A fuel cell system comprising a fuel cell stack, an evaporator for evaporating a mixture of methanol and water to be forwarded through a catalytic reformer for producing portions of free hydrogen. The fuel cell stack being composed of a number of proton exchange membrane fuel cells each featuring electrodes in form of an anode and a cathode for delivering an electric current. The liquid fuel using a. pre-evaporator, which. partly evaporates the fuel, followed by a. nozzle, which atomizes the fuel into a fine mist, before being passed to the final evaporation zone. This configuration ensures that liquid fuel for producing thermal, neat is converted into a form that facilitates a burner to achieve a quick heating up of the fuel, cell system into production mode.

A catalyst system includes a complex having formula I which advantageously has a sterically protecting N-heterocyclic carbene (NHC) carbene-pyridine ligand to handle harsh reactions conditions than many prior art catalysts:

##STR00001##

wherein M is a transition metal; o is 0, 1, 2, 3, or 4; R.sub.1 is a C.sub.1-6 alkyl, a C.sub.6-18 aryl, or an optionally substituted C.sub.5-18 heteroaryl. In a refinement, R.sub.1 is methyl, ethyl, butyl, n-propyl, isopropyl, n-butyl, sec-butyl, or t-butyl; R.sub.2, R.sub.3, R.sub.3′ are independently an optionally substituted C.sub.1-6 alkyl, halo (e.g., Cl, F, Br, etc), NO.sub.2, an optionally substituted C.sub.6-18 aryl, or an optionally substituted C.sub.5-18 heteroaryl; R.sub.4, R.sub.4′ are independently an optionally substituted C.sub.1-6 alkyl, halo, NO.sub.2, an optionally substituted C.sub.6-18 aryl, or an optionally substituted C.sub.5-18 heteroaryl; and X.sup.− is a negatively charge counter ion and L.sub.1, L.sub.2 are each independently a neutral ligand.

The integrated processes herein provide improved carbon efficiency for processes based on coal or biomass gasification or steam methane reforming. Provided are also ethylene oxide carbonylation products such as beta-propiolactone and succinic anhydride having a bio-based content between 0% and 100%, and methods for producing and analyzing the same.

Hydrogen purification devices and their components are disclosed. In some embodiments, the devices may include at least one foil-microscreen assembly disposed between and secured to first and second end frames. The at least one foil-microscreen assembly may include at least one hydrogen-selective membrane and at least one microscreen structure including a non-porous planar sheet having a plurality of apertures forming a plurality of fluid passages. The planar sheet may include generally opposed planar surfaces configured to provide support to the permeate side. The plurality of fluid passages may extend between the opposed surfaces. The at least one hydrogen-selective membrane may be metallurgically bonded to the at least one microscreen structure.

A solids discharge system (SDS) is configured to separate solids from product gas. The system includes a solids separation device and at least one solids transfer conduit configured to receive solids from the solids separation device. The solids transfer conduit is selectively partitioned into a plurality of compartments (or “sections”) along its length by isolation valves. A gas supply conduit and a gas discharge conduits are connected to one of the sections to facilitate removal of solids. A filter in fluid communication with that section is configured to prevent solids from passing through the gas discharge conduit so that the solids can be removed from one of the sections of the solids transfer conduit. A product gas generation system incorporates first and second reactors, the latter of which receives products created by the second reactor.

A solids discharge system (SDS) is configured to separate solids from product gas. The system includes a solids separation device and at least one solids transfer conduit configured to receive solids from the solids separation device. The solids transfer conduit is selectively partitioned into a plurality of compartments (or “sections”) along its length by isolation valves. A gas supply conduit and a gas discharge conduits are connected to one of the sections to facilitate removal of solids. A filter in fluid communication with that section is configured to prevent solids from passing through the gas discharge conduit so that the solids can be removed from one of the sections of the solids transfer conduit. A product gas generation system incorporates first and second reactors, the latter of which receives products created by the second reactor.

Disclosed are a fuel supply module that may maintain an entrainment ratio in a constant range even under a load change, and a fuel reforming apparatus for a fuel cell using the same. The fuel supply module includes: a water vapor storage for storing water vapor therein; a fuel storage for storing fuel therein; a mixer having a first inlet, a second inlet, and an outlet; a first inlet pipe for connecting the water vapor storage and the first inlet of the mixer with each other; a second inlet pipe for connecting the fuel storage and the second inlet of the mixer with each other; an outlet pipe connected to the outlet of the mixer; and a bypass pipe having one end connected to the first inlet pipe and the other end connected to the outlet pipe.

The disclosure relates to methods of capturing carbon by microbial fermentation of a gaseous substrate comprising CO into one or more first products which, in turn, may be incorporated into an article of manufacture or one or more second products. Further, the disclosure relates to improving carbon capture and/or efficiency.

The present invention relates to a steam reforming catalyst for hydrogen production. More specifically, the present invention provides a novel catalysts support for sustainable hydrogen production by steam reforming process using bio-based materials feedstock such as ethanol, glycerol, n-butanol and ethylene glycol. The said improved support catalyst and metal doped catalysts therefrom, are comprising of combination of crystalline Mesoporous cellular foam (MCF) silica and basic site assistant for enhancing catalytic activity of doped active metals thereon and lower coke formation. The benefits of present invention is in the cost efficient steam reforming process for hydrogen production, wherein the said catalysts are efficiently providing a high reactant conversion at lower temperature, no coke formation, high thermal stability for longer time and effective catalytic performance for multiple cycles.

Hydrogen generation assemblies, hydrogen purification devices, and their components, and methods of manufacturing those assemblies, devices, and components are disclosed. In some embodiments, the devices may include an insulation base having insulating material and at least one passage that extends through the insulating material. In some embodiments, the at least one passage may be in fluid communication with a combustion region.