C01B3/025

Low steam/carbon revamp of a plant comprising a steam reforming section and a water-gas shift section

The present invention relates to a revamp method for increasing the front-end capacity of a plant comprising a reforming section, wherein a feed is reformed in at least one reforming step to a reformed stream comprising CH.sub.4, CO, CO.sub.2, H.sub.2 and H.sub.2O a shift section wherein the reformed stream is shifted in a shift reaction in at least a high temperature shift step,
said method comprising the steps of In the High temperature shift step exchanging an original Fe-based catalyst with a non-Fe-based catalyst Increasing the feed flow to the reforming section, and The HTS step is carried out at a reduced steam/dry-gas ratio (S/DG) compared to an original S/DG in the original HTS step with the original Fe-based catalyst.

GAS PRODUCTION PLANT
20230035358 · 2023-02-02 ·

A gas production plant includes an electrolysis arrangement for the production of gaseous hydrogen; an air separation arrangement for the production of gaseous nitrogen; a gas mixer configured to mix the gaseous hydrogen and the gaseous nitrogen in a predetermined mixing ratio; and an injector for injecting the resulting gaseous mixture into an export pipeline. A method of providing gaseous reactants for an ammonia synthesis plant is also provided.

INTEGRATION OF POWER GENERATION WITH METHANE REFORMING
20230092064 · 2023-03-23 ·

The system includes a methane reformer, a combined cycle power generator, and a switch. The reformer is configured to react methane with steam. The combined cycle power generator includes a steam turbine, a gas turbine, a power generator, and a water boiler. The steam turbine is configured to rotate in response to receiving steam. The gas turbine is configured to rotate in response to receiving a mixture of fuel and air. The power generator is configured to convert rotational energy from the steam turbine and the gas turbine into electricity. In a first position, the switch is configured to direct exhaust from the gas turbine to the reformer, thereby providing heat to the reformer. In a second position, the switch is configured to direct exhaust from the gas turbine to the water boiler, thereby providing heat to the water boiler to generate steam.

METHOD AND APPARATUS FOR IMPROVING A REFORMING PROCESS BY USING RENEWABLE ELECTRICAL ENERGY AS A HEATING INPUT TO THE REFORMING PROCESS
20230072910 · 2023-03-09 ·

A method for improving a reforming process by using renewable electrical energy as a heating input to the reforming process is provided. The method includes partially preheating combustion air using a first electrical heater, wherein the first electrical heater is configured to be supplied with the renewable electrical energy generated by a renewable source, wherein the first electrical heater is integrated in between a cold air preheater and a hot air preheater of a process plant that performs the reforming process; utilizing, by the first electrical heater, a bad based on an availability of the renewable electrical energy received from the renewable source; and providing, by the first electrical heater, the preheated combustion air at an outlet of the first electrical heater to a boiler of the process plant based on the bad utilized by the first electrical heater.

HYDROGEN AND/OR AMMONIA PRODUCTION PROCESS

Disclosed herein is a method of producing hydrogen, the method comprising: receiving a feed gas comprising hydrocarbons; performing one or more reforming processes on the feed gas so as to generate a reformed gas comprising hydrogen and carbon monoxide; performing a water-gas-shift process on the reformed gas so as to generate a shifted gas comprising hydrogen and carbon dioxide; performing a hydrogen separation process and a carbon dioxide separation process on the shifted gas to thereby generate separate streams of hydrogen, carbon dioxide and a rest gas; and the method further comprises recycling at least part of the rest gas by feeding at least part of the rest gas back into one or more of the one or more reforming processes, the water-gas-shift process, the hydrogen separation process and the carbon dioxide separation process; wherein the portion of the rest gas that is recycled is at least 50%, preferably at least 80%, and more preferably at least 90%.

REFORMING PROCESS INTEGRATED WITH GAS TURBINE GENERATOR

A reforming process comprising for production of a hydrogen-containing synthesis gas with a thermally integrated gas turbine engine wherein the hot exhaust gas of the gas turbine engine is the heat source for preheating one or more process streams of the reforming process.

Apparatus and Method for Producing Synthesis Gas
20230159330 · 2023-05-25 ·

An apparatus for producing synthesis gas (syngas) is provided. The apparatus includes a hub, including an autothermal dry reforming of methane apparatus, configured to receive CO.sub.2 and O.sub.2, and configured to produce a first stream of syngas with low a H.sub.2/CO mole ratio; an autothermal steam reforming of methane apparatus, configured to receive steam and O.sub.2, and configured to produce a second stream of syngas with a high H.sub.2/CO mole ratio; an H.sub.2 separation apparatus, configured to receive H.sub.2 and CO.sub.2, and coupled to the autothermal dry reforming of methane apparatus to deliver CO.sub.2 thereto; and a reactor for converting CO to H.sub.2 using a water-gas shift reaction, coupled to the autothermal steam reforming of methane apparatus to receive the second stream of syngas, and coupled to the H.sub.2 separation apparatus to deliver a stream of H.sub.2 and CO.sub.2 thereto. A method for producing synthesis gas is provided. The method includes configuring an autothermal dry reforming of methane apparatus to receive CO.sub.2 from industrial emission sources and an H.sub.2 separation apparatus, which receives H.sub.2 and CO.sub.2 from a water gas shift reactor fed with a portion of the second stream of syngas from an autothermal steam reforming of methane apparatus.

CO-PRODUCTION OF METHANOL, AMMONIA AND UREA
20230073089 · 2023-03-09 · ·

Sequential and once-through (single pass) process for the co-production of methanol and ammonia and conversion of at least a part of ammonia to urea by reaction of the ammonia with carbon dioxide collected from a primary reformer flue gas together with carbon dioxide separated from reformed gas in a carbon dioxide removal stage.

Transition metal carbide chemical looping reforming

A process for producing syngas including at least H.sub.2 and CO. The process includes the steps of a) generating a transition metal carbide by reacting a corresponding transition metal oxide with a fuel to produce a stream of syngas; and b) combining the transition metal carbide with oxygen to oxidize the transition metal carbide to regenerate the corresponding transition metal oxide, thereby producing a gas output comprising at least one or more oxidized carbon compounds and heat for autothermal operation.

PROCESS AND PLANT FOR PRODUCING METHANOL AND AMMONIA
20220315434 · 2022-10-06 ·

What is proposed is a process and a plant for parallel production of methanol and ammonia by heterogeneously catalyzed reaction of hydrogen and carbon oxides on the one hand and hydrogen and nitrogen on the other hand. This includes producing a raw synthesis gas stream and dividing it into two portions. A first raw synthesis gas substream is used as input for a methanol synthesis to obtain raw methanol and a methanol synthesis purge stream. A second raw synthesis gas substream is subjected to a CO conversion, a carbon dioxide separation and a liquid nitrogen scrubbing and then sent to an ammonia synthesis. According to the invention at least a portion of the methanol synthesis purge stream is sent to the ammonia synthesis and at least one substream obtained from the second raw synthesis gas substream is passed to the methanol synthesis.