Patent classifications
C10G1/002
Production of hydrocarbons from recycled or renewable organic material
A method is disclosed of producing hydrocarbons from a recycled or renewable organic material, wherein the recycled or renewable organic material contains from 5 to 30 wt-% oxygen as organic oxy-gen compounds and from 1 to 1000 ppm phosphorous as phosphorous compounds. Exemplary methods include (a) providing the recycled or renewable organic material (c) thermally cracking the recycled or renewable organic material thereby reducing the oxygen and phosphorous content of the recycled or renewable organic material to obtain (i) a vapor fraction containing a major part of volatiles, and (ii) a thermally cracked recycled or renewable organic material fraction containing less oxygen and less phosphorous than the recycled or renewable organic material provided in step (a); and (f) hydrotreating the thermally cracked recycled or renewable organic material fraction in a presence of a hydrotreating catalyst; to obtain hydrocarbons containing less than 1 wt % oxygen and less phosphorous than the recycled or re-newable organic material provided in step (a).
HIGH PRESSURE DEPOLYMERIZATION OF HDPE AND PP
A method of depolymerizing polymeric material including the steps of: (a) feeding a polymeric material to a depolymerization reactor maintained at a temperature in the range of from 400° C. to 600° C. and operated under a pressure in the range of from 4 to 15 barg; and (b) depolymerizing at least a portion of the polymeric material thereby forming a first gaseous product and a first liquid product.
Manufacture of a synthetic fuel
The present invention provides a process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, the process comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; sequentially removing ammoniacal, sulphurous and carbon dioxide impurities from the raw synthesis gas to form desulphurised gas and recovering carbon dioxide in substantially pure form; converting at least a portion of the desulphurised synthesis gas to a useful product. Despite having selected a more energy intensive sub-process i.e. physical absorption for removal of acid gas impurities, the overall power requirement of the facility is lower on account of lower steam requirements and thereby leading to a decrease in the carbon intensity score for the facility.
EXTRACTION SOLVENTS FOR PLASTIC-DERIVED SYNTHETIC FEEDSTOCK
Disclosed are extraction solvents used in compositions and methods to refine synthetic feedstocks derived from plastic. Methods of refining plastic-derived synthetic feedstocks are also provided. For example, a method of refining a plastic-derived synthetic feedstock composition may include adding an extraction solvent to a synthetic feedstock composition derived from plastic pyrolyis to provide an extract phase and a raffinate phase, wherein the extraction solvent includes a polar organic extraction solvent immiscible in the synthetic feedstock. The methods may also include separating the raffinate phase from the extract phase to obtain a refined synthetic feedstock.
PLASTIC BLENDING METHODS, SYSTEMS, AND APPPARATUS FOR EFFICIENTLY REDUCING CARBON FOOTPRINTS IN REFINING SYSTEMS AND PETROCHEMICAL PROCESSING SYSTEMS
Aspects of the present disclosure relate to methods, systems, and apparatus for efficiently reducing carbon footprints in refining systems and petrochemical processing systems. In one aspect, a plastic powder feedstock is blended into a feedstock of a processing system to re-use plastic and reduce carbon footprints. In one implementation, a method of blending plastics into a processing system includes pulverizing a plastic supply to a plastic stock having a granule size that is within a range of 7 nanometers to 10 nanometers. The method includes separating the plastic stock to remove a portion having a granule size that is outside of the range of 7 nanometers to 10 nanometers and generate a plastic feedstock. The method includes blending the plastic feedstock into a feedstock of the processing system to generate a blended feedstock, and processing the blended feedstock.
PROCESS OF CATALYTIC CRACKING OF SOLID WASTE FROM PINE DERIVATIVES INDUSTRY
A process for catalytic cracking of waste originating from pine processing industry for producing a mixture of chemical compounds, e.g., components for formulation of adhesives, foams, antioxidants, sugars, among others. Optionally, additional steps can be added to the process for processing the obtained mixtures in order to obtain purer fractions with greater commercial interest and value.
PROCESS TO PREPARE A GAS OIL PRODUCT
The invention is directed to a process to prepare a gas oil product from a carbonaceous particles of a biomass source comprising the following steps: (a) pyrolysis of the carbonaceous particles to a gaseous mixture of hydrocarbons in the absence of oxygen, (b) quenching the gaseous mixture of hydrocarbons by contacting with a liquid quench mixture of hydrocarbons having a lower temperature than the gaseous mixture thereby obtaining a rich liquid quench mixture and a quenched gas, and (c) isolating from the quenched gas a gas oil product by means of vacuum distillation, wherein the liquid gas oil is partly supplied to the top of the vacuum distillation column as a distillation reflux, partly used as part of the liquid quench mixture in (b) and partly discharged as the gas oil product.
Circular chemicals or polymers from pyrolyzed plastic waste and the use of mass balance accounting to allow for crediting the resultant products as circular
This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based, fossil fuel-based, or bio-based feedstock. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways. The use of a mass balance approach which attributes the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit has been developed, which permits ISCC certification agency approval.
BIOCARBON COMPOSITIONS WITH OPTIMIZED COMPOSITIONAL PARAMETERS, AND PROCESSES FOR PRODUCING THE SAME
In some variations, the disclosure provides a renewable biocarbon composition comprising from 50 wt % to 99 wt % total carbon, wherein the biocarbon composition is characterized by a base-acid ratio selected from 0.1 to 10, an iron-calcium ratio selected from 0.05 to 5, iron-plus-calcium parameter selected from 5 to 50 wt %, a slagging factor selected from 0.001 to 1, and/or a fouling factor or modified fouling factor selected from 0.1 to 10. Some variations provide a process comprising: providing a biomass feedstock; pyrolyzing the biomass feedstock to generate an intermediate biocarbon stream; washing or treating the intermediate biocarbon stream with an acid, a base, a salt, a metal, H.sub.2, H.sub.2O, CO, CO.sub.2, or a combination thereof, and/or introducing an additive in the process, to adjust a base-acid ratio or other compositional parameter; and recovering a biocarbon composition comprising from 50 wt % to 99 wt % total carbon and optimized for a compositional parameter.
ELECTRIC-POWERED, CLOSED-LOOP, CONTINUOUS-FEED, ENDOTHERMIC ENERGY-CONVERSION SYSTEMS AND METHODS
Electric-powered, closed-loop, continuous-feed, endothermic energy-conversion systems and methods are disclosed. In one embodiment, the presently disclosed energy-conversion system includes a shaftless auger. In another embodiment, the presently disclosed energy-conversion system includes a drag conveyor. In yet another embodiment, the presently disclosed energy-conversion system includes a distillation and/or fractionating stage. The endothermic energy-conversion systems and methods feature mechanisms for natural resource recovery, refining, and recycling, such as secondary recovery of metals, minerals, nutrients, and/or carbon char.