The present invention relates to a mechanochemical based synthesis of perfluoropyridine monomers, polymers made using such monomers and methods of making and using articles comprising such polymers. Such perfluoropyridine monomers are easily chemically tuned have the strength needed for high temperature applications and the flexibility needed for low temperature applications. In addition, to the aforementioned monomers, a mechanochemical based synthesis for such perfluoropyridine monomers is provided. All of the aforementioned performance application advantages are also found in polymers comprising Applicants' perfluoropyridine monomers.

Provided is a lubricant solution capable of being applied to a magnetic disk without use of a fluorine solvent. A lubricant solution in accordance with an aspect of the present invention includes: water; and a perfluoropolyether compound that satisfies Expression (I) below:

N.sub.OH/(Mn/1500)≥2  (1), where N.sub.OH represents the number of hydroxyl groups per molecule of the perfluoropolyether compound and Mn represents a number average molecular weight of the perfluoropolyether compound.

Provided is a lubricant composition having small shear rate dependence of its apparent viscosity. The lubricant composition includes a perfluoropolyether as a base oil, and fluorine resin particles as a thickener. The lubricant composition further includes a fluorine-containing polymer having a tetrafluoroethylene structure under a state in which the polymer is dissolved in the perfluoropolyether.

The present invention relates to a fluorine-containing ether compound represented by Formula (1),
R.sup.1—R.sup.2—CH.sub.2—R.sup.3—CH.sub.2—R.sup.4  (1).
(In Formula (1), R.sup.1 is an end group including an organic group having at least one double bond or triple bond, R.sup.2 is a divalent linking group bonded to R.sup.1 by etheric oxygen, R.sup.3 is a perfluoropolyether chain, R.sup.4 is an end group having two or three polar groups with each polar group being bonded to different carbon atoms, and the carbon atoms, to which the polar groups are bonded, being bonded to each other via a linking group including carbon atoms to which the polar groups are not bonded.)

Fluoropolyether compounds that can be used as a lubricant, such as for magnetic recording media. The compounds have a terminal group that includes a phenol or benzene. The fluoropolyether compounds reduce the head to media distance while keeping comparable reliability in a hard disk drive compared to current industrial widely used fluoropolyether based lubricants.

An object of an aspect of the present invention is to provide: a lubricant excellent in adsorbability on the surface of a magnetic disk and in contamination resistance; and a magnetic disk which uses the lubricant and which is excellent in durability. The lubricant in accordance with an aspect of the present invention contains a fluoropolyether compound having, at a terminal thereof, a hydroxyalkenyl group or a hydroxyalkynyl group.

The present invention relates to a composition suitable to be used as working fluid, said composition being in the form of a solution and comprising at least one (per)fluoropolyether polymer [polymer (P)] and at least one amorphous polymer [polymer (F)].

An epilamization agent containing at least one compound including at least hydrophobic and oleophobic moieties arranged to impart epilame properties to the compound, and at least one hydrophilic moiety arranged to make the compound soluble in aqueous medium, the hydrophilic moiety being linked to the compound by at least one cleavable group. A method for coating a substrate with epilame, including: preparing an aqueous epilamization bath by solubilising such an epilamization agent, placing the substrate in contact with the epilamization agent in the epilamization bath, separating the hydrophilic moiety from the epilamization agent by cleavage, rinsing the substrate to eliminate the hydrophilic residues from the hydrophilic moiety and drying.

Lubricant compositions and methods of applying lubricant compositions are provided that overcome problems associated with over-lubrication and waste of lubricants in a variety of industrial settings. In various aspects, a lubricant composition is provided with one or more carriers, wherein the surface tensions of the lubricant and carrier are selected to provide precise lubrication of a surface with the lubricant effectively wetting the surface. In various aspects, a lubricant composition is provided with one or more carriers, wherein the boiling points of the lubricant and carrier are selected to provide precise lubrication with easy removal of the carrier and wetting of the lubricant on the surface. In various aspects, methods of applying a precise amount of lubricant to a surface are provided to avoid waste of lubricant in various industrial settings.

Invention relates to corrosion-inhibiting compositions and the process of using said compositions to protect metal from corrosion. The compositions comprise of sulfonates, a carboxylic-sulfonic acid metal complex, antioxidants, fluorinated copolymers, hydrophobic silanes and siloxane additives and solvent.