Systems and methods are provided for integration of polymeric waste co-processing in cokers to produce circular chemical products from coker gas, including a method of producing circular chemical products comprising: providing a coker gas that is at least partially derived from polymeric waste, wherein the coker gas has an olefin content of about 10 wt % to about 30 wt %, a sulfur content of about 0.5 wt % to about 5 wt %, and a total halide content of about 1 wppm to about 150 wppm; and oxygen-containing compounds in an amount of about 0.5 wt % to about 15 wt %; and converting the coker gas into at least a polymer.

Systems and methods are provided for integration of polymeric waste co-processing in cokers to produce circular chemical products from coker gas, including a method of producing circular chemical products comprising: providing a coker gas that is at least partially derived from polymeric waste, wherein the coker gas has an olefin content of about 10 wt % to about 30 wt %, a sulfur content of about 0.5 wt % to about 5 wt %, and a total halide content of about 1 wppm to about 150 wppm; and oxygen-containing compounds in an amount of about 0.5 wt % to about 15 wt %; and converting the coker gas into at least a polymer.

A method of continuously recovering hydrocarbons from carbon ores can include providing first and second vessels containing rubblized carbon ore. A cooling fuel gas can be introduced into the first vessel. The cooling fuel gas can include oxygen and a recycle gas from the second vessel, which includes hydrocarbons and oxidation products. The oxygen can be consumed through oxidation in an oxidation zone in the first vessel. The temperature of the oxidation zone can be controlled by limiting the oxygen concentration in the cooling fuel gas. This can produce a hot oxidation product gas that heats rubblized carbon ore in a pyrolysis zone downstream of the oxidation zone. Gaseous and vapor hydrocarbons can be produced in the pyrolysis zone. The vapor hydrocarbons can be condensed in a condensing zone downstream of the pyrolysis zone and then collected. The remaining gaseous hydrocarbons and oxidation products can be recycled as the recycle gas. The oxidation zone and the pyrolysis zone can continuously move through the rubblized carbon ore in a downstream direction. Optionally, by using nitrogen free oxygen for the oxidation, a nitrogen free stream of carbon dioxide is produced suitable for carbon dioxide capture and management. This can also eliminate the production of NOx in the oxidation process.

A method of continuously recovering hydrocarbons from carbon ores can include providing first and second vessels containing rubblized carbon ore. A cooling fuel gas can be introduced into the first vessel. The cooling fuel gas can include oxygen and a recycle gas from the second vessel, which includes hydrocarbons and oxidation products. The oxygen can be consumed through oxidation in an oxidation zone in the first vessel. The temperature of the oxidation zone can be controlled by limiting the oxygen concentration in the cooling fuel gas. This can produce a hot oxidation product gas that heats rubblized carbon ore in a pyrolysis zone downstream of the oxidation zone. Gaseous and vapor hydrocarbons can be produced in the pyrolysis zone. The vapor hydrocarbons can be condensed in a condensing zone downstream of the pyrolysis zone and then collected. The remaining gaseous hydrocarbons and oxidation products can be recycled as the recycle gas. The oxidation zone and the pyrolysis zone can continuously move through the rubblized carbon ore in a downstream direction. Optionally, by using nitrogen free oxygen for the oxidation, a nitrogen free stream of carbon dioxide is produced suitable for carbon dioxide capture and management. This can also eliminate the production of NOx in the oxidation process.

A method of producing a coal mixture includes blending a plurality of coals, wherein formula (1) and formula (2) are satisfied: $\begin{array}{cc}{}_{\mathrm{calc}}=\underset{i}{\overset{N}{.Math.}}{}_i{x}_i& \left(1\right)\end{array}$
.sub.calc1.210.sup.10 (mol/g-coal)(2)
wherein .sub.calc is a hydrogen ion release capacity per unit mass (mol/g-coal) of the coal mixture, .sub.i is the hydrogen ion release capacity per unit mass (mol/g-coal) of a coal i, x.sub.i is a blending ratio of the coal i blended in the coal mixture, and N is a total number of brands of coal contained in the coal mixture.

A method of producing a coal mixture includes blending a plurality of coals, wherein formula (1) and formula (2) are satisfied: $\begin{array}{cc}{}_{\mathrm{calc}}=\underset{i}{\overset{N}{.Math.}}{}_i{x}_i& \left(1\right)\end{array}$
.sub.calc1.210.sup.10 (mol/g-coal)(2)
wherein .sub.calc is a hydrogen ion release capacity per unit mass (mol/g-coal) of the coal mixture, .sub.i is the hydrogen ion release capacity per unit mass (mol/g-coal) of a coal i, x.sub.i is a blending ratio of the coal i blended in the coal mixture, and N is a total number of brands of coal contained in the coal mixture.

High quality coke products made in horizontal ovens such as heat recovery, non-recovery or Thompson ovens from an optimized coal blend. The coke products have unique properties such as an oblong shape and improved Coke Strength after Reaction (CSR) and Coke Reactivity Index (CRI) properties.

The delayed coking method includes directing a heated secondary feedstock, which contains heated primary feedstock and recirculate, from a reaction furnace to a coking chamber. Vapor-liquid coking products formed in the coking chamber are then directed to a fractionation column, which fractionates hydrocarbon gas, gasoline, light and heavy gas oils, and bottom residues. Heavy gas oil from the fractionation column is directed to a thermal cracking furnace, the products of which are cooled by cooled light gas oil and directed to an evaporator for separation. In the evaporator, gases and light boiling products are removed by evaporation and returned to the fractionation column, and the remaining distillate cracking residue is separated and used as a component of the recirculate, along with bottom residues from the fractionation column. The resulting process produces high quality and high yield needle and anode cokes.

Systems and methods of production for consistently sized and shaped optically anisotropic mesophase pitch from vacuum residue, one method including supplying processed vacuum residue to an extruder; heating the processed vacuum residue throughout a horizontal profile of the extruder from an inlet to an outlet of the extruder; venting hydrocarbon off-gases from the extruder along the horizontal profile of the extruder from the inlet to the outlet of the extruder; and physically shaping the consistently sized and shaped mesophase pitch at the outlet of the extruder for production of carbon fibers.

Systems and methods of production for consistently sized and shaped optically anisotropic mesophase pitch from vacuum residue, one method including supplying processed vacuum residue to an extruder; heating the processed vacuum residue throughout a horizontal profile of the extruder from an inlet to an outlet of the extruder; venting hydrocarbon off-gases from the extruder along the horizontal profile of the extruder from the inlet to the outlet of the extruder; and physically shaping the consistently sized and shaped mesophase pitch at the outlet of the extruder for production of carbon fibers.