An integrated process for the production of a useful liquid hydrocarbon product comprises: feeding a gasification zone with an oxygen-containing feed and a first carbonaceous feedstock comprising waste materials and/or biomass, gasifying the first carbonaceous feedstock in the gasification zone to produce first synthesis gas, partially oxidising the first synthesis gas in a partial oxidation zone to generate partially oxidised synthesis gas, combining at least a portion of the first synthesis gas and/or the partially oxidised synthesis gas and at least a portion of electrolysis hydrogen obtained from an electrolyser in an amount to achieve the desired hydrogen to carbon monoxide molar ratio of from about 1.5:1 to about 2.5:1, and to generate a blended synthesis gas, wherein the electrolyser operates using green electricity; and subjecting at least a portion of the blended synthesis gas to a conversion process effective to produce the liquid hydrocarbon product.

An asymmetric system containing a first conductive polymer modified with a redox active moiety and a second conductive polymer modified with a surfactant is used for the separation of organic compounds from aqueous solutions. The asymmetric system has complementary hydrophobicity tunability in response to electrochemical modulations. For example, both materials are hydrophobic in their respective neutral states, therefore exhibiting affinity toward organic compounds. Application of a mild potential drives the desorption of the organic compounds and regeneration of the materials. The asymmetric system can be used in a cyclic fashion, through repeated electrical discharge or shorting of the two electrodes to program the capture of organics from a feed solution, and application of a potential to stimulate the release of the adsorbed organics.

An asymmetric system containing a first conductive polymer modified with a redox active moiety and a second conductive polymer modified with a surfactant is used for the separation of organic compounds from aqueous solutions. The asymmetric system has complementary hydrophobicity tunability in response to electrochemical modulations. For example, both materials are hydrophobic in their respective neutral states, therefore exhibiting affinity toward organic compounds. Application of a mild potential drives the desorption of the organic compounds and regeneration of the materials. The asymmetric system can be used in a cyclic fashion, through repeated electrical discharge or shorting of the two electrodes to program the capture of organics from a feed solution, and application of a potential to stimulate the release of the adsorbed organics.

The embodiments of the present disclosure relate to a method and apparatus for producing a CNM product that may comprise carbon nanotubes (CNTs). The method and apparatus employ carbon dioxide (CO.sub.2) and a carbonate electrolyte that is lithium-free as reactants in an electrolysis reaction in order to make CNTs. In some embodiments of the present disclosure, a graphene-defect agent may be introduced into the electrolysis reaction.

The embodiments of the present disclosure relate to a method and apparatus for producing a CNM product that may comprise carbon nanotubes (CNTs). The method and apparatus employ carbon dioxide (CO.sub.2) and a carbonate electrolyte that is lithium-free as reactants in an electrolysis reaction in order to make CNTs. In some embodiments of the present disclosure, a graphene-defect agent may be introduced into the electrolysis reaction.

In this disclosure, a process of recycling acid, base and the salt reagents required in the Li recovery process is introduced. A membrane electrolysis cell which incorporates an oxygen depolarized cathode is implemented to generate the required chemicals onsite. The system can utilize a portion of the salar brine or other lithium-containing brine or solid waste to generate hydrochloric or sulfuric acid, sodium hydroxide and carbonate salts. Simultaneous generation of acid and base allows for taking advantage of both chemicals during the conventional Li recovery from brines and mineral rocks. The desalinated water can also be used for the washing steps on the recovery process or returned into the evaporation ponds. The method also can be used for the direct conversion of lithium salts to the high value LiOH product. The method does not produce any solid effluent which makes it easy-to-adopt for use in existing industrial Li recovery plants.

An electrolytic liquid production device includes: an electrolyzer configured to perform electrolytic treatment to a liquid; elastic body configured to press the electrolyzer; and housing having the electrolyzer and elastic body disposed inside housing. Housing has inlet port that the liquid supplied to the electrolyzer flows into, and outlet port that an electrolytic liquid produced in the electrolyzer flows out from. Elastic body includes positioning depressed portion, and housing includes positioning protruding portion. Elastic body is positioned with respect to housing by inserting positioning protruding portion of housing into positioning depressed portion of elastic body. Thus, there is provided an electrolytic liquid production device capable of suppressing bias of elastic body inside housing.

An electrolytic liquid production device includes: an electrolyzer configured to perform electrolytic treatment to a liquid; elastic body configured to press the electrolyzer; and housing having the electrolyzer and elastic body disposed inside housing. Housing has inlet port that the liquid supplied to the electrolyzer flows into, and outlet port that an electrolytic liquid produced in the electrolyzer flows out from. Elastic body includes positioning depressed portion, and housing includes positioning protruding portion. Elastic body is positioned with respect to housing by inserting positioning protruding portion of housing into positioning depressed portion of elastic body. Thus, there is provided an electrolytic liquid production device capable of suppressing bias of elastic body inside housing.

An electrolytic cell for treating wastewater comprises an anode assembly, a cathode assembly and at least one bipolar electrode assembly placed between the anode and the cathode assembly such that the anodes of the anode assembly and the cathodes of the cathode assembly are interleaved with the bipolar plates of the bipolar electrode assembly. Each bipolar electrode assembly comprises a series of bipolar electrodes which operate as an anode or as a cathode, stacked in a vertical direction along a threaded bolt made of an electrically conductive material such that the bipolar electrodes operating as anodes are oriented in an opposite direction to the bipolar electrodes operating as cathodes and have their ends overlapping over a predetermined portion and being separated by conductive spacers. In preferred embodiments, only the anodes and the bipolar electrodes operating as anodes are coated with catalyst which saves costs and simplifies the manufacturing process.

Catalysts for selective production of hydrogen peroxide and methods of making and using thereof have been developed. The catalysts include an alloyed or doped metal oxide which permits tuning of the catalytic properties of the catalysts for selection of a desired pathway to a product, such as hydrogen peroxide. The catalysts may be incorporated into electrochemical or photochemical devices.