Provided are: a heavy release additive for a release sheet, for imparting an excellent release coating whereby heavy release force is obtained curability is not reduced, low-temperature curing is possible, and there is also minimal reduction in residual adhesion rate of a released adhesive sheet; an addition-reaction-type organopolysiloxane composition; and a release sheet. A heavy release additive for a release sheet, containing an acrylic-silicone-based graft copolymer having a weight-average molecular weight of 30,000-2,000,000 obtained by radical polymerization of an organopolysiloxane compound (A) having a radical-polymerizable group, and a radical-polymerizable monomer (B) having an acrylic group and/or a methacrylic group, the heavy release additive for a release sheet wherein the component (A) includes an organopolysiloxane compound (A1) having one radical-polymerizable group in each molecule thereof, and the component (B) includes a radical-polymerizable monomer (B2) having two or more radical-polymerizable groups in each molecule thereof.

A method of making a release coated article is described comprising: providing a release coating comprising at least 50 wt. % of monomer(s) comprising an ethylenically unsaturated group and a terminal alkyl group with at least 18 (e.g. contiguous) carbon atoms based on the total amount of ethylenically unsaturated components; crosslinking components(s) comprising at least two ethylenically unsaturated groups; and at least one polymerization initiator. The release coating is substantially solventless, comprising no greater than 1 wt. % of non-polymerizable organic solvent. The method further comprises applying the release coating to a major surface of a substrate; and polymerizing the monomer(s) and crosslinking component(s) of the release coating after applying the release coating to the substrate. Also described are release coating compositions.

A method of making a release coated article is described comprising: providing a release coating composition comprising at least 50 wt. % of a mixture of ethylenically unsaturated monomers based on the total ethylenically unsaturated components; wherein the mixture comprises monomer(s) with a linear alkyl group with at least 18 carbon atoms, and monomer(s) with a branched alkyl group with 7 to 31 carbon atoms, and crosslinking component(s) comprising at least two ethylenically unsaturated groups. The method comprises applying the release coating to a major surface of a substrate and polymerizing the monomer(s) and crosslinking component(s) of the release coating. The monomer(s) with linear alkyl groups and branched alkyl groups are typically present at a weight ratio such that the release coating is a liquid at 25° C. Also described are release coating compositions and articles.

Provided is a mold release film capable of transferring a concave-convex structure to the surface of an adhesive film.

An article and a method of making thereof. The article includes a polymeric film having a first major surface and a second major surface; and a plurality of discrete domains of an inkjet printing ink comprising a low adhesion backsize coating composition deposited on the first major surface of the polymeric film; wherein the low adhesion backsize coating composition has a viscosity between 1 to 30 cp at a printing temperature between 20 to 70 degrees Celsius.

An article and a method of making thereof. The article includes a polymeric film having a first major surface and a second major surface; a first plurality of domains of a first inkjet printing ink comprising a first low adhesion backsize coating composition deposited on the first major surface of the polymeric film; and a second plurality of domains of a second inkjet printing ink comprising a second low adhesion backsize coating composition deposited on the first major surface of the polymeric film; wherein the first and second low adhesion backsize coating composition has a viscosity between 1 to 30 cp at a printing temperature between 20 to 70 degrees Celsius; and wherein at least some of the first plurality of domains overlaps some of the second plurality of domains.

A processing tape may include a base layer, an adhesive layer disposed on the base layer, a protection release film on the adhesive layer, and a first release layer interposed between the adhesive layer and the protection release film. The first release layer may include a silicone-based material and may be non-photo-curable.

Provided is a mold release film capable of transferring a concave-convex structure to the surface of an adhesive film.

An oriented heat-treated principal film capable of thermally-induced self-forming, including one or more (co)polymers and exhibiting a relaxation temperature (T.sub.r), the oriented heat-treated principal film having opposed first and second major faces, a land portion on the second major face and one or more modification zones on the second major face. A cross-linked (co)polymeric carrier layer is in contact with the first major face. Each modification zone includes a central closed portion and a rim portion surrounding the central closed portion and being surrounded by a land portion. An average thickness of each rim portion is greater than an average thickness of the land portion surrounding the central closed portion. An average thickness of each central closed portion is less than the average thickness of the land portion surrounding the central portion. Methods for making such films and adhesive articles comprising such films are also disclosed.

An article and a method of making the article. The article includes a polymeric film having a first major surface and a second major surface; and an inkjet pattern of a low adhesion backsize coating composition deposited on the first major surface of the polymeric film; wherein the low adhesion backsize coating composition has a viscosity between 1 to 30 cp at a printing temperature between 20 to 70 degrees Celsius.