Provided are a copolymer of diallylamines and sulfur dioxide having a high molecular weight and a low content amount of impurities such as halogens, and a production method with which it is possible to produce such a copolymer relatively simply and at low cost. This problem is solved by: a copolymer having a weight-average molecular weight of 150,000 or higher obtained by GPC measurement and a degree of polymerization of 1000 or higher, the copolymer being obtained by copolymerizing sulfur dioxide and a sulfonate or alkyl sulfate salt of diallylamines having a specific structure; and a method for producing a copolymer, the method having a step for copolymerizing sulfur dioxide and a sulfonate or alkyl sulfate salt of diallylamines having a specific structure in ethylene glycol or in propylene glycol monomethyl ether.

Provided are a copolymer of diallylamines and sulfur dioxide having a high molecular weight and a low content amount of impurities such as halogens, and a production method with which it is possible to produce such a copolymer relatively simply and at low cost. This problem is solved by: a copolymer having a weight-average molecular weight of 150,000 or higher obtained by GPC measurement and a degree of polymerization of 1000 or higher, the copolymer being obtained by copolymerizing sulfur dioxide and a sulfonate or alkyl sulfate salt of diallylamines having a specific structure; and a method for producing a copolymer, the method having a step for copolymerizing sulfur dioxide and a sulfonate or alkyl sulfate salt of diallylamines having a specific structure in ethylene glycol or in propylene glycol monomethyl ether.

A coating for a medical device or appliance may include a fluoropolymer and a polyimide. Such coatings may provide a lubricious exterior surface that facilitates insertion or displacement of a medical device in a body lumen. Some coatings that include a fluoropolymer and a polyimide may, among other functions and characteristics, provide increased strength and/or durability relative to some other coatings.

A coating for a medical device or appliance may include a fluoropolymer and a polyimide. Such coatings may provide a lubricious exterior surface that facilitates insertion or displacement of a medical device in a body lumen. Some coatings that include a fluoropolymer and a polyimide may, among other functions and characteristics, provide increased strength and/or durability relative to some other coatings.

Disclosed is a non-stick coating for an article, particularly for a baking pan or other household and utility item, comprises at least a base layer (G) burnt onto a surface (O) of the article and a covering layer (D) burnt above the base layer. The base layer and the covering layer each have a dry film thickness of 1 to 25 ?m, wherein the base layer contains 10 to 100 wt.-%, related to the weight of the burnt base layer, of a thermoplastic resin having a temperature resistance exceeding 200? C., and wherein the covering layer contains a thermoplastic resin having a temperature resistance exceeding 200? C. and optionally a silicone resin. Both the base layer and also the covering layer are free of perfluorinated and polyfluorinated alkyl compounds. Due to the fact that the covering layer comprises a content of thermoplastic resin of at least 30 wt.-%, related to the weight of the burnt covering layer, and of at least 2.5 wt.-%, related to the weight of the burnt covering layer, of a silicone oil, novel fluorine-free non-stick coatings with good substrate adhesion and very good deep-drawing properties are obtained. In a process for applying the non-stick coating, the base layer to be formed is applied as a liquid varnish onto the surface of the article and subsequently dried at 250 to 440? C., subsequently the covering layer is applied as liquid varnish onto the predried base layer, and finally the layers are bonded to each other and to the surface of the article by means of heat treatment at 250 to 440? C.

Disclosed is a non-stick coating for an article, particularly for a baking pan or other household and utility item, comprises at least a base layer (G) burnt onto a surface (O) of the article and a covering layer (D) burnt above the base layer. The base layer and the covering layer each have a dry film thickness of 1 to 25 ?m, wherein the base layer contains 10 to 100 wt.-%, related to the weight of the burnt base layer, of a thermoplastic resin having a temperature resistance exceeding 200? C., and wherein the covering layer contains a thermoplastic resin having a temperature resistance exceeding 200? C. and optionally a silicone resin. Both the base layer and also the covering layer are free of perfluorinated and polyfluorinated alkyl compounds. Due to the fact that the covering layer comprises a content of thermoplastic resin of at least 30 wt.-%, related to the weight of the burnt covering layer, and of at least 2.5 wt.-%, related to the weight of the burnt covering layer, of a silicone oil, novel fluorine-free non-stick coatings with good substrate adhesion and very good deep-drawing properties are obtained. In a process for applying the non-stick coating, the base layer to be formed is applied as a liquid varnish onto the surface of the article and subsequently dried at 250 to 440? C., subsequently the covering layer is applied as liquid varnish onto the predried base layer, and finally the layers are bonded to each other and to the surface of the article by means of heat treatment at 250 to 440? C.

A coating material composition containing polytetrafluoroethylene, a binder resin, and a filler being at least one kind selected from calcium fluoride, iron oxide and talc, wherein the content of N-methyl-2-pyrrolidone is less than 1% by weight of the composition. Also disclosed is a coating film formed of the coating material composition.

A coating material composition containing polytetrafluoroethylene, a binder resin, and a filler being at least one kind selected from calcium fluoride, iron oxide and talc, wherein the content of N-methyl-2-pyrrolidone is less than 1% by weight of the composition. Also disclosed is a coating film formed of the coating material composition.

Provided is an aqueous amine-free coating composition including at least one heterocyclic polymer, wherein the heterocyclic polymer is in the form of powder having a d.sub.90 less than or equal to 20 m. Also provided is an aqueous amine-free non-stick coating composition including such an aqueous composition for a coating, and the respective methods for producing same. Further provided is a method for producing an item on one of the faces of a metal substrate, from at least one layer of coating composition or one layer of non-stick coating composition according to the invention.

Provided is an aqueous amine-free coating composition including at least one heterocyclic polymer, wherein the heterocyclic polymer is in the form of powder having a d.sub.90 less than or equal to 20 m. Also provided is an aqueous amine-free non-stick coating composition including such an aqueous composition for a coating, and the respective methods for producing same. Further provided is a method for producing an item on one of the faces of a metal substrate, from at least one layer of coating composition or one layer of non-stick coating composition according to the invention.