The present invention relates to a process for purifying a crude nitrogen-containing, sulfur-containing, halogen-containing pyrolysis oil originating from the pyrolysis of plastic waste, comprising (i) subjecting the crude pyrolysis oil to a treatment with a trapping agent selected from (a) an elemental metal of group 1, 2, 6, 7, 8, 9, 10, 11, 12, 13 of the IUPAC periodic table, a mixture or an alloy thereof; (b) an oxide of metals of group 1, 2, 6, 7, 8, 9, 10, 11, 12, 13 of the IUPAC periodic table or a mixture thereof; (c) an alkoxide of metals of group 1, 2 of the IUPAC periodic table or a mixture thereof; (d) a solid sorption agent as defined in the claims; or a combination of at least two trapping agents (a), (b), (c) or (d); (ii) separating the product obtained into a purified pyrolysis oil fraction having a reduced nitrogen, sulfur and halogen content in relation to the crude pyrolysis oil and a fraction comprising the trapping agent which has bound at least a part of the sulfur, nitrogen, halogen present in the crude pyrolysis oil

Chemical recycling facilities for processing mixed waste plastic are provided herein. Such facilities have the capability of processing mixed plastic waste streams and utilize a variety of recycling facilities, such as, for example, solvolysis facility, a pyrolysis facility, a cracker facility, a partial oxidation gasification facility, an energy recovery facility, and a solidification facility. Streams from one or more of these individual facilities may be used as feed to one or more of the other facilities, thereby maximizing recovery of valuable chemical components and minimizing unusable waste streams.

Chemical recycling facilities for processing mixed waste plastic are provided herein. Such facilities have the capability of processing mixed plastic waste streams and utilize a variety of recycling facilities, such as, for example, solvolysis facility, a pyrolysis facility, a cracker facility, a partial oxidation gasification facility, an energy recovery facility, and a solidification facility. Streams from one or more of these individual facilities may be used as feed to one or more of the other facilities, thereby maximizing recovery of valuable chemical components and minimizing unusable waste streams.

Systems and methods of processing pyoil are disclosed. A pyoil is treated by an adsorbent to trap, and/or adsorb gum and/or gum precursors and other heteroatom containing components, thereby removing the gum and/or gum precursors from the pyoil and producing a purified pyoil. The purified pyoil can then be cracked to produce chemicals including olefins and aromatics.

A method for upgrading heavy oil by using a coke production byproduct comprises the steps of: producing a mixed solution by mixing a coke production byproduct and heavy oil; and hydrogenating the mixed solution under a hydrogenation catalyst, wherein the present disclosure is economical and effective by being able to reduce the amount of coke formation and significantly reduce the partial pressure of added hydrogen by using the coke production byproduct as a hydrogen donor.

The disclosure relates to a process for converting lignin (10) to renewable product (80), wherein the process comprises the following steps; mixing (100) lignin (10) with aqueous solution (20) to obtain a mixture (30); heating (110) the mixture (30) of step (a) to a temperature between 290 and 350° C., under a pressure from 70 to 165 bar, to obtain a first product mix (40); separating aqueous phase (53) and oil phase (50), and optionally gas (51) and solids (52), of the first product mix (40) of step (b); and heating (130) the oil phase (50) of step (c) and solvent (60) to obtain a second product mix (70). The second product mix (70) can be used as such, it can be directed to separation (140) or it can be upgraded. The obtained liquid renewable product is suitable as chemicals, fuel, fuel components or feedstock for fuel production.

Disclosed is a method for maximizing ethylene or propene production, the main steps thereof being: taking crude oil and distillate thereof, pre-processing urban mixed-waste plastics as raw material, then entering same into a catalytic cracking reactor, removing via a two-stage pre-wash tower and related separation, then cooling the reacted high-temperature oil and gas and removing impurities to obtain light and heavy distillate oils; performing a hydrogenation reaction operation on the heavy distillate oil; performing light distillate oil separation, performing a recombination operation on its olefins, its alkanes entering a steam cracking apparatus to produce rich ethylene, and its aromatic components being separated as by-products; the product of the described hydrogenation and recombination reaction and the steam-cracked distillate oil is recycled to the catalytic cracking reactor. In the production method of the present invention, the yield of ethylene and propene together is 45-75 m % of the raw material, and the yield of aromatics is 15-30 m % of the raw material; in particular, when using urban mixed-waste plastics as raw material, the ethylene or propene thus produced are used to produce new plastics by way of a conventional polymerization process, achieving the chemical recycling of waste plastics.

In this invention, a portion of the products from a pyrolysis reactor are reacted in a process to form one or more chemical intermediates.

The present invention discloses a rapid evaluation method for quality of lignin-pyrolyzed bio-oil and an application thereof, and particularly relates to a rapid evaluation method for quality of lignin-pyrolyzed bio-oil based on radical detection and an application thereof. The method can be used to evaluate the quality of lignin-pyrolyzed bio-oil by detecting the spin concentration of radicals in lignin char obtained by lignin pyrolysis, thus avoiding the complex processes involved in the evaluation for the quality of conventional pyrolyzed bio-oils such as, extraction, separation and detection and reducing the detection costs substantially. The detection method of the present invention is simple and easy to operate, thus achieving the rapid evaluation for the quality of lignin-pyrolyzed bio-oil. Moreover, the detection method of the present invention is non-contact detection without destructive samples, which is applicable to the rapid detection on the quality of lignin-pyrolyzed bio-oil in the field of industry and scientific research. The present invention further broadens the application fields of radical detection and contributes to the development of radical detection technology in the field of pyrolysis, and provides a reliable method for the detection of lignin-pyrolyzed bio-oil, which has good application prospect.

A process for liquid-liquid extraction of an oil-blend of non-uniform oligomeric and polymeric components comprising: (a) preselecting a desired molecular weight (Mw) boundary between heavy and light components; (b) selecting an extractive solvent or an extractive mixture of solvents, which form essentially a single phase with the light components; (c) mixing the oil-blend and the extractive solvent or extractive mixture of solvents selected in step (b) at elevated temperature, which is at least at or above said fractionation temperature, and wherein the extractive solvent/mixture of solvents to oil-blend ratio is from 1:2 to 100:1; (d) allowing a phase split to form between the heavy components fraction and the light components/extractive solvent fraction at the fractionation temperature or at most 10° C. below the fractionation temperature; (e) followed by separation of said fractions.