The present disclosure provides methods of preparing heterostructures of a carbon-based structure and a metal oxide structure. Also provided are heterostructures formed via the methods described herein and devices comprising such heterostructures.

Provided is a low-density clad steel sheet having excellent formability and fatigue properties, including a base material; and cladding materials provided on both side surfaces of the base material, wherein the base material is a lightweight steel sheet including, by weight, C: 0.3 to 1.0%, Mn: 4.0 to 16.0%, Al: 4.5 to 9.0%, and a remainder of Fe and inevitable impurities, and each of the cladding materials is martensitic carbon steel including, by weight, C: 0.1 to 0.45%, Mn: 1.0 to 3.0%, and a remainder of Fe and inevitable impurities.

Provided is a low-density clad steel sheet having excellent formability and fatigue properties, including a base material; and cladding materials provided on both side surfaces of the base material, wherein the base material is a lightweight steel sheet including, by weight, C: 0.3 to 1.0%, Mn: 4.0 to 16.0%, Al: 4.5 to 9.0%, and a remainder of Fe and inevitable impurities, and each of the cladding materials is martensitic carbon steel including, by weight, C: 0.1 to 0.45%, Mn: 1.0 to 3.0%, and a remainder of Fe and inevitable impurities.

A steel sheet with a metallic coating is provided. A composition of the metallic coating includes from 2.0 to 24.0% by weight of zinc, from 7.1 to 12.0% by weight of silicon, optionally from 1.1 to 8.0% by weight of magnesium, and optionally additional elements chosen from Pb, Ni, Zr, or Hf. The content by weight of each additional element is less than 0.3%. A balance of the composition is aluminum, unavoidable impurities and residual elements. A ratio Al/Zn is from 4.0 to 6.0.

A steel sheet with a metallic coating is provided. A composition of the metallic coating includes from 2.0 to 24.0% by weight of zinc, from 7.1 to 12.0% by weight of silicon, optionally from 1.1 to 8.0% by weight of magnesium, and optionally additional elements chosen from Pb, Ni, Zr, or Hf. The content by weight of each additional element is less than 0.3%. A balance of the composition is aluminum, unavoidable impurities and residual elements. A ratio Al/Zn is from 4.0 to 6.0.

An ingot, having a volume between 0.15 m.sup.3 and 0.80 m.sup.3 and a surface area to volume ratio between 10 m.sup.−1 and 18 m.sup.−1, made of at least one metal, having longitudinal faces extending between two end faces and including at least one hole extending from one of the longitudinal faces, the maximum distance between any point of the hole periphery, to its closest longitudinal face, noted MaxL, the at least one hole being configured such that said maximum distance MaxL is smaller than the minimal distance, noted MinE, between any point of the hole periphery and its closest end face.

An ingot, having a volume between 0.15 m.sup.3 and 0.80 m.sup.3 and a surface area to volume ratio between 10 m.sup.−1 and 18 m.sup.−1, made of at least one metal, having longitudinal faces extending between two end faces and including at least one hole extending from one of the longitudinal faces, the maximum distance between any point of the hole periphery, to its closest longitudinal face, noted MaxL, the at least one hole being configured such that said maximum distance MaxL is smaller than the minimal distance, noted MinE, between any point of the hole periphery and its closest end face.

A method of extending the corrosion resistance of a ground anchoring region of a steel or alloy fence or trellis post already having a sacrificial coating or non-sacrificial coating along an entire length of the fence or trellis post, said method including the step of applying at least one additional coating to the ground anchoring region so as to extend the corrosion resistance of the ground anchoring region. The at least one additional coating can be a sacrificial coating and/or non-sacrificial coating.

A metallic component includes a core formed of steel. A zinc alloy layer is disposed on the core. The zinc alloy layer is formed of zinc and a very small amount of aluminum, such as 0.14 weight percent or less. A method of creating a component includes providing a steel core, providing a zinc bath consisting of essentially of 0.01 to 0.14 weight percent aluminum, and hot dipping the steel core into the zinc bath to form a zinc coating on the steel core resulting in a zinc-coated steel component. The aluminum may be provided in even lower contents, such as less than 0.08 weight percent, or even less than 0.05 weight percent. The zinc-coated steel component may then be spot welded to another component without first annealing the zinc-coated component. Rather, heat treating is performed locally at the weld joint by the welding procedure alone.

A metallic component includes a core formed of steel. A zinc alloy layer is disposed on the core. The zinc alloy layer is formed of zinc and a very small amount of aluminum, such as 0.14 weight percent or less. A method of creating a component includes providing a steel core, providing a zinc bath consisting of essentially of 0.01 to 0.14 weight percent aluminum, and hot dipping the steel core into the zinc bath to form a zinc coating on the steel core resulting in a zinc-coated steel component. The aluminum may be provided in even lower contents, such as less than 0.08 weight percent, or even less than 0.05 weight percent. The zinc-coated steel component may then be spot welded to another component without first annealing the zinc-coated component. Rather, heat treating is performed locally at the weld joint by the welding procedure alone.