Patent classifications
C10G47/24
REACTOR SYSTEM AND PROCESS FOR UPGRADING HEAVY HYDROCARBONACEOUS MATERIAL
The present invention relates to a hydrocracking reactor system and a process utilizing the same for upgrading heavy hydrocarbonaceous material to value-added products. Accordingly, an aspect of the present invention includes dispersing a liquid feedstock pre-mixed with a catalyst from top of a reactor vessel to obtain dispersed droplets having a predetermined droplet size less than 500 m, introducing a gaseous feed comprising primarily of hydrogen from bottom of the reactor vessel to form a continuous gaseous phase throughout a cross-section of the reactor vessel, and allowing the dispersed droplets to contact the continuous gaseous phase throughout the cross-section of the reactor vessel to form reaction effluent comprising one or more lighter product hydrocarbons. The method may further include removing at least a top portion and at least a bottom portion of the reaction effluent from the reactor vessel.
PROCESS AND SYSTEM FOR CONVERSION OF CRUDE OIL TO PETROCHEMICALS AND FUEL PRODUCTS INTEGRATING STEAM CRACKING AND FLUID CATALYTIC CRACKING
Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking and fluid catalytic cracking. Feeds to the mixed feed steam cracker include light products and naphtha from hydroprocessing zones within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline and FCC naphtha aromatics extraction zone within the battery limits.
PROCESS AND SYSTEM FOR CONVERSION OF CRUDE OIL TO PETROCHEMICALS AND FUEL PRODUCTS INTEGRATING STEAM CRACKING AND FLUID CATALYTIC CRACKING
Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking and fluid catalytic cracking. Feeds to the mixed feed steam cracker include light products and naphtha from hydroprocessing zones within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline and FCC naphtha aromatics extraction zone within the battery limits.
HYDROCRACKING PROCESS AND DEVICE WITH REDUCTION OF POLYNUCLEAR AROMATIC COMPOUNDS
In the hydrocracking process in accordance with the invention, which comprises a hydrocracking section, a high pressure hot separator and a fractionation section, upstream of the fractionation section, a stripper or reboiler column type separation column is added which treats at least a portion of the heavy effluent obtained from the high pressure hot separator. All or a portion of the bottom fraction from said column, which is rich in polynuclear aromatic compounds, is purged. At least a portion of the bottom fraction obtained from the fractionation section, which is constituted by unconverted products, is recycled to the reaction section.
HYDROCRACKING PROCESS AND DEVICE WITH REDUCTION OF POLYNUCLEAR AROMATIC COMPOUNDS
In the hydrocracking process in accordance with the invention, which comprises a hydrocracking section, a high pressure hot separator and a fractionation section, upstream of the fractionation section, a stripper or reboiler column type separation column is added which treats at least a portion of the heavy effluent obtained from the high pressure hot separator. All or a portion of the bottom fraction from said column, which is rich in polynuclear aromatic compounds, is purged. At least a portion of the bottom fraction obtained from the fractionation section, which is constituted by unconverted products, is recycled to the reaction section.
ALIPHATIC CRACKING AND DEALKYLATION WITH HYDROGEN DILUENT
A naphtha cracking feed stream is taken, heated and passed to a cracking reactor. Hydrogen is added to the cracking reactor to mitigate catalyst deactivation. The aliphatic compounds are selectively cracked and at least a portion of the alkyl groups on the aromatic compounds are selectively dealkylated in the presence of a cracking catalyst to produce a cracked effluent stream comprising aromatic compounds and cracked olefins.
Pyrolysis tar upgrading process
A process for upgrading pyrolysis tar to higher value products. More particularly, this invention relates to the upgrading of steam cracker tar using relatively small amounts of a transition metal sulfide-containing particulate catalyst dispersed throughout the tar chargestock and in the presence of hydrogen, at relatively mild hydroconversion conditions.
Pyrolysis tar upgrading process
A process for upgrading pyrolysis tar to higher value products. More particularly, this invention relates to the upgrading of steam cracker tar using relatively small amounts of a transition metal sulfide-containing particulate catalyst dispersed throughout the tar chargestock and in the presence of hydrogen, at relatively mild hydroconversion conditions.
METHOD FOR CONVERTING FEEDSTOCKS COMPRISING A HYDROTREATMENT STEP, A HYDROCRACKING STEP, A PRECIPITATION STEP AND A SEDIMENT SEPARATION STEP, IN ORDER TO PRODUCE FUEL OILS
The invention concerns a process for the treatment of a hydrocarbon feed, said process comprising the following steps: a) a hydrotreatment step, in which the hydrocarbon feed and hydrogen are brought into contact over a hydrotreatment catalyst, b) an optional step of separating the effluent obtained from the hydrotreatment step a), c) a step of hydrocracking at least a portion of the effluent obtained from step a) or at least a portion of the heavy fraction obtained from step b), d) a step of separating the effluent obtained from step c), e) a step of precipitating sediments, f) a step of physical separation of the sediments from the heavy liquid fraction obtained from step e), g) a step of recovering a liquid hydrocarbon fraction having a sediment content, measured using the ISO 10307-2 method, of 0.1% by weight or less.
METHOD FOR CONVERTING FEEDSTOCKS COMPRISING A HYDROTREATMENT STEP, A HYDROCRACKING STEP, A PRECIPITATION STEP AND A SEDIMENT SEPARATION STEP, IN ORDER TO PRODUCE FUEL OILS
The invention concerns a process for the treatment of a hydrocarbon feed, said process comprising the following steps: a) a hydrotreatment step, in which the hydrocarbon feed and hydrogen are brought into contact over a hydrotreatment catalyst, b) an optional step of separating the effluent obtained from the hydrotreatment step a), c) a step of hydrocracking at least a portion of the effluent obtained from step a) or at least a portion of the heavy fraction obtained from step b), d) a step of separating the effluent obtained from step c), e) a step of precipitating sediments, f) a step of physical separation of the sediments from the heavy liquid fraction obtained from step e), g) a step of recovering a liquid hydrocarbon fraction having a sediment content, measured using the ISO 10307-2 method, of 0.1% by weight or less.