A spheroidal graphite cast iron meeting N.sub.(5-)≥250, N.sub.5-20)/N.sub.(5-)≥0.6, and N.sub.(30-)/N.sub.(5-)≤0.2, wherein N.sub.(5-) represents the number (/mm.sup.2) of graphite particles having equivalent-circle diameters of 5 μm or more, N.sub.(5-20) represents the number (/mm.sup.2) of graphite particles having equivalent-circle diameters of 5 μm or more and less than 20 μm, and N.sub.(30-) represents the number (/mm.sup.2) of graphite particles having equivalent-circle diameters of 30 μm or more, among graphite particles observed in an arbitrary cross section of at least 1 mm.sup.2.

The present invention relates to the technological field of cast iron alloys for automotive and similar applications. Problem to be solved: Presently, structural parts of internal combustion engines are made of gray cast iron alloys that rarely have a tensile strength limit range greater than 350 MPa or vermicular cast iron alloys that do not remain stable at high temperatures. Solution of the problem: It is disclosed a vermicular cast iron alloy that, due to the addition of amounts of Molybdenum, Copper and Tin, with Hot Resistance Factor from 0.5 to 1.7% (HRF=3×(% Mo)+1×(% Sn)+0.25×(% Cu)) achieves a tensile strength limit of 500 to 550 MPa at room temperature and up to 300° C., and a tensile strength limit of 430 to 450 MPa at 400° C.

The present invention relates to the technological field of cast iron alloys for automotive and similar applications. Problem to be solved: Presently, structural parts of internal combustion engines are made of gray cast iron alloys that rarely have a tensile strength limit range greater than 350 MPa or vermicular cast iron alloys that do not remain stable at high temperatures. Solution of the problem: It is disclosed a vermicular cast iron alloy that, due to the addition of amounts of Molybdenum, Copper and Tin, with Hot Resistance Factor from 0.5 to 1.7% (HRF=3×(% Mo)+1×(% Sn)+0.25×(% Cu)) achieves a tensile strength limit of 500 to 550 MPa at room temperature and up to 300° C., and a tensile strength limit of 430 to 450 MPa at 400° C.

The invention consists of a gray cast iron comprising carbon, silicon, vanadium, manganese, nickel, chromium, molybdenum, copper, sulfur, phosphorous, tin and titanium, wherein: the percentage by weight of carbon is from 3.70 to 3.90%; the percentage by weight of silicon is from 1.30 to 2.10%; the percentage by weight of vanadium is from 0.10 to 0.15%; the percentage by weight of manganese is from 0.60 to 0.90%; the percentage by weight of nickel is from 0.05 to 0.50%; the percentage by weight of chromium is from 0.20 to 0.35%; the percentage by weight of molybdenum is no more than 0.10%; the percentage by weight of copper is no more than 0.35%; the percentage by weight of sulfur is less than 0.10%; the percentage by weight of phosphorous is less than 0.10%; the percentage by weight of tin is less than 0.10%; the percentage by weight of titanium is no more than 0.01%; the remainder by weight being iron.

The invention consists of a gray cast iron comprising carbon, silicon, vanadium, manganese, nickel, chromium, molybdenum, copper, sulfur, phosphorous, tin and titanium, wherein: the percentage by weight of carbon is from 3.70 to 3.90%; the percentage by weight of silicon is from 1.30 to 2.10%; the percentage by weight of vanadium is from 0.10 to 0.15%; the percentage by weight of manganese is from 0.60 to 0.90%; the percentage by weight of nickel is from 0.05 to 0.50%; the percentage by weight of chromium is from 0.20 to 0.35%; the percentage by weight of molybdenum is no more than 0.10%; the percentage by weight of copper is no more than 0.35%; the percentage by weight of sulfur is less than 0.10%; the percentage by weight of phosphorous is less than 0.10%; the percentage by weight of tin is less than 0.10%; the percentage by weight of titanium is no more than 0.01%; the remainder by weight being iron.

A diesel engine piston is cast in one piece and consists of almost fully pearlitic cast iron with spheroidal graphite as the piston material. Such a piston is used for “light vehicle” diesel engines, “heavy duty” diesel engines and “large bore” diesel engines.

A spheroidal graphite cast iron having a chemical composition of: C: 3.0% to 4.0%, Si: 2.0% to 2.4%, Cu: 0.20% to 0.50%, Mn: 0.15% to 0.35%, S: 0.005% to 0.030%, Mg: 0.03% to 0.06%, each by mass, and the balance being Fe and inevitable impurities, where Mn and Cu are contained at 0.45% to 0.75% in total; and a structure in which a ferrite layer encloses spheroidal graphite crystallized out in a matrix of pearlite. Part of the pearlite is extended from the matrix side to the spheroidal graphite side to divide the ferrite layer at one or more areas.

A centrifugally cast composite roll for rolling comprising an outer layer and an inner layer, which are integrally fused to each other, the outer layer being made of an Fe-based alloy comprising by mass 1.70-2.70% of C, 0.3-3% of Si, 0.1-3% of Mn, 1.1-3.0% of Ni, 4.0-10% of Cr, 2.0-7.5% of Mo, 3-6.0% of V, 0.1-2% of W, 0.2-2% of Nb, 0.01-0.2% of B, and 0.01-0.1% of N, the balance being Fe and inevitable impurities, and the inner layer being made of ductile cast iron.

The present invention provides a casting method and cast product of spherical graphite cast iron, in which, even with a small modulus, there is no chill, the spherical graphite in the tissue is further made ultrafine, the dispersion of the particle diameter is small, and the number of the particles is several times that of the conventional one in the as cast state where heat treatment is not carried out.

A casting method of a spherical graphite cast iron comprised from, a melting process, a spheroidizing treatment process, an inoculation process, and a casting process, in which the original molten metal after the inoculation process is poured and filled up to a product space through a gate of a metal mold; wherein the original molten metal before being filled up to the product space is controlled to a semi-solidification temperature range. An amount of nitrogen at the time of melting of the (cast iron?) is controlled to 0.9 ppm (mass) or less. The casting process is carried out by controlling the pouring temperature and the heat removal amount from the molten metal so that the temperature of the raw material when passing through the gate becomes a substantially constant temperature between an eutectic temperature and a liquidus temperature.

The present invention provides a die-cast product producing method and a spheroidizing agent of a spherical graphite cast iron with ultrafine spherical graphite by simple method and good reproducibility.

The present invention provides a sand mold producing method and a spheroidizing agent capable of producing an ultrafine spherical graphite cast iron with good reproducibility even in a sand mold thin walled spherical graphite cast iron, which has solidification cooling conditions equivalent to those of a metal mold.

The present invention provides a producing method of a die-cast product of a spherical graphite cast iron using a spheroidizing agent, in which a C amount is 0.5 mass % or more, a total nitrogen amount N is 150 ppm (by mass) or less, and a nitrogen amount generated during melting is 15 ppm (by mass) or less, in a producing method of a sand mold cast product of a thin walled spherical graphite cast iron having a melting process, a spheroidizing process, an inoculation process, and a casting process.