Provided is a method for obtaining high-purity scandium oxide efficiently from a solution containing scandium. The method for producing high-purity scandium oxide of the present invention has a first firing step S12 for subjecting a solution containing scandium to oxalation treatment using oxalic acid and firing the obtained crystals of scandium oxalate at a temperature of 400 to 600° C., inclusive, a dissolution step S13 for dissolving the scandium compound obtained by firing in one or more solutions selected from hydrochloric acid and nitric acid to obtain a solution, a reprecipitation step S14 for subjecting the solution to oxalation treatment using oxalic acid and generating a reprecipitate of scandium oxalate, and a second firing step S15 for firing the reprecipitate of obtained scandium oxalate to obtain scandium oxide.

Provided is a method for obtaining high-purity scandium oxide efficiently from a solution containing scandium. The method for producing high-purity scandium oxide of the present invention has a first firing step S12 for subjecting a solution containing scandium to oxalation treatment using oxalic acid and firing the obtained crystals of scandium oxalate at a temperature of 400 to 600° C., inclusive, a dissolution step S13 for dissolving the scandium compound obtained by firing in one or more solutions selected from hydrochloric acid and nitric acid to obtain a solution, a reprecipitation step S14 for subjecting the solution to oxalation treatment using oxalic acid and generating a reprecipitate of scandium oxalate, and a second firing step S15 for firing the reprecipitate of obtained scandium oxalate to obtain scandium oxide.

A process for extracting fluoride from a solution of high pH comprising more than 0.1 mol of alkaline hydroxide and/or alcoholate per liter dissolved in a polar solvent is described. The polar solvent is chosen from water, lower alcohols, and mixtures thereof. The process is characterized in that the solution liquid is contacted with a solid phase adsorbent chosen from a) alkaline earth salts comprising carbonate anions, oxo anions, sulphate anions, or phosphate anions, and alkaline earth salts comprising a mixture of such anions or a mixture of such anions with hydroxyl anions, and b) cation binding resins loaded with one or more 3-valent cations, chosen from 3-valent cations of Al, Ga, In, Fe, Cr, Sc, Y, La and lanthanoides.

A process for treating spent lithium ion batteries to recover metals is disclosed. The process includes discharging the spent lithium ion batteries. The discharged lithium ion batteries are shredded and roasted in a furnace to produce roasted material. The roasted material is sieved to separate a coarser fraction and a finer fraction. The coarser fraction comprises aluminium chips and copper chips. The finer fraction is further treated to recover copper, cobalt, and nickel sequentially with a purity of 99.3-99.9%. The process also recovers manganese as manganese dioxide and lithium as lithium carbonate. The process does not generate any solid waste as all the metals and by-products such as carbon powder and gypsum cake are saleable.

A process for treating spent lithium ion batteries to recover metals is disclosed. The process includes discharging the spent lithium ion batteries. The discharged lithium ion batteries are shredded and roasted in a furnace to produce roasted material. The roasted material is sieved to separate a coarser fraction and a finer fraction. The coarser fraction comprises aluminium chips and copper chips. The finer fraction is further treated to recover copper, cobalt, and nickel sequentially with a purity of 99.3-99.9%. The process also recovers manganese as manganese dioxide and lithium as lithium carbonate. The process does not generate any solid waste as all the metals and by-products such as carbon powder and gypsum cake are saleable.

Integrated recycling method and processes including recycling spent catalyst to produce one or more water-soluble metal salts and one or more water-insoluble tail byproducts, and recycling rechargeable batteries to produce one or more battery-grade metals and one or more pure metallic byproducts, wherein the water insoluble tail byproduct is a feedstock in recycling the rechargeable batteries, the impure metallic byproduct is a feedstock in recycling the spent catalyst, or both.

The alunite ore processing method consists of crushing, grinding and flotation of raw alunite ore. The enriched alunite ore is roasted at 520 to 620 C., the roasting time is 1 to 3 hours. The roasted alunite is leached with 5 to 20% sodium carbonate solution, which is in 100 to 110% of the stoichiometric amount required to bond the SO.sub.3 aluminum sulfate in the alunite with leaching conditions of 70-100 C. for 0.5-2.0 hours. The obtained slurry contains all of the potassium sulfate from the alunite and all of the sodium sulfate obtained from sodium carbonate. In the insoluble residue remains all aluminium oxide and residual rock. The sulfate solution is separated from the insoluble residue and is converted with potassium chloride to potassium sulphate (fertilizer) and kitchen salt. The insoluble residue is treated by the Bayer method without the use of an autoclave and results in aluminium oxide (alumina) and quartz sand.

The alunite ore processing method consists of crushing, grinding and flotation of raw alunite ore. The enriched alunite ore is roasted at 520 to 620 C., the roasting time is 1 to 3 hours. The roasted alunite is leached with 5 to 20% sodium carbonate solution, which is in 100 to 110% of the stoichiometric amount required to bond the SO.sub.3 aluminum sulfate in the alunite with leaching conditions of 70-100 C. for 0.5-2.0 hours. The obtained slurry contains all of the potassium sulfate from the alunite and all of the sodium sulfate obtained from sodium carbonate. In the insoluble residue remains all aluminium oxide and residual rock. The sulfate solution is separated from the insoluble residue and is converted with potassium chloride to potassium sulphate (fertilizer) and kitchen salt. The insoluble residue is treated by the Bayer method without the use of an autoclave and results in aluminium oxide (alumina) and quartz sand.

A granulated material is provided which enables a reduction in the amount of adhesion of the granulated material to a conveyor junction.

A granulated material includes sludge in an amount of greater than 30 mass % and 90 mass % or less and sintered ore powder in an amount of 10 mass % or greater and less than 70 mass %. The granulated material includes granulated particles in which at least a portion of the sludge adheres to at least a portion of the sintered ore powder.

A granulated material is provided which enables a reduction in the amount of adhesion of the granulated material to a conveyor junction.

A granulated material includes sludge in an amount of greater than 30 mass % and 90 mass % or less and sintered ore powder in an amount of 10 mass % or greater and less than 70 mass %. The granulated material includes granulated particles in which at least a portion of the sludge adheres to at least a portion of the sintered ore powder.