The invention relates to a method for the production and removal of a temporary protective layer for a cathodic coating, particularly for the production of a hardened steel component with an easily paintable surface, wherein a steel sheet made of a hardenable steel alloy is subjected to a preoxidation, wherein said preoxidation forms a FeO layer with a thickness of 100 nm to 1,000 nm and subsequently a melt dip coating is conducted, wherein, during the melt dip coating, a zinc layer is applied having a thickness of 5 to 20 μm, preferably 7 to 14 μm, on each side, wherein the melt dip process and the aluminum content of the zinc bath is adjusted such that, during the melt dip coating, an aluminum content for the barrier layer results of 0.15 g/m.sup.2 to 0.8 g/m.sup.2 and the steel sheet or sheet components made therefrom is subsequently heated to a temperature above the austenitizing temperature and is then cooled at a speed greater than the critical hardening speed in order to cause hardening, wherein oxygen-affine elements are contained in the zinc bath for the melt dip coating in a concentration of 0.10 wt.-% to 15 wt.-% that, during the austenitizing on the surface of the cathodic protective layer, form a thin skin comprised of the oxide of the oxygen-affine elements and said oxide layer is blasted after hardening by irradiation of the sheet component with dry ice particles.

The invention relates to a method for the production and removal of a temporary protective layer for a cathodic coating, particularly for the production of a hardened steel component with an easily paintable surface, wherein a steel sheet made of a hardenable steel alloy is subjected to a preoxidation, wherein said preoxidation forms a FeO layer with a thickness of 100 nm to 1,000 nm and subsequently a melt dip coating is conducted, wherein, during the melt dip coating, a zinc layer is applied having a thickness of 5 to 20 μm, preferably 7 to 14 μm, on each side, wherein the melt dip process and the aluminum content of the zinc bath is adjusted such that, during the melt dip coating, an aluminum content for the barrier layer results of 0.15 g/m.sup.2 to 0.8 g/m.sup.2 and the steel sheet or sheet components made therefrom is subsequently heated to a temperature above the austenitizing temperature and is then cooled at a speed greater than the critical hardening speed in order to cause hardening, wherein oxygen-affine elements are contained in the zinc bath for the melt dip coating in a concentration of 0.10 wt.-% to 15 wt.-% that, during the austenitizing on the surface of the cathodic protective layer, form a thin skin comprised of the oxide of the oxygen-affine elements and said oxide layer is blasted after hardening by irradiation of the sheet component with dry ice particles.

There is provided a method of manufacturing an Ni-base superalloy which enables a uniform coat of a glass lubricant to be maintained even after heated to hot forging temperature. The method of manufacturing an Ni-base superalloy in which a forging stock containing an Ni-base superalloy, coated with a lubricant, is subjected to hot forging includes: a preliminary oxidation step of previously generating a Cr oxide coating film having a film thickness of 0.5 to 50 μm on the forging stock thereby to obtain a preliminarily oxidized material; a lubricant coating step of coating the preliminarily oxidized material with a glass lubricant containing borosilicate glass as a main component thereby to obtain a material to be forged; and a hot forging step of hot forging the material to be forged thereby to obtain a hot forged material.

There is provided a method of manufacturing an Ni-base superalloy which enables a uniform coat of a glass lubricant to be maintained even after heated to hot forging temperature. The method of manufacturing an Ni-base superalloy in which a forging stock containing an Ni-base superalloy, coated with a lubricant, is subjected to hot forging includes: a preliminary oxidation step of previously generating a Cr oxide coating film having a film thickness of 0.5 to 50 μm on the forging stock thereby to obtain a preliminarily oxidized material; a lubricant coating step of coating the preliminarily oxidized material with a glass lubricant containing borosilicate glass as a main component thereby to obtain a material to be forged; and a hot forging step of hot forging the material to be forged thereby to obtain a hot forged material.

A high-strength cold-rolled steel sheet having excellent bending workability includes, by weight %, 0.13-0.25% of carbon (C), 1.0-2.0% of silicon (Si), 1.5-3.0% of manganese (Mn), 0.08-1.5% of aluminum (Al)+chromium (Cr)+molybdenum (Mo), 0.1% or less of phosphorus (P), 0.01% or less of sulfur (S), 0.01% or less of nitrogen (N), the remainder of Fe and inevitable impurities, and comprises, by area fraction, 3-25% of ferrite, 20-40% of martensite, and 5-20% of retained austenite, in which a nickel-rich layer formed of nickel (Ni) introduced from the outside is provided on a surface layer portion, and the concentration of nickel (Ni) at a depth of 1 μm from the surface may be greater than or equal to 0.15 wt %.

A cold- or hot-rolled steel strip with a metallic coating, the steel strip having iron as the main constituent and, in addition to carbon, an Mn content of 8.1 to 25.0 wt. % and optionally one or more of the alloying elements Al, Si, Cr, B, Ti, V, Nb and/or Mo. The uncoated steel strip is first cleaned, a layer of pure iron is applied to the cleaned surface, an oxygen-containing, iron-based layer containing more than five mass percent of oxygen is applied to the layer of pure iron. The steel strip is then annealed and is reduction-treated in a reducing furnace atmosphere during the annealing treatment to obtain a surface consisting mainly of metallic iron. The steel strip is then hot-dip coated with the metallic coating. This creates uniform and reproducible bonding conditions for the coating on the steel strip surface.

Provided is a grain-oriented electrical steel sheet having a film that is effective for the magnetic properties of the steel sheet and particularly effective for iron loss reduction and has favorable adhesion. In a grain-oriented electrical steel sheet, an insulating film partially enters into a steel substrate to form an anchor part, a depth of the anchor part from the surface of the steel substrate is 3.5 μm or less, and a number of neck parts of 5 μm.sup.2 or less in area is 0.06/μm.sup.2 or less and a number of neck parts of 10 μm.sup.2 to 40 μm.sup.2 in area is 0.005/μm.sup.2 or more and 0.011/μm.sup.2 or less, where each neck part is a remaining part of the insulating film on the surface of the steel substrate when peeling the insulating film from the steel substrate in a bend test for the grain-oriented electrical steel sheet.

Provided is an annealing separating agent composition for a grain-oriented electrical steel sheet, a grain-oriented electrical steel sheet and a method for manufacturing a grain-oriented electrical steel sheet. The annealing separating agent composition for a grain-oriented electrical steel sheet according to an embodiment of the present invention contains 30 to 70% by weight of a calcium compound, and the remainder of magnesium oxide or magnesium hydroxide on a solid basis.

Provided is an annealing separating agent composition for a grain-oriented electrical steel sheet, a grain-oriented electrical steel sheet and a method for manufacturing a grain-oriented electrical steel sheet. The annealing separating agent composition for a grain-oriented electrical steel sheet according to an embodiment of the present invention contains 30 to 70% by weight of a calcium compound, and the remainder of magnesium oxide or magnesium hydroxide on a solid basis.

The present invention relates to a self-collapsed protective coating composition and use thereof. In particular, the invention relates to a self-collapsed protective coating composition for hot stamping of steel material, which can protect the surface of steel material from oxide scale and provide ease for subsequent welding.