated double bond, an anionic group, and a cationic group, an unsaturated group-containing silicon compound (a2) having a group including an ethylenic unsaturated double bond, and a hydrolyzable silyl group, and/or a polar polymerizable compound (a3) having an ethylenic unsaturated double bond, and a polar group selected from amino group, carboxylic group, mercapto group, hydroxy group, and cyano group is used.

Cationic cyclic amine containing polymers and copolymers as well as novel lipids have been designed and synthesized for efficient delivery of nucleic acids to cells in biological systems, specifically for in vitro cell transfection research.

Provided is an agent for dispersing an electrically conductive carbon material, in which the agent consists of a polymer which has an oxazoline group in a side chain and which is obtained by using an oxazoline group-containing monomer such as that represented by formula (1) for example, and in which the agent exhibits excellent dispersion of an electrically conductive carbon material and produces a thin film that exhibits excellent adhesion to a current collection substrate when formed into a thin film together with the electrically conductive carbon material. ##STR00001## (In the formula, X denotes a polymerizable carbon-carbon double bond-containing group, and R.sup.1-R.sup.4 each independently denote a hydrogen atom, a halogen atom, an alkyl group optionally having a branched structure having 1-5 carbon atoms, an aryl group having 6-20 carbon atoms, or an aralkyl group having 7-20 carbon atoms.)

Provided is an agent for dispersing an electrically conductive carbon material, in which the agent consists of a polymer which has an oxazoline group in a side chain and which is obtained by using an oxazoline group-containing monomer such as that represented by formula (1) for example, and in which the agent exhibits excellent dispersion of an electrically conductive carbon material and produces a thin film that exhibits excellent adhesion to a current collection substrate when formed into a thin film together with the electrically conductive carbon material. ##STR00001## (In the formula, X denotes a polymerizable carbon-carbon double bond-containing group, and R.sup.1-R.sup.4 each independently denote a hydrogen atom, a halogen atom, an alkyl group optionally having a branched structure having 1-5 carbon atoms, an aryl group having 6-20 carbon atoms, or an aralkyl group having 7-20 carbon atoms.)

The present invention provides a material for forming an organic film, containing a compound shown by the following general formula (1), and an organic solvent, where X represents an organic group having a valency of n1 and 2 to 50 carbon atoms, n1 represents an integer of 1 to 10, and R.sub.1 represents at least one or more of the following general formulae (2) to (4). This aims to provide an organic film material for forming an organic film that has all of high filling property, high planarizing property, and excellent adhesive force to a substrate. ##STR00001##