Patent classifications
C25B11/02
COPPER AND ANTIMONY BASED MATERIAL AND ELECTRODE FOR THE SELECTIVE CONVERSION OF CARBON DIOXIDE TO CARBON MONOXIDE
An electrocatalyst material comprising cuprous oxide and antimony, the process for the production thereof and its use in the electrochemical reduction of CO.sub.2 to CO with high selectivity and efficiency are described.
ELECTROLYTIC CELL EQUIPPED WITH MICROELECTRODES
An electrolytic cell equipped with microelectrodes for the generation of un-separated products and the method for obtaining it. The cell and the microelectrodes are obtained using a technology for the production of microelectromechanical systems (MEMS). The anodic and cathodic microelectrodes have an electrocatalytic coating and are mutually intercalated at an interelectrodic gap lower than 300 micrometres.
ELECTROLYTIC CELL EQUIPPED WITH MICROELECTRODES
An electrolytic cell equipped with microelectrodes for the generation of un-separated products and the method for obtaining it. The cell and the microelectrodes are obtained using a technology for the production of microelectromechanical systems (MEMS). The anodic and cathodic microelectrodes have an electrocatalytic coating and are mutually intercalated at an interelectrodic gap lower than 300 micrometres.
Continuous Capture of Carbon Dioxide From Exhaust Gas and Conversion Thereof to Useful Chemistries
A method including collecting exhaust gas comprising carbon dioxide (CO.sub.2) at a wellsite to provide a collected exhaust gas, separating CO.sub.2 from the collected exhaust gas to provide a separated CO.sub.2, and forming an alcohol product utilizing at least a portion of the separated CO.sub.2. The alcohol product can include methanol, ethanol, a precursor thereof, or a combination thereof.
Continuous Capture of Carbon Dioxide From Exhaust Gas and Conversion Thereof to Useful Chemistries
A method including collecting exhaust gas comprising carbon dioxide (CO.sub.2) at a wellsite to provide a collected exhaust gas, separating CO.sub.2 from the collected exhaust gas to provide a separated CO.sub.2, and forming an alcohol product utilizing at least a portion of the separated CO.sub.2. The alcohol product can include methanol, ethanol, a precursor thereof, or a combination thereof.
Energy-efficient diaphragm-electrolyser
The invention relates to the field of electrochemical production of disinfectants, where a solution of alkaline metals is used as the electrolyte in the anode chamber. The invention offers a new design for electrolyzers, reducing power consumption in the production of disinfectants by known methods. As a result of this invention, power consumed in the production of 1 gram of active chlorine by known methods will be reduced by 20%, and the possibilities for producing disinfectants with active chlorine content 7500 ppm in an electrolyzer without channelling the water into external cooling devices will also expand.
Energy-efficient diaphragm-electrolyser
The invention relates to the field of electrochemical production of disinfectants, where a solution of alkaline metals is used as the electrolyte in the anode chamber. The invention offers a new design for electrolyzers, reducing power consumption in the production of disinfectants by known methods. As a result of this invention, power consumed in the production of 1 gram of active chlorine by known methods will be reduced by 20%, and the possibilities for producing disinfectants with active chlorine content 7500 ppm in an electrolyzer without channelling the water into external cooling devices will also expand.
ELECTROLYTIC CELL FOR PRODUCTION OF ORGANIC CHEMICAL HYDRIDES
To provide an electrolysis cell for producing an organic chemical hydride capable of advancing a reduction reaction in a cathode of an organic compound having an unsaturated bond with high current efficiency and a small electric power consumption unit.
An electrolysis cell 10 for producing an organic chemical hydride includes a solid polymer electrolyte film 11 which has proton conductivity; a cathode 12 which is provided on one surface of the solid polymer electrolyte film 11 and generates a hydride by reducing a substance to be hydrogenated; a cathode chamber 13 which accommodates the cathode 12 and to which the substance to be hydrogenated is supplied; an electrode catalyst-containing anode 14 which is provided on another surface of the solid polymer electrolyte film 11 and generates a proton by oxidizing water; and an anode chamber 15 which accommodates the anode 14 and to which an electrolytic solution is supplied, in which at least one of a surface of the cathode 12 side and a surface of the anode 14 side of the solid polymer electrolyte film 11 is hydrophilized.
Controlled electrochemical oxidation of Pt(II) ions for continuous methane-to-methanol conversion
Disclosed is an electrochemical method for continuous regeneration of a Pt.sup.IV oxidant to furnish overall electrochemical methane oxidation. Cl-adsorbed Pt electrodes catalyze facile oxidation of Pt.sup.II to Pt.sup.IV without concomitant methanol oxidation. Exploiting this electrochemistry, the Pt.sup.II/IV ratio in solution is maintained via in situ monitoring of the solution potential coupled with dynamic modulation of the electric current. Remarkably, this method leads to sustained methane oxidation catalysis with ˜70% selectivity for methanol.
Controlled electrochemical oxidation of Pt(II) ions for continuous methane-to-methanol conversion
Disclosed is an electrochemical method for continuous regeneration of a Pt.sup.IV oxidant to furnish overall electrochemical methane oxidation. Cl-adsorbed Pt electrodes catalyze facile oxidation of Pt.sup.II to Pt.sup.IV without concomitant methanol oxidation. Exploiting this electrochemistry, the Pt.sup.II/IV ratio in solution is maintained via in situ monitoring of the solution potential coupled with dynamic modulation of the electric current. Remarkably, this method leads to sustained methane oxidation catalysis with ˜70% selectivity for methanol.