A method of inhibiting corrosion of metal surfaces of piping, tubing, heat exchangers and other metal equipment during acid stimulation of an oil and gas well is provided. The method includes introduction of an acidic treatment fluid containing an inorganic acid and a corrosion inhibitor of formula I into the oil and gas well.

An inhibition corrosion package for use with an acidic composition, where the package comprises a terpene component; a propargyl alcohol or derivative thereof; at least one amphoteric surfactant; and a solvent. Also disclosed are acidic compositions combining the corrosion inhibition package according to a preferred embodiment of the present invention for use in various industrial operations including but not limited to oil and gas operations. Also disclosed are methods of use of such compositions.

An inhibition corrosion package for use with an acidic composition, where the package comprises a terpene component; a propargyl alcohol or derivative thereof; at least one amphoteric surfactant; and a solvent. Also disclosed are acidic compositions combining the corrosion inhibition package according to a preferred embodiment of the present invention for use in various industrial operations including but not limited to oil and gas operations. Also disclosed are methods of use of such compositions.

A method for reducing or preventing corrosion or fouling in an apparatus for carrying out a chemical process, where corrosion or fouling is caused by acidic compounds present in the chemical process, which comprises the addition of at least one quaternary ammonium hydroxide of the formula (I) to the apparatus, wherein the chemical process is carried out: [Chem. 1] where R.sup.1, R.sup.2, R.sup.3 are each independently C.sub.1-C.sub.10 alkyl; R.sup.4 is inter alia C.sub.1-C.sub.18 alkyl, benzyl, monocycloalkyl having 5, 6, 7 or 8 carbon atoms, bicycloalkyl having 6 to 8 carbon atoms, tricycloalkyl having 7 to 10 carbon atoms, where monocycloalkyl, bicycloalkyl and tricycloalkyl are unsubstituted or substituted by 1 or 2 methyl groups, or tri-C.sub.1-C.sub.4 alkyl ammonium groups. R.sup.1 and R.sup.2 together with the nitrogen atom may also form a 5 or 6-membered, saturated nitrogen heterocycle, which is unsubstituted or carries 1 or 2 methyl groups; and/or R.sup.3 and R.sup.4 together with the nitrogen atom may also form a 5 or 6-membered, saturated nitrogen heterocycle, which is unsubstituted or carries 1 or 2 methyl groups.

A method for reducing or preventing corrosion or fouling in an apparatus for carrying out a chemical process, where corrosion or fouling is caused by acidic compounds present in the chemical process, which comprises the addition of at least one quaternary ammonium hydroxide of the formula (I) to the apparatus, wherein the chemical process is carried out: [Chem. 1] where R.sup.1, R.sup.2, R.sup.3 are each independently C.sub.1-C.sub.10 alkyl; R.sup.4 is inter alia C.sub.1-C.sub.18 alkyl, benzyl, monocycloalkyl having 5, 6, 7 or 8 carbon atoms, bicycloalkyl having 6 to 8 carbon atoms, tricycloalkyl having 7 to 10 carbon atoms, where monocycloalkyl, bicycloalkyl and tricycloalkyl are unsubstituted or substituted by 1 or 2 methyl groups, or tri-C.sub.1-C.sub.4 alkyl ammonium groups. R.sup.1 and R.sup.2 together with the nitrogen atom may also form a 5 or 6-membered, saturated nitrogen heterocycle, which is unsubstituted or carries 1 or 2 methyl groups; and/or R.sup.3 and R.sup.4 together with the nitrogen atom may also form a 5 or 6-membered, saturated nitrogen heterocycle, which is unsubstituted or carries 1 or 2 methyl groups.

A method of inhibiting corrosion of metal during acid stimulation of an oil and gas well, whereby the oil and gas well is treated with an acidic treatment fluid containing 10 to 28 wt. % of an acid and 0.001 to 0.045 wt. % of a corrosion inhibitor of formula I, each based on a total weight of the acidic treatment fluid,

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wherein R.sup.1 to R.sup.5 are independently hydrogen, an optionally substituted alkyl, an optionally substituted aryl, an optionally substituted alkoxy, an optionally substituted alkanoyloxy, a carboxy, an optionally substituted alkoxycarbonyl, a hydroxy, a halo, a nitro, a cyano, or wherein two of these adjacent substituents represented by R.sup.1 to R.sup.5, together form a methylene dioxy group.

Corrosion inhibitor compositions for reducing the corrosive effect of acidic environments on metallic substrates are provided herein. In particular, the present disclosure describes corrosion inhibitor compositions comprising a condensation product of a trifunctional amine and a fatty acid. The present disclosure also describes methods of preparing and of using such corrosion inhibitor compositions.

Aspects described herein generally relate to a method of coating a metallic surface. The method includes forming a solution including a corrosion inhibitor having one or more thiol moieties and a hydroxide. The metallic surface is coated with the solution to form a treated metallic surface. The treated metallic surface is further coated with an organosilane, an acid, and a metal alkoxide to form a coating system.

Aspects described herein generally relate to a method of coating a metallic surface. The method includes forming a solution including a corrosion inhibitor having one or more thiol moieties and a hydroxide. The metallic surface is coated with the solution to form a treated metallic surface. The treated metallic surface is further coated with an organosilane, an acid, and a metal alkoxide to form a coating system.

A method for the fracking or stimulation of a hydrocarbon-bearing formation, said method comprising the steps of: providing a wellbore in need of stimulation; inserting a plug in the wellbore at a predetermined location; inserting a perforating tool and a spearhead or breakdown acid into the wellbore; positioning the tool at said predetermined location; perforating the wellbore with the tool thereby creating a perforated area; allowing the spearhead acid to come into contact with the perforated area for a predetermined period of time sufficient to prepare the formation for fracking or stimulation; removing the tool from the wellbore; and initiating the fracking of the perforated area using a fracking fluid. Also disclosed is a corrosion inhibiting composition for use with the acid composition.