Fuel oil compositions, and methods for blending such fuel oil compositions, to enhance initial compatibility and longer term stability when such fuel oil compositions are blended to meet IMO 2020 low sulfur fuel oil requirements (ISO 8217). In one or more embodiments, asphaltenic resid base stocks are blended with high aromatic slurry oil to facilitate initial compatibility such that low sulfur cutter stocks, e.g., vacuum gas oil and/or cycle oil, may be further blended therein to cut sulfur content while maintaining longer term stability. These fuel oil compositions are economically advantageous when used as marine low sulfur fuel oils because greater concentrations of high viscosity resids are present in the final blend.

A non-petroleum or renewable feedstock containing oxygen and contaminants of metals, gums, and resins is treated by introducing the feedstock into a reactor at a flow velocity of from 20 ft/sec to 100 ft/sec. The feedstock is heated within the reactor to a temperature of from 700° F. to 1100° F. to remove and/or reduce the content of the contaminants to form a reactor product. The reactor product is cooled to form a cooled reactor product. Non-condensable gases, metals and water are separated and removed from the cooled reactor product to form a final product. The final product has an oxygen content that is 60% or less of that of the feedstock, and wherein the final product comprises 25 wt % or less any triglycerides, monoglycerides, diglycerides, free fatty acids, phosphatides, sterols, tocopherols, tocotrienols, or fatty alcohols, from 5 wt % to 30 wt % naphtha, and 50 wt % or more diesel.

A renewable hydrocarbon composition as disclosed includes monobranched isoparaffins, dibranched isoparaffins, tribranched isoparaffins multibranched isoparaffins, and n-paraffins, having carbon numbers from C8 to C30. Said renewable hydrocarbon composition has high cetane number and excellent cold properties. The renewable hydrocarbon composition can be used as diesel fuel or as a diesel fuel component.

One exemplary embodiment can be a process for producing a diesel fuel. The process can include providing a hydrocarbon feed to a residue processing unit. Generally, the residue processing unit includes a solvent deasphalting zone, a hydroprocessing zone, and a hydroprocessing fractionation zone. The process can further include recycling at least a portion of an unconverted oil stream from the hydroprocessing fractionation zone, and sending one part of the at least a portion of the recycled unconverted oil stream to the unconverted oil fractionation zone providing a light unconverted oil stream downstream of the solvent deasphalting zone and a heavy unconverted oil stream to the solvent deasphalting zone.

A diesel fuel composition containing a renewable diesel component and oxymethylene ethers having molecular structure CH3O—(CH2O)n-CH3 with n=3-5 (OME3-5). A method for producing a diesel fuel composition and use thereof. Use of OME3-5 to decrease particle emission of renewable diesel fuels is further disclosed.

The invention relates to a catalytic process for upgrading a renewable crude oil produced from biomass and/or waste comprising providing a renewable crude oil and pressurizing it to a pressure in the range in the range 60 to 150 bar, contacting the pressurized renewable crude oil with hydrogen and at least one heterogeneous catalyst contained in a first reaction zone at a weight based hourly space velocity (WHSV) in the range 0.1 to 2.0 h.sub.−1 and at a temperature in the range of 150° C. to 360° C., hereby providing a partially upgraded renewable crude oil, separating the partially upgraded renewable crude oil from the first reaction zone to a partially upgraded heavy renewable oil fraction, a partially upgraded light renewable oil fraction, a water stream and a process gas stream, introducing the separated and partially upgraded heavy renewable oil fraction and separated process gas to a second reaction zone comprising at least two reactors arranged in parallel and being adapted to operate in a first and a second mode of operation, the reactors comprising dual functioning heterogeneous catalyst(-s) capable of performing a catalytic steam cracking reaction in a first mode of operation or a steam reforming reaction in a second mode of operation, where the partially upgraded heavy renewable oil fraction from the first reaction zone is contacted with the dual functioning heterogeneous catalyst and steam at a pressure of 10 to 150 bar and a temperature of 350° C. to 430° C. whereby a catalytic steam cracking of the partially upgraded heavy renewable oil is performed in the reactors in the first mode of operation, hereby providing a further upgraded heavy renewable oil fraction, while separated process gas from the first and/or second reaction zone is contacted with the dual functioning catalyst and steam at a pressure of 0.1 to 10 bar and a temperature of 350 to 600° C. in the reactors in the second mode of operation and contacted with the dual functioning catalyst, thereby producing a hydrogen enriched gas, separating the further upgraded heavy renewable oil fraction from the catalytically steam cracking reactor to at least one light renewable oil fraction, a heavy renewable oil fraction, a hydrogen rich process gas and a water phase, separating hydrogen from the hydrogen enriched gas from the catalytic steam cracking zone and/or from the catalytic steam reforming and recycling it to the first reaction zone, alternating the reactors between the first mode of operation and the second mode of operation at predetermined time intervals thereby allowing for regeneration of the heterogeneous catalyst for the catalytic steam cracking in the first mode of op

Process and plant for producing hydrocarbon products from a feedstock originating from a renewable source, where a hydrogen-rich stream and on off-gas stream comprising hydrocarbons is formed. A portion of the hydrogen-rich stream is used as a recycle gas stream in a hydroprocessing stage for the production of said hydrocarbon products, and another portion may be used for hydrogen production, while the off-gas stream is treated to remove its H.sub.2S content and used as a recycle gas stream in the hydrogen producing unit, from which the hydrogen produced i.e. make-up hydrogen, is used in the hydroprocessing stage. The invention enables minimizing natural gas consumption in the hydrogen producing unit as well as steam reformer size.

A process and an apparatus for pyrolysis of mixed plastic feedstock producing petroleum products are described. In one example, a process for producing petroleum products includes charging feedstock of mixed polymer materials into a reactor apparatus. Heat energy is applied to the feedstock while advancing the feedstock through the reactor apparatus in an anaerobic operation. The energy input to the reactor apparatus is controlled by controlling a temperature gradient within the reactor vessel to produce petroleum gas product. The process involves in situ chemical reactions comprising cracking and recombination reactions that that are controlled to convert solid hydrocarbonaceous portion of the feedstock to molten fluids and gases inside the reactor vessel and to produce gaseous petroleum products which exit the reactor vessel. The separated solid residue from the pyrolysis process is also removed from the reactions vessel.

A method for producing oil, comprising injecting water and a solvent into a formation; producing a mixture comprising water, solvent, oil, and gas from the formation; separating the mixture into a first stream comprising oil, water, and a first portion of the solvent, and a second stream comprising gas and a second portion of the solvent, and exposing the second stream to water to remove the second portion of the solvent from the gas.

A catalyst is illustrated, which has 70-90 parts by weight of mica, 1-10 parts by weight of zeolite, 5-15 parts by weight of titanium dioxide, 1-10 parts by weight of aluminum oxide, 1-5 parts by weight of sodium oxide and 1-5 parts by weight of potassium oxide. The present disclosure also illustrates a pyrolysis device using the catalyst, and further illustrates a pyrolysis method using the catalyst and/or the pyrolysis device for thermally cracking an organic polymer.