In the production of an internal-tin-processed Nb.sub.3Sn superconducting wire, the present invention provides a Nb.sub.3Sn superconducting wire that is abundant in functionality, such as, the promotion of formation of a Nb.sub.3Sn layer, the mechanical strength of the superconducting filament (and an increase in interface resistance), the higher critical temperature (magnetic field), and the grain size reduction, and a method for producing it. A method for producing a Nb.sub.3Sn superconducting wire according to an embodiment of the present invention includes a step of providing a bar 10 that has a Sn insertion hole 12 provided in a central portion of the bar 10 and a plurality of Nb insertion holes 14 provided discretely along an outer peripheral surface of the Sn insertion hole 12, and that has an alloy composition being Cu-xZn-yM (x: 0.1 to 40 mass %, M=Ge, Ga, Mg, or Al, provided that, for Mg, x: 0 to 40 mass %), a step of mounting an alloy bar with an alloy composition of Sn-zQ (Q=Ti, Zr, or Hf) into the Sn insertion hole 12 and inserting Nb cores into the Nb insertion holes 14, a step of subjecting the bar 10 to diameter reduction processing to fabricate a Cu-xZn-yM/Nb/Sn-zQ composite multicore wire with a prescribed outer diameter, and a step of subjecting the composite multicore wire to Nb.sub.3Sn phase generation heat treatment.

In the production of an internal-tin-processed Nb.sub.3Sn superconducting wire, the present invention provides a Nb.sub.3Sn superconducting wire that is abundant in functionality, such as, the promotion of formation of a Nb.sub.3Sn layer, the mechanical strength of the superconducting filament (and an increase in interface resistance), the higher critical temperature (magnetic field), and the grain size reduction, and a method for producing it. A method for producing a Nb.sub.3Sn superconducting wire according to an embodiment of the present invention includes a step of providing a bar 10 that has a Sn insertion hole 12 provided in a central portion of the bar 10 and a plurality of Nb insertion holes 14 provided discretely along an outer peripheral surface of the Sn insertion hole 12, and that has an alloy composition being Cu-xZn-yM (x: 0.1 to 40 mass %, M=Ge, Ga, Mg, or Al, provided that, for Mg, x: 0 to 40 mass %), a step of mounting an alloy bar with an alloy composition of Sn-zQ (Q=Ti, Zr, or Hf) into the Sn insertion hole 12 and inserting Nb cores into the Nb insertion holes 14, a step of subjecting the bar 10 to diameter reduction processing to fabricate a Cu-xZn-yM/Nb/Sn-zQ composite multicore wire with a prescribed outer diameter, and a step of subjecting the composite multicore wire to Nb.sub.3Sn phase generation heat treatment.

A watch case (6) including a rotating bezel (1), a middle (3) and a connecting spring (2) between the rotating bezel (1) and the middle (3), the connecting spring (2) being accommodated within a first groove (7) formed in an external wall (3a) of the middle (3) and within a second groove (8) formed in an internal wall (1 a) of the rotating bezel (1), the first and second grooves (7,8) being preferably arranged opposite one another. The connecting spring (2) is made of an alloy with memory of shape.

A watch case (6) including a rotating bezel (1), a middle (3) and a connecting spring (2) between the rotating bezel (1) and the middle (3), the connecting spring (2) being accommodated within a first groove (7) formed in an external wall (3a) of the middle (3) and within a second groove (8) formed in an internal wall (1 a) of the rotating bezel (1), the first and second grooves (7,8) being preferably arranged opposite one another. The connecting spring (2) is made of an alloy with memory of shape.

The invention relates to a copper alloy having the following composition (in % by weight): from 10.6 to 18% of Al, from 10.5 to 14.5% of Ni, optionally up to 2% of Fe, optionally up to 1% of Co, optionally up to 0.5% of Ti, optionally up to 0.5% of Mn, optionally up to 0.15% of B, optionally up to 0.1% of Ca, optionally up to 0.1% of C,

a balance copper and unavoidable impurities. Nickel aluminides of the NiAl type are embedded as precipitates in the microstructure of the alloy. The invention further relates to a number of uses of this copper alloy.

A metal matrix self-lubricating composite and a manufacturing method therefor. The metal matrix self-lubricating composite comprises a metal matrix and a mixture layer compounded on a surface of the metal matrix, the mixed layer comprising a copper alloy and a self-lubricating material. The method for manufacturing the metal matrix self-lubricating composite comprises the following steps: a) sintering copper alloy powder on a surface of a metal matrix to form a copper alloy layer on the surface of the metal matrix; b) blade-coating or dip-coating a lubricating material on a surface of the copper alloy layer, and performing vacuumization to obtain a metal plate, and drying the metal plate; c) repeating step b) for multiple times; and d) sintering the metal plate obtained in step c) to obtain the metal matrix self-lubricating composite. In the present invention, a vacuumization mode is used and vacuumization operations are repeated, so that a dense mixture layer on which a self-lubricating material is dispersed on a copper alloy is formed, and the metal matrix self-lubricating composite has good lubricity and abrasion resistance.

A metal matrix self-lubricating composite and a manufacturing method therefor. The metal matrix self-lubricating composite comprises a metal matrix and a mixture layer compounded on a surface of the metal matrix, the mixed layer comprising a copper alloy and a self-lubricating material. The method for manufacturing the metal matrix self-lubricating composite comprises the following steps: a) sintering copper alloy powder on a surface of a metal matrix to form a copper alloy layer on the surface of the metal matrix; b) blade-coating or dip-coating a lubricating material on a surface of the copper alloy layer, and performing vacuumization to obtain a metal plate, and drying the metal plate; c) repeating step b) for multiple times; and d) sintering the metal plate obtained in step c) to obtain the metal matrix self-lubricating composite. In the present invention, a vacuumization mode is used and vacuumization operations are repeated, so that a dense mixture layer on which a self-lubricating material is dispersed on a copper alloy is formed, and the metal matrix self-lubricating composite has good lubricity and abrasion resistance.

Provided is a copper alloy sputtering target, wherein, based on charged particle activation analysis, the copper alloy sputtering target has an oxygen content of 0.6 wtppm or less, or an oxygen content of 2 wtppm or less and a carbon content of 0.6 wtppm or less. Additionally provided is a method for manufacturing a copper alloy sputtering target, wherein a copper raw material is melted in a vacuum or an inert gas atmosphere, a reducing gas is thereafter introduced into the melting atmosphere, an alloy element is subsequently added to a molten metal for alloying, and an obtained ingot is processed into a target shape. The present invention aims to provide a copper alloy sputtering target that generates few particles during sputtering, and a method for manufacturing such a sputtering target.

Provided is a copper alloy sputtering target, wherein, based on charged particle activation analysis, the copper alloy sputtering target has an oxygen content of 0.6 wtppm or less, or an oxygen content of 2 wtppm or less and a carbon content of 0.6 wtppm or less. Additionally provided is a method for manufacturing a copper alloy sputtering target, wherein a copper raw material is melted in a vacuum or an inert gas atmosphere, a reducing gas is thereafter introduced into the melting atmosphere, an alloy element is subsequently added to a molten metal for alloying, and an obtained ingot is processed into a target shape. The present invention aims to provide a copper alloy sputtering target that generates few particles during sputtering, and a method for manufacturing such a sputtering target.

Copper alloys exhibiting enhanced oxidation resistance are provided by adding an amount of sulfur that is effective to enhance oxidative resistance. Such sulfur addition can be achieved by combining elemental forms of copper and sulfur and heating the mixture to form a molten alloy, or by forming a sulfur-rich pre-mix that is added to a base alloy composition. Forming a pre-mix provides improved homogeneity and distribution of the sulfur predominantly in the form of a metal sulfide.