A reformer system (11) having a hydrodesulfurizer (12) provides desulfurized natural gas feedstock to a catalytic steam reformer (16), the outflow of which is treated by a water gas shift reactor (20) and optionally a preferential CO oxidizer (58) to provide reformate gas (28, 28a) having high hydrogen and moderate carbon dioxide content. To avoid damage to the hydrodesulfurizer from overheating, any deleterious hydrogen reactants, such as the oxygen in peak shave gas or olefins, in the non-desulfurized natural gas feedstock (35) are reacted (38) with hydrogen (28, 28a; 71) to convert them to alkanes (e.g., ethylene and propylene to ethane and propane) and to convert oxygen to water in a catalytic reactor (38) having no sulfide sorbent, and cooled (46), below a temperature which would damage the reactor, by evaporative cooling with pressurized hot water (42). Hydrogen for the desulfurizer and the hydrogen reactions may be provided as recycle reformate (28, 28a) or from a mini-CPO (67), or from other sources.

Methods for steam reforming with a red mud catalyst support composition, one method including providing a methane feed and a steam feed to react over the red mud catalyst support composition at increased temperature and increased pressure to produce synthesis gas comprising H.sub.2 and CO, the composition comprising red mud material produced from an alumina extraction process from bauxite ore.

A pulse jet system and method is disclosed. In an example, the pulse jet system includes a combustion chamber, intake ports to deliver combustion agents to the combustion chamber, an expansion chamber to cool a combustion product following combustion of the combustion agents in the combustion chamber, and an exhaust to exit the cooled gas from the expansion chamber. In another example, the pulse jet system includes a combustion chamber with intake ports to deliver combustion agents to the combustion chamber, wherein the combustion chamber is part of a four cycle engine. The pulse jet system also includes an expansion chamber to cool a combustion product following combustion of the combustion agents in the combustion chamber.

The present invention comprises a process for producing hydrogen, wherein in a first stage hydrocarbons are decomposed into solid carbon and into a hydrogen-containing gaseous product mixture, the hydrogen-containing gaseous product mixture, which has a composition in respect of the main components CH4, N2, and H2 of 20% to 95% by volume H2 and 80% to 5% by volume CH4 and/or N2, is discharged from the first stage at a temperature of 50 to 300° C., and this is supplied at a temperature differing from this exit temperature by not more than 100° C. to an electrochemical separation process and, in this second stage, the hydrogen-containing product mixture is separated in the electrochemical separation process at a temperature of 50 to 200° C. into hydrogen having a purity of >99.99% and a remaining residual gas mixture.

The invention is directed to a process to prepare an activated carbon product and a syngas mixture comprising hydrogen and carbon monoxide from a solid torrefied biomass feed comprising the following steps, (i) subjecting the solid biomass feed to a pyrolysis reaction thereby obtaining a gaseous fraction comprising hydrogen, carbon monoxide and a mixture of gaseous organic compounds and a solid fraction comprising of char particles, (ii) separating the solids fraction from the gaseous fraction, (iii) subjecting the gaseous fraction obtained in step (ii) to a continuously operated partial oxidation to obtain a syngas mixture further comprising water and having an elevated temperature and (iv) activating the char particles as obtained in step (ii) to obtain the activated carbon product.

A plant and method for hydrogen purification are provided, which comprise a Swing Adsorption (SA) stage and a recycle of purged gaseous impurities.

Reactors are provided that can include a first set of fluid channels and a second set of fluid channels oriented in thermal contact with the first set of fluid channels. The reactor assemblies can also provide where the channels of either one or both of the first of the set of fluid channels are non-linear. Other implementations provide for at least one of the first set of fluid channels being in thermal contact with a plurality of other channels of the second set of fluid channels. Reactor assemblies are also provided that can include a first set of fluid channels defining at least one non-linear channel having a positive function, and a second set of fluid channels defining at least another non-linear channel having a negative function in relation to the positive function of the one non-linear channel of the first set of fluid channels. Processes for distributing energy across a reactor are provided. The processes can include transporting reactants via a first set of fluid channels to a second set of fluid channels, and thermally engaging at least one of the first set of fluid channels with at least two of the second set of fluid channels.

The present invention is directed to modifications of bitumen and heavy oil upgrading and refining processes to synthesize synthetic crude oil and other valuable synthesized hydrocarbon products in an efficient manner along with the production of commercially valuable co-products from by-products formed by the upgrading process.

Provided are a composition and a manufacturing method of a solid CO.sub.2 sorbent having excellent physical properties and chemical reaction characteristics, particularly having an excellent mid-temperature range activity for a fluidized bed process, for use in collecting a CO.sub.2 source (pre-combustion or pre-utilization) in syngas application fields such as integrated coal gasification combined cycle (IGCC) power systems, synthetic natural gas (SNG) and synthetic liquid fuel (CTL).

A process and apparatus for producing a hydrogen-enriched product and recovering CO.sub.2 from an effluent stream from a hydrogen production process unit are described. The process utilizes a CO.sub.2 recovery system integrated with a PSA system that produces at least two product streams to recover additional hydrogen and CO.sub.2 from the tail gas stream of a hydrogen PSA unit in the hydrogen production process.