A process for recovering a metal in the form of a metal halide from a metal-containing source is described, the process comprising the steps of: —(i) forming a solid metal halide containing product by contacting the metal-containing source with a gaseous halide in an oxidising environment and at a temperature below the vaporisation temperature of the metal halide of interest; (ii) heating the metal halide containing product formed in step (i) to a temperature at or above the vaporisation temperature of the metal halide to form a gaseous metal halide containing product; and (iii) condensing the gaseous metal halide containing product of step (ii) to recover the metal halide of interest.

The present invention is a method for treating an alloy, by which a solution that contains nickel and/or cobalt is obtained from an alloy that contains copper, zinc, and nickel and/or cobalt, said method comprising: a leaching process wherein a leachate is obtained by subjecting the alloy to a leaching treatment by means of an acid in the coexistence of a sulfurizing agent; a reduction process wherein the leachate is subjected to a reduction treatment with use of a reducing agent; and an ion exchanging process wherein a solution that contains nickel and/or cobalt is obtained by bringing a solution, which has been obtained in the reduction process, into contact with an amino phosphoric acid-based chelate resin, thereby having zinc adsorbed on the amino phosphoric acid-based chelate resin.

A hydrometallurgical method for simultaneously extracting zinc, lead, silver, iron and calcium from electric arc furnace dust (hazardous waste) produced by the steelmaking industry (steelworks), in the form of industrial products: zinc as zinc sulphate or zinc cathodes; lead and silver as a concentrate of lead and silver; iron as reduced elemental iron for return to the electric arc furnace; and, lastly, calcium as gypsum, without solid waste or liquid effluents being generated relates to the chemical nature of the electric arc furnace dust (complex oxides) changes to a sulfide complex, and eliminating the hazards associated with the generation of fugitive heavy-metal salts. In addition, the hydrometallurgical problem of low recovery of zinc and iron is solved. Consequently, hydrometallurgy is made easier and more environmentally friendly, as condensed water is used as a leachate, the condensed water being continuously regenerated by vacuum evaporation systems without generating effluents.

The invention relates to the field of efficient separation and recovery of bromine by full wet method, especially to a two-step separating method of bromide and recovery of lead and zinc from printed circuit board Incineration ash. It mainly includes first sodium hydroxide alkaline leaching, secondary sodium peroxide alkaline leaching, pH adjustment, separate lead and zinc, bromide evaporation and crystallization to recover crude bromide and other steps. Compared with traditional comprehensive recovery process of ash, the invention uses sodium hydroxide to dissolve bromide, lead and zinc, and uses the strong oxidation of sodium peroxide in alkaline environment, copper bromide and other bromine are oxidized and leached; through two-step method, the efficient leaching of bromine, lead and zinc is realized, silver and other precious metals are enriched at the same time. It is beneficial to subsequent recovery of precious metals and has the characteristics of short tail liquid discharge.

An alloy treatment method is provided, in which a solution containing nickel and/or cobalt is obtained from an alloy containing nickel and/or cobalt and also containing copper and zinc, the method comprising: a leaching step for subjecting the alloy to a leaching treatment with an acid under the condition where a sulfating agent is present to produce a leachate; a reduction step for subjecting the leachate to a reduction treatment using a reducing agent to produce a reduced solution; an oxidation/neutralization step for adding an oxidizing agent and a neutralizing agent to the reduced solution to produce a neutralized solution containing nickel and/or cobalt and also containing zinc; and a solvent extraction step for subjecting the neutralized solution to a solvent extraction procedure using an acidic phosphorus compound-based extractant to produce a solution containing nickel and/or cobalt.

Disclosed is a fuming furnace with a lead collecting and discharging function, the fuming furnace comprising a furnace body; the furnace body is provided with a hearth therein and a tuyere thereon; the bottom of the hearth forms a molten pool; the furnace body is further provided with a slag discharging outlet and a lead discharging outlet thereon; the furnace body comprises a furnace bottom water jacket and a hearth water jacket; the furnace bottom water jacket is provided with a refractory brick layer at the inner wall thereof; the refractory brick layer is provided with a lead collecting and discharging channel therein for collecting and discharging lead; the lead collecting and discharging channel is in communication with the lead discharging outlet, and the lead collecting and discharging channel is in communication with the molten pool via joints between the refractory bricks forming the refractory brick layer.

Disclosed is a fuming furnace with a lead collecting and discharging function, the fuming furnace comprising a furnace body; the furnace body is provided with a hearth therein and a tuyere thereon; the bottom of the hearth forms a molten pool; the furnace body is further provided with a slag discharging outlet and a lead discharging outlet thereon; the furnace body comprises a furnace bottom water jacket and a hearth water jacket; the furnace bottom water jacket is provided with a refractory brick layer at the inner wall thereof; the refractory brick layer is provided with a lead collecting and discharging channel therein for collecting and discharging lead; the lead collecting and discharging channel is in communication with the lead discharging outlet, and the lead collecting and discharging channel is in communication with the molten pool via joints between the refractory bricks forming the refractory brick layer.

A method for producing metal zinc by liquid/liquid extraction, comprising leaching of a zinc-bearing solid raw material containing antimony with a slightly acid aqueous solution, at a pH value maintained above 3 and less than or equal to 5, with formation of a suspension, drawing-off from the suspension of an aqueous phase containing zinc in solution to be subject to the extraction, additional leaching of the remaining suspension with an acid aqueous solution, at a pH value maintained below 3.5 and greater than or equal to 1, with formation of a pulp, introduction of a neutralizing agent in this pulp with coprecipitation of antimony and other impurities and separation from this neutralized pulp of a zinc-bearing aqueous solution which is recycled to the step for leaching the zinc-bearing solid raw material.

A method for producing metal zinc by liquid/liquid extraction, comprising leaching of a zinc-bearing solid raw material containing antimony with a slightly acid aqueous solution, at a pH value maintained above 3 and less than or equal to 5, with formation of a suspension, drawing-off from the suspension of an aqueous phase containing zinc in solution to be subject to the extraction, additional leaching of the remaining suspension with an acid aqueous solution, at a pH value maintained below 3.5 and greater than or equal to 1, with formation of a pulp, introduction of a neutralizing agent in this pulp with coprecipitation of antimony and other impurities and separation from this neutralized pulp of a zinc-bearing aqueous solution which is recycled to the step for leaching the zinc-bearing solid raw material.

A variety of systems, methods and compositions are disclosed, including, in one method for recycling a spent alkaline battery comprising: dissolving insoluble metal ions in aqueous solution thereby producing pregnant leach solution; extracting zinc sulfate from aqueous solution thereby producing zinc sulfate product and raffinate solution comprising manganese sulfate and potassium sulfate; separating manganese hydroxide from raffinate solution thereby producing manganese sulfate product and aqueous potassium sulfate solution; crystallizing aqueous potassium sulfate solution to produce solid potassium sulfate product. A system for recycling spent alkaline battery comprising: first liquid-solid extraction unit capable of dissolving insoluble metal ions in aqueous solution thereby producing pregnant leach solution; liquid-liquid extraction unit capable of extracting zinc from pregnant leach solution; second liquid-solid extraction unit capable of precipitating manganese hydroxide from raffinate produced by liquid-liquid extraction unit; and third liquid-solid extraction unit capable of crystallizing aqueous potassium sulfate solution produced by second liquid-solid extraction unit.