Treated aldehyde-based resins containing one or more polyamines and methods for making and same. The treated aldehyde-based resin can be or include an aldehyde-based resin and a polyamine. The polyamine can be or include one or more aromatic polyamines, one or more poly(C.sub.2-C.sub.5 alkylene) polyamines, or a mixture thereof. The treated aldehyde-based resin can include about 0.05 wt % to about 10 wt % of the polyamine, based on a solids weight of the aldehyde-based resin.

A resist underlayer film-forming composition comprising a novolac resin obtained by reacting an aromatic compound (A) with an aldehyde (B) having formyl group bonded to a secondary carbon atom or tertiary carbon atom of a C.sub.2-26 alkyl group. A resist underlayer film-forming composition according to the first aspect, in which the novolac resin comprises a unit structure of Formula (1):

##STR00001##

(in Formula (1), A is a bivalence group derived from a C.sub.6-40 aromatic compound; b.sup.1 is a C.sub.1-16 alkyl group; and b.sup.2 is a hydrogen atom or a C.sub.1-9 alkyl group). A is the bivalent group derived from an aromatic compound comprising an amino group, a hydroxy group, or both an amino group and a hydroxy group.

The present invention generally relates to curable compositions that include a benzoxazine resin and a polyamide resin, wherein the polyamide resin is a reaction product of (i) a dicarboxylic acid, wherein the dicarboxylic acid includes a non-aromatic, dicarboxylic dimer acid and the mole fraction of the non-aromatic, dicarboxylic dimer acid is between from 0.10 to 1.00, based on the total moles of dicarboxylic acid used to form the polyamide resin; and (ii) a diamine; and wherein the polyamide resin is amine terminated and includes amine end-groups. The curable compositions may be used to produce an article comprising a cured composition wherein the cured composition is the reaction product of the curable composition according to any one of the curable compositions of the present disclosure. The present invention also relates to methods of coating substrates using the curable compositions of the present disclosure.

The present invention generally relates to curable compositions that include a benzoxazine resin and a polyamide resin, wherein the polyamide resin is a reaction product of (i) a dicarboxylic acid, wherein the dicarboxylic acid includes a non-aromatic, dicarboxylic dimer acid and the mole fraction of the non-aromatic, dicarboxylic dimer acid is between from 0.10 to 1.00, based on the total moles of dicarboxylic acid used to form the polyamide resin; and (ii) a diamine; and wherein the polyamide resin is amine terminated and includes amine end-groups. The curable compositions may be used to produce an article comprising a cured composition wherein the cured composition is the reaction product of the curable composition according to any one of the curable compositions of the present disclosure. The present invention also relates to methods of coating substrates using the curable compositions of the present disclosure.

The present disclosure provides an organic sulfur acid-free composition containing a benzoxazine, phenolic compound and nitrogen-containing heterocyclic compound. The organic sulfur acid-free composition, upon curing at temperatures as low as 130-140 C., renders void free cured articles having well balanced thermal, chemical and mechanical properties. The organic sulfur acid-free composition may be used in a variety of applications, such as in coatings, structural and non-structural composites and encapsulating systems for electronic and electrical components.

The present disclosure provides an organic sulfur acid-free composition containing a benzoxazine, phenolic compound and nitrogen-containing heterocyclic compound. The organic sulfur acid-free composition, upon curing at temperatures as low as 130-140 C., renders void free cured articles having well balanced thermal, chemical and mechanical properties. The organic sulfur acid-free composition may be used in a variety of applications, such as in coatings, structural and non-structural composites and encapsulating systems for electronic and electrical components.

The present disclosure provides an organic sulfur acid-free composition containing a benzoxazine, phenolic compound and nitrogen-containing heterocyclic compound. The organic sulfur acid-free composition, upon curing at temperatures as low as 130-140 C., renders void free cured articles having well balanced thermal, chemical and mechanical properties. The organic sulfur acid-free composition may be used in a variety of applications, such as in coatings, structural and non-structural composites and encapsulating systems for electronic and electrical components.

Microcapsules are disclosed that have a core composition encapsulated within a polymer wall, and an inorganic shell connected to an exterior surface of the polymer wall by a surfactant. The inorganic shell has a cation attracted to the surfactant and an anion or anion equivalent chemically bonded to the cation to form the shell or has the metal portion of a metal-containing compound attracted to the surfactant to form the shell. The shell may comprise a Ca, Mg, or Ag metal compound. The shell may be a graphene oxide-metal compound.

A method for the manufacture of mineral wool products is disclosed. In one example, the method comprises reacting an aqueous phenol-formaldehyde resole with free formaldehyde with a first amount of urea, thereby preparing a prereact. The prereact is contacted with a second amount of urea. The resulting mixture of prereact and second amount of urea, as part of a binder, optionally with additives is applied to the surface of mineral fibers. The binder is cured on the surface of the mineral fibers. A mineral wool product with reduced emissions of formaldehyde is also disclosed.

A method for the manufacture of mineral wool products is disclosed. In one example, the method comprises reacting an aqueous phenol-formaldehyde resole with free formaldehyde with a first amount of urea, thereby preparing a prereact. The prereact is contacted with a second amount of urea. The resulting mixture of prereact and second amount of urea, as part of a binder, optionally with additives is applied to the surface of mineral fibers. The binder is cured on the surface of the mineral fibers. A mineral wool product with reduced emissions of formaldehyde is also disclosed.