A semicrystalline polyarylethersulfone (PAES) useful for additive manufacturing may be made by a method comprising: dissolving an amorphous polyarylethersulfone in a polar aprotic halogenated hydrocarbon solvent at a temperature adequate to effectively form a solution, and subsequently and spontaneously bring about reprecipitation of a semicrystalline polyarylethersulfone from the solution. The semicrystalline polyarylethersulfone may have a crystallinity of at least 30% by weight. The semicrystalline PAES, upon being heated, melting and uniting together in layers during additive manufacturing cools without substantially recrystallizing, allows for deformation-free articles to be formed having low residual stress.

Disclosed is a non-stick coating for an article, particularly for a baking pan or other household and utility item, comprises at least a base layer (G) burnt onto a surface (O) of the article and a covering layer (D) burnt above the base layer. The base layer and the covering layer each have a dry film thickness of 1 to 25 μm, wherein the base layer contains 10 to 100 wt.-%, related to the weight of the burnt base layer, of a thermoplastic resin having a temperature resistance exceeding 200° C., and wherein the covering layer contains a thermoplastic resin having a temperature resistance exceeding 200° C. and optionally a silicone resin. Both the base layer and also the covering layer are free of perfluorinated and polyfluorinated alkyl compounds. Due to the fact that the covering layer comprises a content of thermoplastic resin of at least 30 wt.-%, related to the weight of the burnt covering layer, and of at least 2.5 wt.-%, related to the weight of the burnt covering layer, of a silicone oil, novel fluorine-free non-stick coatings with good substrate adhesion and very good deep-drawing properties are obtained. In a process for applying the non-stick coating, the base layer to be formed is applied as a liquid varnish onto the surface of the article and subsequently dried at 250 to 440° C., subsequently the covering layer is applied as liquid varnish onto the predried base layer, and finally the layers are bonded to each other and to the surface of the article by means of heat treatment at 250 to 440° C.

Disclosed is a non-stick coating for an article, particularly for a baking pan or other household and utility item, comprises at least a base layer (G) burnt onto a surface (O) of the article and a covering layer (D) burnt above the base layer. The base layer and the covering layer each have a dry film thickness of 1 to 25 μm, wherein the base layer contains 10 to 100 wt.-%, related to the weight of the burnt base layer, of a thermoplastic resin having a temperature resistance exceeding 200° C., and wherein the covering layer contains a thermoplastic resin having a temperature resistance exceeding 200° C. and optionally a silicone resin. Both the base layer and also the covering layer are free of perfluorinated and polyfluorinated alkyl compounds. Due to the fact that the covering layer comprises a content of thermoplastic resin of at least 30 wt.-%, related to the weight of the burnt covering layer, and of at least 2.5 wt.-%, related to the weight of the burnt covering layer, of a silicone oil, novel fluorine-free non-stick coatings with good substrate adhesion and very good deep-drawing properties are obtained. In a process for applying the non-stick coating, the base layer to be formed is applied as a liquid varnish onto the surface of the article and subsequently dried at 250 to 440° C., subsequently the covering layer is applied as liquid varnish onto the predried base layer, and finally the layers are bonded to each other and to the surface of the article by means of heat treatment at 250 to 440° C.

A resin film having an aromatic polysulfone as a forming material is provided. The resin film has a thickness of less than 100 μm, and further contains an organic compound having a boiling point no lower than 250° C. and no higher than 400° C. The organic compound is contained in an amount of at least 500 ppm and at most 4000 ppm relative to the mass of the aromatic polysulfone.

A resin film having an aromatic polysulfone as a forming material is provided. The resin film has a thickness of less than 100 μm, and further contains an organic compound having a boiling point no lower than 250° C. and no higher than 400° C. The organic compound is contained in an amount of at least 500 ppm and at most 4000 ppm relative to the mass of the aromatic polysulfone.

A resin film having an aromatic polysulfone as a forming material is provided. The resin film has a thickness of less than 100 μm, and further contains an organic compound having a boiling point no lower than 250° C. and no higher than 400° C. The organic compound is contained in an amount of at least 500 ppm and at most 4000 ppm relative to the mass of the aromatic polysulfone.

Provided is an aqueous amine-free coating composition including at least one aromatic polymer, wherein the aromatic polymer is in the form of powder having a d.sub.90 less than or equal to 20 μm and in that the aqueous coating composition further includes polar aprotic solvent at a content greater than 0% by weight and less than or equal to 25% by weight. Also provided is an aqueous amine-free non-stick coating composition including such an aqueous composition for a coating, and the respective methods for producing same. Further provided is a method for producing an item on one of the faces of a metal substrate, from at least one layer of the coating composition or one layer of the non-stick coating composition.

Provided is an aqueous amine-free coating composition including at least one aromatic polymer, wherein the aromatic polymer is in the form of powder having a d.sub.90 less than or equal to 20 μm and in that the aqueous coating composition further includes polar aprotic solvent at a content greater than 0% by weight and less than or equal to 25% by weight. Also provided is an aqueous amine-free non-stick coating composition including such an aqueous composition for a coating, and the respective methods for producing same. Further provided is a method for producing an item on one of the faces of a metal substrate, from at least one layer of the coating composition or one layer of the non-stick coating composition.

Antibacterial coatings and methods of making the antibacterial coatings are described herein. In particular, a method for forming an organocatalyzed polythioether coating is provided in which a first solution including a bis-silylated dithiol and a fluoroarene is prepared. A second solution including an organocatalyst is prepared. The first solution and the second solution are mixed to form a mixed solution. The mixed solution is applied to a substrate, and the substrate is cured.

Antibacterial coatings and methods of making the antibacterial coatings are described herein. In particular, a method for forming an organocatalyzed polythioether coating is provided in which a first solution including a bis-silylated dithiol and a fluoroarene is prepared. A second solution including an organocatalyst is prepared. The first solution and the second solution are mixed to form a mixed solution. The mixed solution is applied to a substrate, and the substrate is cured.