Siloxane-based gel adhesives with improved shear holding power are prepared from curable compositions. The curable compositions include a siloxane fluid with a viscosity of at least 1,000,000 centiPoise, a siloxane-(meth)acrylate co-polymer, and siloxane tackifying resin. The curable compositions can contain an initiator or can be cured by e-beam radiation without an initiator. The siloxane-(meth)acrylate copolymer is the reaction product of a reaction mixture of an ethylenically unsaturated siloxane-containing macromer, an alkyl (meth)acrylate monomer; optionally a reinforcing monomer, and an initiator.

Siloxane-based gel adhesives with improved shear holding power are prepared from curable compositions. The curable compositions include a siloxane fluid with a viscosity of at least 1,000,000 centiPoise, a siloxane-(meth)acrylate co-polymer, and siloxane tackifying resin. The curable compositions can contain an initiator or can be cured by e-beam radiation without an initiator. The siloxane-(meth)acrylate copolymer is the reaction product of a reaction mixture of an ethylenically unsaturated siloxane-containing macromer, an alkyl (meth)acrylate monomer; optionally a reinforcing monomer, and an initiator.

A silicone pressure sensitive adhesive with amphiphilic copolymers for maintaining adhesion in a moist environment. The amphiphilic copolymers for silicone adhesives include at least one silicone moiety and at least one hydrophilic segment. Such adhesives are applicable to securing medical devices to human skin.

A silicone pressure sensitive adhesive with amphiphilic copolymers for maintaining adhesion in a moist environment. The amphiphilic copolymers for silicone adhesives include at least one silicone moiety and at least one hydrophilic segment. Such adhesives are applicable to securing medical devices to human skin.

One embodiment relates to an, article and a method for producing an article including a plurality of substrates, and an adhesive bonded between at least two of the plurality of substrates. The adhesive can include a polycarbonate copolymer that includes reacted resorcinol, siloxane, and bisphenol-A. Another embodiment relates to an article having a first polyimide substrate, a second polyimide substrate, and an adhesive bonded between the first substrate and the second substrate. The article can have a 2 minute integrated heat release rate of less than or equal to 65 kilowatt-minutes per square meter (kW−min/m.sup.2) and a peak heat release rate of less than 65 kilowatts per square meter (kW/m.sup.2) as measured using the method of FAR F25.4, in accordance with Federal Aviation Regulation FAR 25.853(d).

One embodiment relates to an, article and a method for producing an article including a plurality of substrates, and an adhesive bonded between at least two of the plurality of substrates. The adhesive can include a polycarbonate copolymer that includes reacted resorcinol, siloxane, and bisphenol-A. Another embodiment relates to an article having a first polyimide substrate, a second polyimide substrate, and an adhesive bonded between the first substrate and the second substrate. The article can have a 2 minute integrated heat release rate of less than or equal to 65 kilowatt-minutes per square meter (kW−min/m.sup.2) and a peak heat release rate of less than 65 kilowatts per square meter (kW/m.sup.2) as measured using the method of FAR F25.4, in accordance with Federal Aviation Regulation FAR 25.853(d).

This UV curable silicone composition contains (A) an organopolysiloxane represented by general formula (1)

##STR00001##

[R.sup.1 represents a monovalent hydrocarbon group having 1-20 carbon atoms, R.sup.2 represents an aromatic group, X represents a group represented by formula (2), a, m, and n respectively represent numbers in the ranges of 1≤a≤3, 1≤m≤2,000, 1≤n≤2,000, and m/(n+m)≥0.01 is satisfied.

##STR00002##

(R.sup.1 is as defined above. R.sup.3 represents an oxygen atom or an alkylene group having 1-20 carbon atoms, R.sup.4 represents an acryloyloxyalkyl group, a methacryloyloxyalkyl group, an acryloyloxyalkyloxy group, or a methacryloyloxyalkyloxy group, p represents a number in the range of 0≤p≤10, and c represents a number in the range of 1≤c≤3)], (B) a mono-functional (meth)acrylate compound not containing a siloxane structure, and (C) a photopolymerization initiator, and provides, as a temporary fixing material, a cured product having excellent adhesiveness and rubber strength.

Pressure sensitive adhesive compositions are described comprising at least one low Tg ethylenically unsaturated monomer, and at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups. The low Tg ethylenically unsaturated monomer typically has a Tg no greater than 10° C. In some embodiments, the composition comprises at least 50, 55, 60, 65, or 70 wt-% of low Tg ethylenically unsaturated monomer. The low Tg ethylenically unsaturated monomer is typically an alkyl (meth)acrylate comprising 4 to 20 carbon atoms. In another embodiment, an adhesive composition is described comprising a syrup. The syrup comprising i) a free-radically polymerizable solvent monomer; ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl (meth)acrylate monomers, and iii) at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups. The free-radically polymerizable solvent monomer, polymerized units of the solute (meth)acrylic polymer, or a combination thereof comprise a low Tg ethylenically unsaturated monomer. Also described are pressure sensitive adhesive articles and method of preparing adhesive articles.

A silicone-polyester copolymer has the formula X.sub.g[Z.sub.jY.sub.o].sub.c, where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polyester moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0≤j<2, and 0<o<2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-polyester copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-polyester copolymer and a condensation-reaction catalyst.

A silicone-polyester copolymer has the formula X.sub.g[Z.sub.jY.sub.o].sub.c, where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polyester moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0≤j<2, and 0<o<2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-polyester copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-polyester copolymer and a condensation-reaction catalyst.