An ammonia removal material to be used for obtaining a mixed gas (B) having an ammonia concentration of 0.1 mol ppm or less from a mixed gas (A) including hydrogen, nitrogen, and ammonia and having an ammonia concentration exceeding 0.1 mol ppm, the ammonia removal material containing zeolite having a pore size of 0.5 nm or more and 2.0 nm or less, a method for removing ammonia from the mixed gas using the ammonia removal material, and a method for producing a hydrogen gas for a fuel cell automobile, the method including the method for removing ammonia.

Ammonia removal equipment including a first ammonia removal apparatus that removes ammonia in a mixed gas containing hydrogen and ammonia, a second ammonia removal apparatus that is installed at a stage subsequent to the first ammonia removal apparatus and that treats a first treated gas treated by the first ammonia removal apparatus, and a first ammonia concentration measurement apparatus that measures the ammonia concentration in the first treated gas treated by the first ammonia removal apparatus.

The process can be used in any hydrocarbon process in which it is desirable to recover hydrogen. The process can include catalytically reforming a hydrocarbon feed, a paraffin dehydrogenation to produce light olefins or a synthesis gas generating process. There is an effluent stream having hydrogen and hydrocarbons that is first sent to an adsorption zone to produce a pure hydrogen stream and a tail gas stream. The tail gas stream is then sent across a feed side of a membrane having the feed side and a permeate side. The membrane that is selected is selective for hydrogen over one or more C1-C6 hydrocarbons and light ends including CO, CO2, N2 and O2, and withdrawing from the permeate side a permeate stream enriched in hydrogen compared with a residue stream withdrawn from the feed side. The permeate stream is then recycled to be sent through the adsorption zone.

An integrated system for hydrogen purification, storage, and pressurization, including a first heat exchanger, a second heat exchanger, a third heat exchanger, a fourth heat exchanger, a hydrogen storage tank, an adjustable heat and cold source; a gas pump, a first circulation pump, a second circulation pump, a third circulation pump and a fourth circulation pump. The first heat exchanger is provided with a first low-pressure metal hydride reactor. The second heat exchanger is provided with a second low-pressure metal hydride reactor. The third heat exchanger is provided with a medium-pressure metal hydride reactor. The fourth heat exchanger is provided with a high-pressure metal hydride reactor. The first low-pressure metal hydride reactor is connected to the second low-pressure metal hydride reactor, and the medium-pressure metal hydride reactor is connected to the high-pressure metal hydride reactor. An integrated method for hydrogen purification, storage, and pressurization is also provided.

A structure in which a plurality of particles each containing a hydrogen absorption metal element are arranged in a fixed member such that the plurality of particles are apart from each other. An entire surface of each of the plurality of particles is surrounded by the fixed member.

A hydrogen storage assembly, in particular for a fuel cell system in a vehicle, includes at least one hydrogen tank for storage of liquid hydrogen and at least one hydrogen sorption/catalyst unit for sorption and catalytic conversion of gaseous hydrogen released from the at least one hydrogen tank. Also, a fuel cell system includes the hydrogen storage assembly.

The present invention relates to a method for production of H.sub.2 from natural gas, solid fossil fuels or biomass. The method comprises the following steps: reacting natural gas in a reformer or reacting solid fossil fuels or biomass in a gasifier to form syngas, reacting the syngas to form a shifted gas mixture, comprising H.sub.2 and CO.sub.2, in a water-gas-shift (WGS) section, separating the shifted gas mixture into a H.sub.2 gas and a H.sub.2 depleted tail gas mixture or retentate gas mixture in a H.sub.2 separation unit, separating the H.sub.2-depleted tail gas mixture or retentate gas mixture into a CO.sub.2 liquid and a CO.sub.2-depleted tail gas mixture in a CO.sub.2 capture and liquefaction unit, and recycling the CO.sub.2-depleted tail gas mixture from the CO.sub.2 capture and liquefaction unit without recompression to the WGS section and to the reformer or the gasifier. The CO.sub.2-depleted tail gas mixture is at a pressure in the range from 25 to 120 bar when recycled to the WGS section and to the reformer or the gasifier.

The present disclosure provides systems and methods for hydrogen production as well as apparatuses useful in such systems and methods. Hydrogen is produced by steam reforming of a hydrocarbon in a gas heated reformer that is heated using one or more streams comprising combustion products of a fuel in an oxidant, preferably in the presence of a carbon dioxide circulating stream.

The system comprises a steam reforming unit to produce hydrogen from exhaust gas supplied, a hydrogen permeable membrane to allow only hydrogen produced by the steam reforming unit to pass through it, a hydrogen storage unit to absorb hydrogen supplied through the hydrogen permeable membrane and release absorbed hydrogen, a fuel cell to generate power using hydrogen supplied from the hydrogen storage unit, a gas clean-up unit to clean up residual gases delivered not passing through the hydrogen permeable membrane, and a control unit to control the hydrogen storage unit to absorb or release hydrogen depending on whether the fuel cell is supplied with sufficient hydrogen.

A method and a system to form hydrogen while removing sulfur from an acid gas stream are provided. An exemplary system includes a reaction furnace including a porous burner, an inlet for an oxygen stream into the porous burner, an inlet for the acid gas stream into the porous burner, and a plurality of inlets on the reaction furnace for injecting an inert coolant.