A polymer/activated carbon composite made up of a branched polyethylenimine and magnetic cores involving Fe.sub.3O.sub.4 disposed activated carbon. The magnetic cores have activated carbonyl groups on the surface. A process for removing organic dyes, such as methyl red, as well as heavy metal ions from a polluted aqueous solution or an industrial wastewater utilizing the composite is introduced. A method of synthesizing the polymer/activated carbon composites is also specified.

This invention provides processes for reducing the environmental availability of one or more environmental pollutants in solids, liquids, and combinations of solids and liquids.

A polymer/activated carbon composite made up of a branched polyethylenimine and magnetic cores involving Fe.sub.3O.sub.4 disposed activated carbon. The magnetic cores have activated carbonyl groups on the surface. A process for removing organic dyes, such as methyl red, as well as heavy metal ions from a polluted aqueous solution or an industrial wastewater utilizing the composite is introduced. A method of synthesizing the polymer/activated carbon composites is also specified.

[SUMMARY]

[OBJECT] To provide a per- and polyfluoroalkyl compound-adsorbing activated carbon having a high collection rate of per- and polyfluoroalkyl compounds in an atmospheric sample, and a filter body using the same.

[ACHIEVING MEANS] A per- and polyfluoroalkyl compound-adsorbing activated carbon for desorbably adsorbing per- and polyfluoroalkyl compounds in an atmospheric sample, the activated carbon including an activated carbon adsorbent having a BET specific surface area of 900 m.sup.2/g or more, a sum (V.sub.mic) of a volume of micropores of 1 nm or less of 0.35 cm.sup.3/g or more, a sum (V.sub.met) of a volume of mesopores of 2 to 60 nm of 0.02 cm.sup.3/g or more, a volume difference (V.sub.s) between the micropore volume (V.sub.mic) and the mesopore volume (V.sub.met) of 0.45 or more, and a surface oxide amount of 0.10 meq/g or more.

[SUMMARY]

[OBJECT] To provide a per- and polyfluoroalkyl compound-adsorbing activated carbon having a high collection rate of per- and polyfluoroalkyl compounds in an atmospheric sample, and a filter body using the same.

[ACHIEVING MEANS] A per- and polyfluoroalkyl compound-adsorbing activated carbon for desorbably adsorbing per- and polyfluoroalkyl compounds in an atmospheric sample, the activated carbon including an activated carbon adsorbent having a BET specific surface area of 900 m.sup.2/g or more, a sum (V.sub.mic) of a volume of micropores of 1 nm or less of 0.35 cm.sup.3/g or more, a sum (V.sub.met) of a volume of mesopores of 2 to 60 nm of 0.02 cm.sup.3/g or more, a volume difference (V.sub.s) between the micropore volume (V.sub.mic) and the mesopore volume (V.sub.met) of 0.45 or more, and a surface oxide amount of 0.10 meq/g or more.

A filter apparatus for removing small molecule chemotherapy agents from blood is provided. The filter apparatus comprises a housing with an extraction media comprised of polymer coated carbon cores. Also provided are methods of treating a subject with cancer of an organ or region comprising administering a chemotherapeutic agent to the organ or region, collecting blood laded with chemotherapeutic agent from the isolated organ, filtering the blood laden with chemotherapeutic agent to reduce the chemotherapeutic agent in the blood and returning the blood to the subject.

A filter apparatus for removing small molecule chemotherapy agents from blood is provided. The filter apparatus comprises a housing with an extraction media comprised of polymer coated carbon cores. Also provided are methods of treating a subject with cancer of an organ or region comprising administering a chemotherapeutic agent to the organ or region, collecting blood laded with chemotherapeutic agent from the isolated organ, filtering the blood laden with chemotherapeutic agent to reduce the chemotherapeutic agent in the blood and returning the blood to the subject.

A method of producing a porous carbon is provided that can change type of functional groups, amount of functional groups, or ratio of functional groups while inhibiting its pore structure from changing. A method of producing a porous carbon includes: a first step of carbonizing a material containing a carbon source and a template source, to prepare a carbonized product; and a second step of immersing the carbonized product into a template removing solution, to remove a template from the carbonized product, and the method is characterized by changing at least two or more of the following conditions: type of the material, ratio of the carbon source and the template source, size of the template, and type of the template removal solution, to thereby control type, amount, or ratio of functional groups that are present in the porous carbon.

A method of producing a porous carbon is provided that can change type of functional groups, amount of functional groups, or ratio of functional groups while inhibiting its pore structure from changing. A method of producing a porous carbon includes: a first step of carbonizing a material containing a carbon source and a template source, to prepare a carbonized product; and a second step of immersing the carbonized product into a template removing solution, to remove a template from the carbonized product, and the method is characterized by changing at least two or more of the following conditions: type of the material, ratio of the carbon source and the template source, size of the template, and type of the template removal solution, to thereby control type, amount, or ratio of functional groups that are present in the porous carbon.

A cross-linked structure of a carbon material is excellent in mechanical strength, such as tensile strength. The carbon materials such as carbon nanotube, graphite, fullerene, and carbon nanocoil, are cross-linked with each other. The carbon materials are cross-linked through a linking group derived from a nucleophilic compound having two or more nucleophilic groups in the molecule.