The present invention provides a steel sheet having excellent wear resistance and composite corrosion resistance, and a method for manufacturing same.

A corrosion-resistant steel sheet according to an embodiment of the present invention comprises, in wt %: 0.04 to 0.10% of carbon (C); 0.1% or less (excluding 0%) of silicon (Si); 0.20 to 0.35% of copper (Cu); 0.1% to 0.2% of nickel (Ni); 0.05 to 0.15% of antimony (Sb); 0.07 to 0.22% of tin (Sn); 0.05 to 0.15% of titanium (Ti); 0.01% or less (excluding 0%) of sulfur (S); 0.005% or less (excluding 0%) of nitrogen (N); the remainder iron (Fe); and unavoidable impurities, and satisfies formulas 1 and 2 below:

[Ni]/[Cu]≥0.5  [Formula 1]

48×([Ti]/48−[S]/32−[N]/14)≥0.04  [Formula 2] wherein, in formulas 1 and 2, [Ni], [Cu], [Ti], [S], and [N] represent contents (wt %) of Ni, Cu, Ti, S, and N contained in the steel sheet, respectively.

A non-oriented electrical steel sheet according to an embodiment of the present invention includes, in wt %, Si: 2.1 to 3.8%, Mn: 0.001 to 0.6%, Al: 0.001 to 0.6%, Bi: 0.0005 to 0.003%, and Ge: 0.0003 to 0.001%, and the balance of Fe and inevitable impurities.

In a tandem type cold rolling mill of a circulating oil-feeding system for continuously rolling a steel sheet by feeding a coolant serving as a rolling oil and a cooling water to each stand, an edge heater for heating both edge portions of the steel sheet to not lower than 60° C. as a steel sheet temperature at an entry side of a roll bite is arranged at an upstream side of the first stand in the cold rolling mill and a device for jetting a coolant having a concentration higher than that of the coolant fed to the firsts stand onto surfaces of both edge portions of the steel sheet is arranged between the edge heater and the first stand. The cold rolling mill can be used to roll a hard-to-roll material such as silicon or stainless steel sheet without causing an edge crack or sheet breakage in low-speed rolling.

The present invention relates to a non-oriented electrical steel sheet including 1.5 to 4.0 wt % of Si, 0.1 to 1.5 wt % of Al, 0.1 to 1.5 wt % of Mn, 0.005 wt % or less (excluding 0%) of C, 0.005 wt % or less (excluding 0%) of N, 0.005 wt % or less (excluding 0%) of Ti, 0.001 to 0.005 wt % of S, 0.1 wt % or less (excluding 0%) of P, 0.02 to 0.2 wt % of at least one of Sn and Sb, and a balance of Fe and other inevitable impurities; and satisfying the following Formulas 1, 2, and 3.
0.9≤[Al]+[Mn]≤2.1  [Formula 1]
0.2≤([Si]+[Al]+[Mn]/2)*([P]+[Sn]+[Sb])≤0.4  [Formula 2]
(Gs.sub.center−Gs.sub.surface)/(Gs.sub.center*t)≤0.5  [Formula 3] (In Formula 1 and Formula 2, [Al], [Mn], [Si], [P], [Sn], and [Sb] represent the content (weight %) of Al, Mn, Si, P, Sn, and Sb, respectively, and in Formula 3, t represents the thickness (mm) of the non-oriented electrical steel sheet, Gs.sub.surface represents the average grain size (μm) from 0 to t/4 or 3t/4 to t based on the thickness direction of the non-oriented steel sheet, Gs.sub.center represents the average grain size (μm) from more than t/4 to less than 3t/4 based on the thickness direction of the non-oriented steel sheet.)

A grain oriented electrical steel sheet includes a base steel sheet, a glass film, and a tension-insulation coating. When a glow discharge emission spectroscopy is conducted from a surface of the glass film toward a depth direction, an analysis starting time Ts, a time T.sup.Al.sub.p at which Al shows a maximum emission intensity, an Al emission intensity F(T.sup.Al.sub.p) at the T.sup.Al.sub.p, a time T.sup.Si.sub.p at which Si shows a maximum emission intensity, and an Al emission intensity F(T.sup.Si.sub.p) at the T.sup.Si.sub.p satisfy 0.05≤F(T.sup.Si.sub.p)/F(T.sup.Al.sub.p)≤0.50 and 2.0≤(T.sup.Al.sub.p−Ts)/(T.sup.Si.sub.p−Ts)≤5.0.

[Problem] To provide a grain-oriented electrical steel sheet which is further improved in terms of iron loss before magnetic domain control, while achieving a sufficient iron loss improvement effect even in the control of a heat-resistant magnetic domain where a sufficient iron loss improvement effect has not been achieved. [Solution] A grain-oriented electrical steel sheet according to one aspect of the present invention comprises abase steel sheet and a glass coating that is formed on the surface of the base steel sheet, and is characterized in that: the base steel sheet contains as chemical components, in mass %, 0.010% or less of C, from 2.00% to 4.00% of Si, from 0.05% to 1.00% of Mn, from 0.010% to 0.065% of Al, 0.004% or less of N and 0.010% or less of S, with the balance being made up of Fe and impurities; the oxygen concentration in the glass coating and the base steel sheet is 2,500 ppm or less; and if I.sub.Al_1 is the first peak intensity of Al and I.sub.Al_2 is the second peak intensity of Al in the concentration profile of Al, the relationship of mathematical formula (1) is satisfied.

I.sub.Al_1<I.sub.Al_2   Formula (1):

A grain-oriented electrical steel sheet of an embodiment of the present invention comprises Si: 1.0% to 7.0% and Y: 0.005% to 0.5% by wt %, and the remainder comprising Fe and other inevitable impurities, and 10 pieces or less of inclusions comprising Y and having a diameter of 30 nm to 5 μm per area of 1 mm.sup.2.

A grain-oriented electrical steel sheet of an embodiment of the present invention comprises Si: 1.0% to 7.0% and Y: 0.005% to 0.5% by wt %, and the remainder comprising Fe and other inevitable impurities, and 10 pieces or less of inclusions comprising Y and having a diameter of 30 nm to 5 μm per area of 1 mm.sup.2.

Disclosed is a manufacturing method for a high silicon grain oriented electrical steel sheet, the silicon content of the high silicon grain oriented electrical steel is greater than 4 wt %, comprising the steps of: (1) performing decarburization annealing of a cold-rolled steel plate; (2) allowing high silicon alloy particles in a completely solid state to collide at a high speed with the surface of the decarburization annealed steel plate to be sprayed, thus forming a high silicon alloy coating on the surface of the steel plate to be sprayed; (3) coating a release agent and drying; and (4) annealing. The manufacturing method for the high silicon grain oriented electrical steel sheet of the present invention is inexpensive, and, the high silicon grain oriented electrical steel sheet produced is of stable quality and is provided with great magnetic performance.

A grain oriented electrical steel sheet includes the texture aligned with Goss orientation. In the grain oriented electrical steel sheet, when a grain size RAα.sub.C, a grain size RAβ.sub.C, and a grain size RAγ.sub.C are defined in a transverse direction C, the grain sizes satisfy RAγ.sub.C<RAα.sub.C and RAγ.sub.C<RAβ.sub.C.