The present invention provides a blended fuel and methods for producing the blended fuel, wherein a low carbon fuel derived from a renewable resource such as biomass, is blended with a traditional, petroleum derived fuel. A blended fuel which includes greater than 10% by volume of low carbon fuel has an overall improved lifecycle greenhouse gas content of about 5% or more compared to the petroleum derived fuel. Also, blending of the low carbon fuel to the traditional, petroleum fuel improves various engine performance characteristics of the traditional fuel.

A process is disclosed that converts flue gas carbon dioxide to liquid fuels with the aid of biomass and methane. This process incorporates biomass pyrolysis, and gasification of the renewable carbon obtained from this pyrolysis with carbon dioxide and methane in two separate gasification reactors. The gasification reactions occur optionally in the presence of microwave energy. Water, liquid fuels and a sequesterable carbon are expected to be the primary products in this carbon negative process.

A Fischer-Tropsch (FT) process with a hybrid membrane/PSA configuration provides high component recoveries from FT off gas with minimum power consumption. Synthesis gas from a synthesis gas production zone is reacted in an FT reaction zone forming a liquid stream and an off gas stream. The off gas from the FT reaction zone, which contains hydrogen, carbon monoxide, and methane reactants, is recycled to the synthesis gas production zone. A purge stream from the recycle loop is sent to a membrane separation unit where it is separated into a permeate stream and a residue stream. The residue stream is separated in a pressure swing adsorption (PSA) unit into a fuel gas stream and a second stream. The second stream can be compressed and recycled to the synthesis gas production zone.

Efficiency of a thermochemical regeneration combustion system is enhanced by incorporation of gaseous products from pyrolysis of fuel such as biomass.

A method for charging a catalyst into a reactor (40) comprising a separation loop (21), comprising the following steps: a) filling the reactor (40) with a solvent S1; b) filling the separation loop (21) with said solvent S1; c) causing said solvent S1 to move in the synthesis reactor (40) and the separation loop (21); d) heating the reactor (40) to a temperature of 100 C. or less; e) injecting an inert gas into the bottom of the reactor (40); f) mixing said catalyst with a solvent S2 in a vessel (30) in order to obtain a liquid/solid mixture; g) increasing the pressure in the vessel (30) then sending the liquid/solid mixture to the reactor (40); h) withdrawing said solvent S1 and/or S2.

A process is described for producing middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis and divided into a light fraction (cold condensate) and a heavy fraction (waxes). The process involves fractionation of the waxes to obtain a light fraction, the final boiling point of which is between 350 C. and 400 C., and a heavy fraction which boils above the light fraction. The light fraction is mixed with at least one portion of the cold condensate. The resultant mixture is hydrotreated in the presence of a hydrotreatment catalyst of at least one portion of the resultant effluent is hydroisomerized in the presence of a catalyst comprising at least one noble metal from Group VIII and at least one zeolite IZM-2. At least one portion of the heavy fraction is subjected to hydrocracking and hydroisomerization in the presence of a hydrocracking catalyst. The resultant effluents are fractionated to obtain at least one middle distillates fraction.

The invention relates to Fischer-Tropsch synthesis in a compact version. A compact reactor comprises a housing, rectangular reaction channels inside the housing, which are filled with a cobalt catalyst, synthesis gas injection nozzles in the number determined by the ratio of the number of channels to the number of synthesis gas injection nozzles, an input and output nozzle for heat transfer medium on which a pressure controller installed, and an assembly for withdrawing synthetic hydrocarbons. The cobalt catalyst is activated by passing hydrogen through it. Synthetic hydrocarbons are produced by passing synthesis gas through the reaction channels filled with the activated cobalt catalyst. The space velocity of synthesis gas is increased every 300-500 h, followed by returning to the initial process conditions. This provides a high-molecular-weight hydrocarbon output per unit mass of the reactor.

A carbonaceous fuel gasification system for all-steam gasification with carbon capture includes a micronized char preparation system comprising a devolatilizer that receives solid carbonaceous fuel, hydrogen, oxygen, and fluidizing steam and produces micronized char, steam, volatiles, hydrogen, and volatiles at outlets. An indirect gasifier includes a vessel comprising a gasification chamber that receives the micronized char, a conveying fluid, and steam. The gasification chamber produces syngas, ash, and steam at one or more outlets. A combustion chamber receives a mixture of hydrogen and oxidant and burns the mixture of hydrogen and oxidant to provide heat for gasification and for heating incoming flows, thereby generating steam and nitrogen. The heat for gasification is transferred from the combustion chamber to the gasification chamber by circulating refractory sand. The system of the present teaching produces nitrogen free high hydrogen syngas for applications such as IGCC with CCS, CTL, and Polygeneration plants.

A process for the generation of energy and/or hydrocarbons and other products utilizing carbonaceous materials. In a first process stage (P1) the carbonaceous materials are supplied and are pyrolysed, wherein pyrolysis coke (M21) and pyrolysis gas (M22) are formed. In a second process stage (P2), the pyrolysis coke (M21) from the first process stage (P1) is gasified, wherein synthesis gas (M24) is formed, and slag and other residues (M91, M92, M93, M94) are removed. In a third process stage (P3), the synthesis gas (M24) from the second process stage (P2) is converted into hydrocarbons and/or other solid, liquid, and/or gaseous products (M60), which are discharged. The three process stages (P1, P2, P3) form a closed cycle. Surplus gas (M25) from the third process stage (P3) is passed as recycle gas into the first process stage (P1), and/or the second process stage (P2), and pyrolysis gas (M22) from the first process stage (P1) is passed into the second process stage (P2), and/or the third process stage (P3).

The present invention describes a process for the isomerization of paraffinic feedstocks operating at a temperature of between 200 C. and 500 C., at a total pressure of between 0.45 MPa and 7 MPa, at a hydrogen partial pressure of between 0.3 and 5.5 MPa, at an hourly space velocity of between 0.1 and 10 kilograms of feedstock introduced per kilogram of catalyst and per hour and using a catalyst comprising at least one metal of group VIII of the periodic table of elements, at least one matrix and at least one zeolite IZM-2, in which the ratio between the number of moles of silicon and the number of moles of aluminium of the zeolite IZM-2 network is between 25 and 55, preferably between 25 and 50, and preferably between 30 and 50.