Provided are methods of making aliphatic or aromatic compounds (e.g., small molecules or polymers) having one or more amine groups and/or imine groups. A method of the present disclosure is an electrohydrogenation method, where a potential is applied to an aliphatic or aromatic compound (e.g., small molecule or polymer) having one or more nitrile groups, where after the potential is applied one or more of the nitrile groups are reduced to an amine or imine. The electrohydrogenation may be carried out using non-pulsed or pulsed potential waveforms.

The present disclosure provides methods for the chemical degradation of polymers, in particular to methods for the degradation of polyesters by electrochemical processes.

The present disclosure provides methods for the chemical degradation of polymers, in particular to methods for the degradation of polyesters by electrochemical processes.

Provided are methods of making aliphatic or aromatic compounds (e.g., small molecules or polymers) having one or more amine groups and/or imine groups. A method of the present disclosure is an electrohydrogenation method, where a potential is applied to an aliphatic or aromatic compound (e.g., small molecule or polymer) having one or more nitrile groups, where after the potential is applied one or more of the nitrile groups are reduced to an amine or imine. The electrohydrogenation may be carried out using non-pulsed or pulsed potential waveforms.

Provided are methods of making aliphatic or aromatic compounds (e.g., small molecules or polymers) having one or more amine groups and/or imine groups. A method of the present disclosure is an electrohydrogenation method, where a potential is applied to an aliphatic or aromatic compound (e.g., small molecule or polymer) having one or more nitrile groups, where after the potential is applied one or more of the nitrile groups are reduced to an amine or imine. The electrohydrogenation may be carried out using non-pulsed or pulsed potential waveforms.

An electrochemical cell includes: a cathode having a first catalyst that reduces carbon dioxide to carbon monoxide; an anode; an electrolyte solution containing a reactant and an electrolyte; and a second catalyst that synthesizes a carbonyl compound from the carbon monoxide and the reactant.

A novel polymers production process, often with fuels/chemicals as by-products. The invention consists of device, addition polymerization, condensation polymerization, process with piping, control and procedure. The device is a mechanical design to continuously remove solid deposit, conductive or not, on electrode surface. Besides overcoming the limitation of electrochemical polymer production where the products blocks the electrode from further operation, the device provides cheaper operation for electrometallurgy to harvest the valuable metals formed on electrode. The novel process allows retrofitting conventional polymer production process by replacing conventional reactor with electrochemical reactor, for low-cost rapid implementation. The novel reactions consist of addition reaction to produce addition polymers; and intermolecular reaction to produce classes of condensation polymers. The clusters of invention enable valuable polymers and chemicals to be produced at low cost for milder conditions and cheaper equipment, while allowing utilization of alternative feedstock especially chemical wastes, for further environmental and economic benefits.

Embodiments of the present invention may provide methods and systems for enhancing bioreactivity of carbonaceous geological material (11) which may include adding carbonaceous geological material to an electrochemical treatment (18) and creating acidic and basic pH levels, peroxides, and radicals (5) which can increase biochemical reactivity, bioavailability, and water solubility of the carbonaceous geological material to provide a reactive carbonaceous geological material (14).

Embodiments of the present invention may provide methods and systems for enhancing bioreactivity of carbonaceous geological material (11) which may include adding carbonaceous geological material to an electrochemical treatment (18) and creating acidic and basic pH levels, peroxides, and radicals (5) which can increase biochemical reactivity, bioavailability, and water solubility of the carbonaceous geological material to provide a reactive carbonaceous geological material (14).

The disclosure relates to a plant, in particular power plant, for maintaining and/or balancing a predetermined carbon dioxide/oxygen ratio in atmospheric air, in particular for improving atmospheric air quality, including at least one electrolysis unit for oxygen production, connected to at least one water supply line for receiving a quantity of water and adapted to separate a received quantity of water by electrolysis into a partial quantity of oxygen and a partial quantity of hydrogen; at least one hydrogen transport unit adapted to provide the partial quantity of hydrogen for storage and/or further processing at least one carbon dioxide absorption unit for purifying ambient air of an outside atmosphere surrounding the plant, including at least one air inlet for supplying the ambient air and at least one downstream absorber unit adapted to extract a quantity of carbon dioxide from the ambient air; and at least one carbon dioxide transport unit adapted to provide the carbon dioxide quantity for storage and/or further processing, wherein the electrolysis unit includes at least one oxygen outlet for discharging the partial quantity of oxygen and the carbon dioxide absorption unit includes at least one air outlet for discharging purified ambient air, wherein the oxygen outlet and the air outlet open into the outside atmosphere.