C01B2203/042

Biogas upgrading to methanol

A method for upgrading biogas to methanol, including the steps of: providing a reformer feed stream comprising biogas; optionally, purifying the reformer feed stream in a gas purification unit; optionally, prereforming the reformer feed stream together with a steam feedstock in a prereforming unit; carrying out steam methane reforming in a reforming reactor heated by means of an electrical power source; providing the synthesis gas to a methanol synthesis unit to provide a product including methanol and an off-gas. Also, a system for upgrading biogas to methanol.

METHOD OF PRODUCING A HYDROGEN-ENRICHED PRODUCT AND RECOVERING CO2 IN A HYDROGEN PROUCTION PROCESS UNIT

A process and apparatus for producing a hydrogen-enriched product and recovering CO.sub.2 from an effluent stream from a hydrogen production process unit are described. The process utilizes a CO.sub.2 recovery system integrated with a PSA system that produces at least two product streams to recover additional hydrogen and CO.sub.2 from the tail gas stream of a hydrogen PSA unit in the hydrogen production process.

METHOD OF RECOVERING A HYDROGEN ENRICHED PRODUCT AND CO2 IN A HYDROGEN PRODUCTION UNIT

A process and apparatus for producing a hydrogen-enriched product and recovering CO.sub.2 from an effluent stream from a hydrogen production unit are described. The effluent from the hydrogen production unit, which comprises a mixture of gases comprising hydrogen, carbon dioxide, water, and at least one of methane, carbon monoxide, nitrogen, and argon, is sent to a PSA system that produces at least two product streams for separation. The PSA system that produces at least two product streams separates the gas mixture into a high-pressure hydrogen stream enriched in hydrogen, optionally a second gas stream containing the majority of the impurities, and a low-pressure tail gas stream enriched in CO.sub.2 and some impurities. The CO.sub.2-rich tail gas stream is compressed and sent to a CO.sub.2 recovery unit, where a CO.sub.2-enriched stream is recovered. The CO.sub.2-depleted overhead gas stream is recycled to the PSA system that produces at least two product streams.

INCREASING HYDROGEN RECOVERY FROM CO + H2 SYNTHESIS GAS
20170267524 · 2017-09-21 ·

The GTLpetrol Process for Maximum H2 Production. The GTLpetrol process uses a proprietary combination of two stage pressure swing adsorption hydrogen purification plus a C02 condensation removal step to give H2 recoveries in the range of 95% to 98% based on H2+CO from synthesis gas generation.

PROCESS AND APPARATUS FOR THE SEPARATION OF TWO GASEOUS STREAMS EACH CONTAINING CARBON MONOXIDE, HYDROGEN AND AT LEAST ONE ACID GAS
20220233994 · 2022-07-28 ·

A process for separating two gaseous streams, including purifying a first gaseous stream in a first acid gas removal absorber, purifying in a first temperature swing adsorption unit, and then separating at a cryogenic temperature in a separation unit to produce a stream of fluid enriched in carbon monoxide and a stream of fluid enriched in hydrogen, sending a second gaseous stream containing at least carbon monoxide, hydrogen and at least one acid gas to a shift reaction unit, the shifted second stream is purified in a second acid gas removal absorber to remove carbon dioxide and the purified second stream is sent as a feed stream to a pressure swing adsorption unit to produce a hydrogen enriched stream, and sending at least part of the stream enriched in hydrogen from the separation unit as a feed stream to the pressure swing adsorption unit to produce the hydrogen-enriched stream.

Hydrogen Production with Membrane Reformer

A system and method of producing hydrogen, including converting hydrocarbon to methane via steam and pre-reforming catalyst in a pre-reformer, converting the methane to hydrogen and carbon dioxide by steam reforming via a reforming catalyst in a membrane reformer, diffusing through hydrogen through a tubular membrane in the membrane reformer.

HYDROGEN GAS SUPPLY APPARATUS AND HYDROGEN GAS SUPPLY METHOD

A hydrogen gas supply apparatus according to one aspect of the present invention includes a compressor configured to compress hydrogen gas and supply the hydrogen gas compressed to a pressure accumulator which accumulates the hydrogen gas, an adsorption column disposed between the discharge port of the compressor and the pressure accumulator, and configured to include an adsorbent for adsorbing impurities in the hydrogen gas discharged from the compressor, and a plurality of valves disposed at the gas inlet/outlet port side of the adsorption column, being at a discharge port side of the compressor, and configured to be able to seal the adsorption column, wherein the space in the adsorption column is sealed using the plurality of valves such that the inside of the adsorption column is maintained to have a high pressure by the hydrogen gas compressed in the case where the compressor is stopped.

PRODUCTION OF SYNTHESIS GAS FROM GASIFYING AND REFORMING CARBONACEOUS MATERIAL

It is provided a method of converting a carbonaceous material into syngas at a carbon conversion rate of at least 78% comprising gasifying the carbonaceous material in a fluidized bed reactor producing a crude syngas, classifying the crude syngas by particle size and density into a cut sizing device, introducing the classified particle crude syngas into a thermal reformer and reforming the classified crude syngas at a temperature above mineral melting point, producing the syngas.

Separation and Recovery System and Method of Hydrogen from Coke Oven Gas (COG) in Steel Industry
20220168688 · 2022-06-02 ·

The present invention relates to a separation and recovery system and method of hydrogen from a coke oven gas (COG) in a steel industry, and more particularly, to a separation and recovery system and method of hydrogen from a coke oven gas (COG) in a steel industry, the system including a pre-processing unit removing impurities including tar, moisture, oil, hydrogen sulfide, and dusts from the coke oven gas (COG), a membrane separation unit including a polymer separation membrane module to generate a hydrogen concentrated gas stream by membrane-separating the coke oven gas (COG) processed in the pre-processing unit, and an adsorption unit separate and recover the hydrogen by allowing the hydrogen concentrated gas stream to contact an absorbent.

FEED GAS REFORMING SYSTEM AND METHOD OF CONTROLLING THE SAME
20220169500 · 2022-06-02 · ·

A feed gas reforming system is provided. The system includes a reformer configured to receive feed gas and supply water and to produce and discharge mixed gas including hydrogen, a pressure swing absorber (PSA) configured to receive the mixed gas and to refine and discharge hydrogen gas, a feed gas supply unit configured to control the supply amount of feed gas, a supply water supply unit configured to control the supply amount of supply water, a hydrogen gas supply unit configured to control the amount of hydrogen gas, and a control unit configured to control the flow rate of hydrogen gas, to control the feed gas supply unit based on the pressure of the discharged hydrogen gas, and to control the supply water supply unit based on the flow rate of feed gas.