There is provided a method for collecting and reusing an active material from positive electrode scrap. The method of reusing a positive electrode active material of the present disclosure includes (a) thermally treating a positive electrode scrap comprising an active material layer on a current collector in air for thermal decomposition of a binder and a conductive material in the active material layer, to separate the current collector from the active material layer, and collecting an active material in the active material layer, (b-1) washing the active material collected from the step (a) with a lithium compound solution which is basic in an aqueous solution, and drying, (b-2) grinding the active material dried from the step (b-1), (b-3) adding a lithium compound to the active material ground from the step (b-2), and (c) annealing the active material having the lithium precursor added thereto, to obtain a reusable active material.

A method of recovering an active material from a positive electrode scrap and reusing the active material is provided. The method of reusing a positive electrode active material includes (a) thermally treating a positive electrode scrap comprising an active material layer on a current collector in air for thermal decomposition of a binder and a conductive material in the active material layer, to separate the current collector from the active material layer, and collecting an active material in the active material layer; (b) washing the active material collected from the step (a) with a cleaning solution; and (c) annealing the active material washed from the step (b) with an addition of a lithium precursor to obtain a reusable active material, wherein a molar ratio of lithium to other metals in the active material after the thermal treatment step (a) or a molar ratio of lithium to other metals in the active material after the washing step (b) has a decreased range of 20% or less when compared with a molar ratio of lithium to other metals in the positive electrode scrap before the thermal treatment step (a).

The present invention lies in the field of pyrometallurgy and discloses a process and a slag suitable for the recovery of Ni and Co from Li-ion batteries or their waste. The slag composition is defined according to:
10%<MnO<40%;
(CaO+1.5*Li.sub.2O)/Al.sub.2O.sub.3>0.3;
CaO+0.8*MnO+0.8*Li.sub.2O<60%;
(CaO+2*Li.sub.2O+0.4*MnO)/SiO.sub.2≥2.0;
Li.sub.2≥1%; and,
Al.sub.2O.sub.3+SiO.sub.2+CaO+Li.sub.2O+MnO+FeO+MgO>85%.
This composition is particularly adapted to limit or avoid the corrosion of furnaces lined with magnesia-bearing refractory bricks.

A method according to an embodiment is for recovering a valuable metal from a waste electrode material of a lithium secondary battery by using lithium carbonate. An anode-cathode mixed electrode material that has been separated by draining, crushing, screening, and sorting a waste lithium secondary battery is preprocessed. A precipitation operation performed by adding lithium carbonate (Li2CO3) to a metal melt acquired by performing sulfuric acid dissolution using sulfuric acid. A valuable metal such as nickel, cobalt, manganese, aluminum, and copper is recovered as a residue in the form of a carbonate composite, and a lithium sulfate (Li2SO4) aqueous solution including lithium is recovered as a filtrate.

The present invention is a method for treating an alloy, by which a solution that contains nickel and/or cobalt is obtained from an alloy that contains copper, zinc, and nickel and/or cobalt, said method comprising: a leaching process wherein a leachate is obtained by subjecting the alloy to a leaching treatment by means of an acid in the coexistence of a sulfurizing agent; a reduction process wherein the leachate is subjected to a reduction treatment with use of a reducing agent; and an ion exchanging process wherein a solution that contains nickel and/or cobalt is obtained by bringing a solution, which has been obtained in the reduction process, into contact with an amino phosphoric acid-based chelate resin, thereby having zinc adsorbed on the amino phosphoric acid-based chelate resin.

A method of making black mass from lithium containing batterie includes the steps of closing a chamber enclosing lithium-containing batteries and injecting nitrogen into the chamber to create an atmosphere sufficiently low in oxygen to prevent explosions and burning of the lithium-containing batteries. The lithium-containing batteries are shredded in the nitrogen atmosphere to produce shredded batteries. The shredded batteries are heated in the nitrogen atmosphere to a temperature sufficient to vaporize electrolyte and plastics from the batteries and produce pyrolyzed fragments. Lithium is present in a water-soluble nitrate form within the pyrolyzed fragments. The pyrolyzed fragments are classified to produce a black mass and a remaining metals fraction. The remaining metals fraction can be further classified to recover ferrous metals, light metals, and heavy metals.

The disclosure relates to a method for producing feedstock in piece form from metal, in particular aluminium and/or aluminium alloys, for a metal-casting installation, in particular aluminium-casting installation, in which scrap parts of metal, in particular of aluminium and/or aluminium alloys, are sorted on the basis of their alloying constituents and/or alloy contents and subsequently, on the basis of an alloy to be produced in the feedstock, the scrap parts are mixed into a composition having a homogeneous distribution of the alloy and fed to a press, in which the scrap parts of the composition are subjected to a pressure that compresses the scrap parts while generating a temperature, wherein, as a result of the application of pressure, the scrap parts are heated up to the transition temperature between solid and liquid of at least some of the scrap parts and/or the alloys and/or alloying constituents thereof before the feedstock is discharged in a specific geometrical form.

There is provided a method for collecting and reusing an active material from positive electrode scrap. The positive electrode active material reuse method of the present disclosure includes (a) thermally treating positive electrode scrap comprising a lithium cobalt oxide positive electrode active material layer on a current collector in air for thermal decomposition of a binder and a conductive material in the active material layer, to separate the current collector from the active material layer, and collecting an active material in the active material layer, (b) washing the collected active material with a lithium compound solution which is basic in an aqueous solution and drying, and (c) annealing the washed active material with an addition of a lithium precursor to obtain a reusable active material.

There is provided a method for collecting and reusing an active material from positive electrode scrap. The positive electrode active material reuse method of the present disclosure includes (a) thermally treating positive electrode scrap comprising a lithium composite transition metal oxide positive electrode active material layer on a current collector in air at 300 to 650° C. for 1 hour or less for thermal decomposition of a binder and a conductive material in the active material layer, to separate the current collector from the active material layer, and collecting an active material in the active material layer, and (b) annealing the collected active material with an addition of a lithium precursor to obtain a reusable active material.

The present invention relates to a method of preparing a precursor material of a positive electrode active material from a waste lithium secondary battery, to a method of preparing a lithium secondary battery positive electrode active material including a precursor material prepared by the same precursor preparation method, and to a lithium secondary battery positive electrode active material prepared by the same positive electrode active material preparation method.