The present disclosure provides a high-power unipolar water electrolysis plant including a rectifier, a first U-bank, and a second U-bank electrically connected in series to the rectifier and to the first U-bank. Each U-bank is formed by a pair of adjacent, longitudinal cell arrays electrically connected to each other. The cell arrays are arranged in a spaced apart, side-by-side arrangement with a service corridor defined therebetween to allow sectional maintenance to be performed on each cell array. Each cell array has a plurality of unipolar water electrolyser cells. Each U-bank has input conduits for delivering water and cooling water to each cell array, output conduits for carrying hydrogen gas, oxygen gas and cooling water away from each cell array. The high-power unipolar water electrolysis plant includes a first jumper and a second jumper to isolate the U-bank, an electrical bypass busbar extension and a third jumper to bypass the U-bank.

Herein discussed is a method of producing hydrogen or carbon monoxide comprising introducing a waste gas having a total combustible species (TCS) content of no greater than 60 vol % into an electrochemical (EC) reactor, wherein the EC reactor comprises a mixed-conducting membrane, wherein the membrane comprises an electronically conducting phase and an ionically conducting phase. Also disclosed herein is an integrated hydrogen production system comprising a waste gas source and an electrochemical (EC) reactor comprising a mixed-conducting membrane, wherein the membrane comprises an electronically conducting phase and an ionically conducting phase, wherein the waste gas source is configured to send its exhaust to the EC reactor, wherein the exhaust has a total combustible species (TCS) content of no greater than 60 vol %.

Herein discussed is a method of producing hydrogen or carbon monoxide comprising introducing a waste gas having a total combustible species (TCS) content of no greater than 60 vol % into an electrochemical (EC) reactor, wherein the EC reactor comprises a mixed-conducting membrane, wherein the membrane comprises an electronically conducting phase and an ionically conducting phase. Also disclosed herein is an integrated hydrogen production system comprising a waste gas source and an electrochemical (EC) reactor comprising a mixed-conducting membrane, wherein the membrane comprises an electronically conducting phase and an ionically conducting phase, wherein the waste gas source is configured to send its exhaust to the EC reactor, wherein the exhaust has a total combustible species (TCS) content of no greater than 60 vol %.

A method and apparatus for producing hydrogen gas whereby a nanobubble generator introduces nanobubbles at a concentration of at least 10.sup.7 nanobubbles per cm.sup.3 into an electrolytic cell comprising a pair of electrodes and a hydrogen-containing, electrolyzable liquid, and the electrolytic cell is operated to produce hydrogen gas.

A method and apparatus for producing hydrogen gas whereby a nanobubble generator introduces nanobubbles at a concentration of at least 10.sup.7 nanobubbles per cm.sup.3 into an electrolytic cell comprising a pair of electrodes and a hydrogen-containing, electrolyzable liquid, and the electrolytic cell is operated to produce hydrogen gas.

A low carbon footprint material is used to decrease the carbon dioxide emission for production of a high carbon footprint substance. A method of forming composite materials comprises providing a first high carbon footprint substance; providing a carbon nanomaterial produced with a carbon-footprint of less than 10 unit weight of carbon dioxide (CO.sub.2) emission during production of 1 unit weight of the carbon nanomaterial; and forming a composite comprising the high carbon footprint substance and from 0.001 wt % to 25 wt % of the carbon nanomaterial, wherein the carbon nanomaterial is homogeneously dispersed in the composite to reduce the carbon dioxide emission for producing the composite material relative to the high carbon footprint substance.

A low carbon footprint material is used to decrease the carbon dioxide emission for production of a high carbon footprint substance. A method of forming composite materials comprises providing a first high carbon footprint substance; providing a carbon nanomaterial produced with a carbon-footprint of less than 10 unit weight of carbon dioxide (CO.sub.2) emission during production of 1 unit weight of the carbon nanomaterial; and forming a composite comprising the high carbon footprint substance and from 0.001 wt % to 25 wt % of the carbon nanomaterial, wherein the carbon nanomaterial is homogeneously dispersed in the composite to reduce the carbon dioxide emission for producing the composite material relative to the high carbon footprint substance.

The present disclosure provides a high-power unipolar water electrolysis plant including a rectifier, a first U-bank, and a second U-bank electrically connected in series to the rectifier and to the first U-bank. Each U-bank is formed by a pair of adjacent, longitudinal cell arrays electrically connected to each other. The cell arrays are arranged in a spaced apart, side-by-side arrangement with a service corridor defined therebetween to allow sectional maintenance to be performed on each cell array. Each cell array has a plurality of unipolar water electrolyser cells. Each U-bank has input conduits for delivering water and cooling water to each cell array, output conduits for carrying hydrogen gas, oxygen gas and cooling water away from each cell array. The high-power unipolar water electrolysis plant includes a first jumper and a second jumper to isolate the U-bank, an electrical bypass busbar extension and a third jumper to bypass the U-bank.

The present disclosure provides a high-power unipolar water electrolysis plant including a rectifier, a first U-bank, and a second U-bank electrically connected in series to the rectifier and to the first U-bank. Each U-bank is formed by a pair of adjacent, longitudinal cell arrays electrically connected to each other. The cell arrays are arranged in a spaced apart, side-by-side arrangement with a service corridor defined therebetween to allow sectional maintenance to be performed on each cell array. Each cell array has a plurality of unipolar water electrolyser cells. Each U-bank has input conduits for delivering water and cooling water to each cell array, output conduits for carrying hydrogen gas, oxygen gas and cooling water away from each cell array. The high-power unipolar water electrolysis plant includes a first jumper and a second jumper to isolate the U-bank, an electrical bypass busbar extension and a third jumper to bypass the U-bank.

Provided are methods of forming active materials for electrochemical cells using low-temperature electrochemical deposition, e.g., less than 200° C. Specifically, these processes allow precise control of the morphology, composition, and size of deposited structures. For example, the deposited structure may be doped, alloyed, or surface treated during their deposition using a combination of different precursors. In particular, silicon structure may be pre-lithiated while these structures are being formed. The selection of working electrodes (surface size and properties), electrolyte composition, and other parameters result in different types of structures, e.g., precipitating from the electrolyte or deposited on the electrode. Low-temperature plating does not require a lot of energy and volatile and invisible precursors. Furthermore, this plating produces a more confined waste stream, suitable for post-reaction recycling. Finally, low-temperature electrochemical deposition can be readily scaled up such that plating bathes and electrode sizes can be chosen to fit the production requirements.