An Fe-based amorphous alloy ribbon reduced in iron loss, less deformed, and highly productive in a condition of a magnetic flux density of 1.45 T is provided. One aspect of the present disclosure provides an Fe-based amorphous alloy ribbon having first and second surfaces, and is provided with continuous linear laser irradiation marks on at least the first surface. Each linear laser irradiation mark is formed along a direction orthogonal to a casting direction of the Fe-based amorphous alloy ribbon, and has unevenness on its surface. When the unevenness is evaluated in the casting direction, a height difference HL×width WA calculated from the height difference HL between a highest point and a lowest point in a thickness direction of the Fe-based amorphous alloy ribbon and the width WA which is a length of the linear irradiation mark on the first surface is 6.0 to 180 μm.sup.2.

A preparation method of glassless grain-oriented silicon steel includes the following operations. During a decarburization annealing, a thickness of an oxide film on a surface of strip is 1.5-2.5 μm; an atomic weight ratio of Si element and Fe element in the oxide film satisfies: Si/(Si+Fe)≥0.76; during a high-temperature annealing, a cooling stage includes sequentially: cooling with an inner cover when a temperature drops from 1200° C. to 500° C.; wherein a protective gas is a mixed gas containing nitrogen and hydrogen, and a volume percentage of the hydrogen in the mixed gas is >3%; cooling with the inner cover when the temperature drops from 500° C. to 200° C.; wherein the protective gas is nitrogen; and cooling in air by removing the inner cover when the temperature is <200° C.

In a laser processing apparatus for refining magnetic domains of a grain-oriented electromagnetic steel sheet by setting a laser beam to be focused on the grain-oriented electromagnetic steel sheet and scanned in a scanning direction, the laser beam focused on the grain-oriented electromagnetic steel sheet is linearly polarized light, and an angle between a linear polarization direction and the scanning direction is higher than 45° and equal to or lower than 90°.

In a laser processing apparatus for refining magnetic domains of a grain-oriented electromagnetic steel sheet by setting a laser beam to be focused on the grain-oriented electromagnetic steel sheet and scanned in a scanning direction, the laser beam focused on the grain-oriented electromagnetic steel sheet is linearly polarized light, and an angle between a linear polarization direction and the scanning direction is higher than 45° and equal to or lower than 90°.

An annealing separator for an oriented electrical steel sheet including: a first component includes a Mg oxide or a Mg hydroxide; and a second component including one kind among oxides and hydroxides of a metal selected from Al, Ti, Cu, Cr, Ni, Ca, Zn, Na, K, Mo, In, Sb, Ba, Bi, and Mn, or two or more kinds thereof.

Provided is a method for manufacturing a grain-oriented electrical steel sheet. A steel slab having a specific chemical composition is heated and hot rolled. A hot-rolled steel sheet thus obtained is subjected to hot band annealing to obtain a cold-rolled steel sheet, which is then subjected to primary recrystallization annealing to obtain a primary recrystallized steel sheet. An annealing separator is applied to the primary recrystallized steel sheet, which is then coiled. The coil is subjected to secondary recrystallization annealing to obtain a grain-oriented electrical steel sheet having an average value of a deviation angle (α.sup.2+β.sup.2).sup.1/2 calculated from a deviation angle α from ideal Goss orientation around an ND rotation axis and a deviation angle β from ideal Goss orientation around a TD rotation axis of 4.5° or less, and an area ratio R.sub.β of crystal grains with β≤0.50° of 15% or less.

A non-oriented electrical steel sheet according to an exemplary embodiment of the present invention includes, by weight %, Si: 2.5 to 6.0%, Al: 0.2 to 3.5%, Mn: 0.2 to 4.5%, Cr: 0.01 to 0.2%, P: 0.005 to 0.08%, Mg: 0.0005 to 0.05%, and a remainder including Fe and inevitable impurities, while satisfying Equation 1 below, and formed with an inner oxidation layer of a 0.2 to 5 μm thickness inside a base steel sheet.
−2.5≤[P]/[Cr]−[Mg]×100≤6.5  [Equation 1]
(In Equation 1, [P], [Cr], and [Mg] respectively represent a content (by wt %) of P, Cr, and Mg).

A non-oriented electrical steel sheet according to an exemplary embodiment of the present invention includes, by weight %, Si: 2.5 to 6.0%, Al: 0.2 to 3.5%, Mn: 0.2 to 4.5%, Cr: 0.01 to 0.2%, P: 0.005 to 0.08%, Mg: 0.0005 to 0.05%, and a remainder including Fe and inevitable impurities, while satisfying Equation 1 below, and formed with an inner oxidation layer of a 0.2 to 5 μm thickness inside a base steel sheet.
−2.5≤[P]/[Cr]−[Mg]×100≤6.5  [Equation 1]
(In Equation 1, [P], [Cr], and [Mg] respectively represent a content (by wt %) of P, Cr, and Mg).

A grain-oriented electrical steel sheet for a stacked transformer core. The steel sheet having a sheet thickness t, where t and an iron loss deterioration ratio obtained by subjecting the steel sheet under elliptic magnetization satisfy the following relations: (i) when t≤0.20 mm, the iron loss deterioration ratio is 85% or less; (ii) when 0.20 mm<t<0.27 mm, the iron loss deterioration ratio is 80% or less; and (iii) when 0.27 mm≤t, the iron loss deterioration ratio is 75% or less. The iron loss deterioration ratio is calculated from ((W.sub.A−W.sub.B)/W.sub.B)×100, where W.sub.A is iron loss under 50 Hz elliptic magnetization of 1.7 T in a rolling direction and 1.0 T in a direction orthogonal to the rolling direction, and W.sub.B is iron loss under 50 Hz alternating magnetization of 1.7 T in the rolling direction.

Provided is a method for manufacturing a grain-oriented electrical steel sheet. The method comprises: hot rolling a slab to obtain a hot rolled sheet; subjecting the hot rolled sheet to hot band annealing as necessary; subjecting the hot rolled sheet to cold rolling; subjecting the cold rolled sheet to decarburization annealing; applying an annealing separator having MgO as a main component onto a surface of the decarburization annealed sheet and subjecting the decarburization annealed sheet to final annealing to form the forsterite film; and applying an insulating coating treatment liquid onto the final annealed sheet and subjecting the final annealed sheet to flattening annealing to form a tension-applying insulating coating. A difference in total tensions between one and opposite surfaces of the sheet is less than 0.5 MPa. A difference in tensions between the forsterite films in one and opposite surfaces of the sheet is 0.5 MPa or more.