The invention is an improved method of making an improved carbon molecular sieve (CMS) membrane in which a precursor polymer (e.g., polyimide) is pyrolyzed at a pyrolysis temperature to form a CMS membrane that is cooled to ambient temperature (about 40° C. or 30° C. to about 20° C.). The CMS membrane is then reheated to a reheating temperature less than the pyrolysis temperature to form the improved CMS membrane. The improved CMS membranes have shown an improved combination of selectivity and permeance as well as stability for separating hydrogen from gas molecules (e.g., methane, ethane, propane, ethylene, propylene, butane, carbon dioxide, nitrogen, butylene, and combinations thereof).

Proposed are a process and a plant for producing a synthesis gas product stream having an adjustable H.sub.2/CO ratio and a pure hydrogen stream, wherein it is provided according to the invention that a substream of a deacidified synthesis gas stream is supplied to a membrane separation plant fitted with a hydrogen-selective membrane and the remaining substream is supplied to a pressure swing adsorption plant, wherein the latter affords a pure hydrogen stream and a fuel gas stream. The hydrogen-enriched permeate stream obtained from the membrane separation is likewise supplied to the pressure swing adsorption plant, thus enhancing the yield of pure hydrogen. The hydrogen-depleted retentate stream obtained from the membrane separation is discharged as a synthesis gas product stream and if of a suitable composition may be utilized as oxo gas.

The invention relates to a device for producing a dihydrogen gas including an enclosure, means for conveying the product into the enclosure, which comprise a screw mounted so as to rotate in the enclosure about a geometric axis of rotation, means for heating the screw by the Joule effect, and a unit for removing impurities present in the gas. The invention also relates to a method for manufacturing dihydrogen using such a device as well as to a use of the device for the treatment of a product such as CSR material or polymer material.

An integrated system for hydrogen purification, storage, and pressurization, including a first heat exchanger, a second heat exchanger, a third heat exchanger, a fourth heat exchanger, a hydrogen storage tank, an adjustable heat and cold source; a gas pump, a first circulation pump, a second circulation pump, a third circulation pump and a fourth circulation pump. The first heat exchanger is provided with a first low-pressure metal hydride reactor. The second heat exchanger is provided with a second low-pressure metal hydride reactor. The third heat exchanger is provided with a medium-pressure metal hydride reactor. The fourth heat exchanger is provided with a high-pressure metal hydride reactor. The first low-pressure metal hydride reactor is connected to the second low-pressure metal hydride reactor, and the medium-pressure metal hydride reactor is connected to the high-pressure metal hydride reactor. An integrated method for hydrogen purification, storage, and pressurization is also provided.

Embodiments of the invention are directed to methods, processes, and systems for safely and reliably purifying hydrogen from a gas mixture containing hydrogen and oxygen.

In a method for producing a gaseous mixture of CO and H.sub.2, a first gas comprising at least 50% CO is compressed in a first compressor to form a first compressed gas cooled to a first temperature and mixes with a second gas comprising at least 50% hydrogen in order to form the gaseous mixture, at least one of the first and second gases originating from a cryogenic distillation separation unit in which a feed gas containing H.sub.2 and CO cools in a first heat exchanger and is separated in at least one distillation column and at least one part of the second gas heats in the separation unit to a third temperature lower than the first temperature and is then sent to mix with the first gas.

Provided are a hydrogen purification device and a hydrogen purification method whereby hydrogen having a high purity can be purified at a high yield from a starting gas. The hydrogen purification device comprises: a starting gas source that supplies a starting gas, said starting gas containing hydrogen molecules and/or a hydride, to a discharge space; a plasma reactor that defines at least a part of the discharge space; a hydrogen flow channel that is connected to the discharge space; and leads out purified hydrogen from the starting gas source; a hydrogen separation membrane that partitions the discharge space from the hydrogen flow channel defines at least a part of the discharge space by one surface thereof and defines at least a part of the hydrogen flow channel by the other surface thereof; an electrode that is positioned outside the discharge space; and an adsorbent that is filled in the discharge space and adsorbs the starting gas. In the hydrogen purification method according to the present invention, the starting gas is adsorbed by the adsorbent in the discharge space. Hydrogen molecules, which have been desorbed from the adsorbent by discharge, are allowed to penetrate through the hydrogen separation membrane 4 and led out into the hydrogen flow channel.

Embodiments of the invention are directed to methods, processes, and systems for safely and reliably purifying hydrogen from a gas mixture containing hydrogen and oxygen.

A process is disclosed for increasing hydrogen recovery in an integrated refinery and petrochemical complex in which natural gas is used as a co-purge gas in a pressure swing adsorption unit. This natural gas is recovered in tail gas from the pressure swing adsorption unit. This process is useful for refinery off-gas and partial oxidation feeds.

Disclosed herein are methods and systems for the production of hydrogen-containing compounds, such as ammonia and urea from a product stream of a fuel cell unit. The production of ammonia and optionally urea can also include a net power production. Alternatively, the hydrogen stream from the fuel cell unit can be directed to the production of synthetic hydrocarbons liquids.