Disclosed is an aqueous adhesive composition which comprises an admixture of: (a) a first aqueous composition comprising, (i) one or more film forming polymers, (ii) one or more lower crystallinity polynitroso compounds, (iii) one or more higher crystallinity polynitroso compounds, and (iv) one or more bismaleimide-containing monomers; and (b) a second aqueous composition comprising (i) an aqueous dispersion of at least one phenolic resin which is a condensation product of a phenol and formaldehyde, wherein the aqueous dispersion is stabilized by at least one polyacrylate; (b) one or more latices formed from one or more halogenated polyolefins; and (c) one or more metal oxides.

The invention provides an adhesive composition. The adhesive composition includes a halohydrin compound, a blocked isocyanate compound and latex, in which the adhesive composition does not include resorcinol, formaldehyde and epoxy compound. The invention also provides a method for treating organic fiber. The method includes impregnating an organic fiber or a fabric with the abovementioned adhesive composition; and drying the organic fiber or the fabric.

The present invention relates to a process for cold bonding elastomeric rubber substrates to non-elastomeric substrates of a different material, preferably metal, by use of a rubber treatment, preferably a primer composition and a 2k adhesive, preferably a 2k epoxy adhesive as well as the thus obtained bonded substrates.

Polybenzoxazine comprises repeat units which comprise at least one unit corresponding to the formulae (I) or (II):

##STR00001##

in which Z.sub.1 and Z.sub.2, which are identical or different, represent an at least divalent, aliphatic, cycloaliphatic or aromatic bonding group comprising at least one carbon atom and optionally at least one heteroatom selected from O, S, N and P. Such a polybenzoxazine may be used as a metal-adhesive layer, in particular for the adhesive bonding of a metal substrate, in particular made of carbon steel, to a rubber.

An adhesive sealant formulation for tires includes: from 20% to 35% by weight of the total formulation of block copolymers, from 55% to 75% by weight of the total formulation of resins, from 0.2% up to 2.0% by weight of the total formulation of a mixture of stabilizers and antioxidants, where the quantity of stabilizers within the mixture varies from 0 up to a maximum 1.50% by weight of the total formulation and the amount of antioxidants varies from 0 up to a maximum of 1.50% by weight of the total formulation, such as in particular: primary phenolic pentaerythritol-tetrakis(3(3,5-di-tert-butyl-4-hydroxyphenyl)propionate); from a minimum of 5% to a maximum of 35% by weight of the total formulation of paraffinic or naphthenic plasticizers; from a minimum of 2% up to a maximum of 5% by weight of the total formulation of mineral fillers.

Disclosed is an aqueous adhesive composition which comprises an admixture of: (a) a first aqueous composition comprising, (i) one or more film forming polymers, (ii) one or more lower crystallinity polynitroso compounds, (iii) one or more higher crystallinity polynitroso compounds, and (iv) one or more bismaleimide-containing monomers; and (b) a second aqueous composition comprising (i) an aqueous dispersion of at least one phenolic resin which is a condensation product of a phenol and formaldehyde, wherein the aqueous dispersion is stabilized by at least one polyacrylate; (b) one or more latices formed from one or more halogenated polyolefins; and (c) one or more metal oxides.

A hot melt adhesive film for bonding an ethylene-vinyl acetate form and a rubber includes a hot melt adhesive film layer and a release film layer. The hot melt adhesive film layer is prepared by the following raw materials in parts by weight: a 20-50 parts by weight of polyethylene-ester copolymer, a 5-15 parts by weight of rubber, a 15-55 parts by weight of thermoplastic polyolefin, a 5-20 parts by weight of tackifier and a 5-30 parts by weight of auxiliary. The release film layer is releasably adhered to the hot melt adhesive film layer.

Methods for forming a TPE-skinned composite include forming a skin layer having at least one surface and having a thermoplastic elastomer and an adhesive promoting agent; providing a foam layer; and forming the foam layer onto the said surface of the skin layer to form the TPE-skinned composite. Optional additives such as an organo-silane compound may be added to further improve the adhesion between the skin layer and the foam. The present disclosure also provides a TPE-skinned composite including a skin layer having a thermoplastic elastomer present in an amount of greater than 90 wt. %; and an adhesive promoting agent present in an amount of from 0.5 wt. % to 10 wt. % based upon the total weight of the skin layer.

An adhesive composition is comprised of a film forming polymer, (ii) a lower crystallinity polynitroso compound, (e.g., poly-(1,4-phenylyenazine-N,N-dioxide)), (iii) a higher crystallinity polynitroso compound (e.g., poly-(1,4-phenylyenazine-N,N-dioxide)), and (iv) a carrier liquid. The composition is useful in bonding metal and rubber to make, for example, components to damp noise, vibration or harshness.

The adhesive sheet for bonding an unvulcanized rubber to a metal, including a base cloth layer impregnated with a solvent dispersed type vulcanization adhesive having reactivity with the unvulcanized rubber; and an adhesive layer having reactivity with the metal.