The disclosure relates to systems and methods for the production of hydrogen (H.sub.2) from ammonia (NH.sub.3) in a membrane reactor that include using ammonia as a sweep gas. Ammonia is converted to hydrogen and nitrogen (N.sub.2), and the hydrogen is separated from the nitrogen and unreacted ammonia by passing the hydrogen through a hydrogen-permeable membrane while using ammonia as a sweep gas. The ammonia sweep gas can be separated from the permeated hydrogen and continuously recycled.

The invention relates to a method for treating a mixture in order to separate carbon dioxide and hydrogen from said mixture, in which: i) the mixture is cooled and partially condensed and a first liquid is separated from the rest of the mixture in a first phase separator; ii) a gas from or derived from a gas from the first phase separator is treated in a hydrogen pressure swing adsorption module in order to produce a hydrogen-rich gas and a hydrogen-depleted residual gas; and iii) said hydrogen-depleted residual gas or a gas derived from said depleted gas is cooled and partially condensed and a second liquid is separated from the remaining gas in a second phase separator, separate from the first phase separator, wherein the first and/or second liquid being rich in carbon dioxide. The invention also relates to an installation for implementing such a method.

The disclosure relates generally to methods and systems for manufacturing ammonia, ammonium sulfate, nitric acid, ammonium nitrate, or combinations thereof, and particularly to clean and efficient methods and system configurations for manufacturing ammonia, ammonium sulfate, nitric acid, ammonium nitrate, or combinations thereof using coal, petcoke, asphaltenes and/or hydrocarbon waste products.

A molten carbonate fuel cell-powered system for capturing carbon dioxide produced by a steam methane reformer system. Tail gas from a pressure swing adsorption system is mixed with exhaust gas from the fuel cell anode, then pressurized and cooled to extract liquefied carbon dioxide. The residual low-CO.sub.2 gas is directed to an anode gas oxidizer, to the anode, to the reformer to be burned for fuel, and/or to the pressure swing adsorption system. Low-CO.sub.2 flue gas from the reformer can be vented to the atmosphere or directed to the anode gas oxidizer. Reduction in the amount of CO.sub.2 reaching the fuel cell allows the fuel cell to be sized according to the power demands of the system and eliminates the need to export additional power output.

A process for producing and purifying a synthesis gas stream that contains CO- and H.sub.2-produced from a hydrocarbon-containing feed in a gas production unit. CO.sub.2 is separated from the synthesis gas stream and CO is cryogenically separated from the synthesis gas stream. CO.sub.2 that makes up 5% to 30% by volume in the synthesis is reduced to less than 10 ppm by volume by temperature swing adsorption. The temperature swing adsorption takes place upstream of the cryogenic separation of CO. The CO.sub.2 is adsorbed using a disordered adsorbent bed wherein the adsorbent is cooled by means of indirect heat transfer from the adsorbent to the heat transfer medium during adsorption and the adsorbent loaded with CO.sub.2 is heated by indirect heat transfer from the heat transfer medium to the adsorbent to effect desorption of CO.sub.2.

A method for separating hydrogen and nitrogen from a gas mixture, including a) thereby partially condensing a hydrogen and nitrogen gas mixture and producing a two-phase stream, b) phase separating the two-phase stream, producing a nitrogen-enriched liquid fraction and a hydrogen-enriched gaseous fraction, c) expanding the nitrogen-enriched liquid fraction, producing a lower-pressure nitrogen-enriched liquid or two-phase stream, d) adding heat to the lower-pressure nitrogen-enriched liquid stream, producing a warm nitrogen enriched gaseous stream, and e) adding heat to the hydrogen-enriched gaseous fraction, producing a hydrogen-rich product stream. Wherein, at least a portion of the heat added in step d) is removed in step a), at least a portion of the heat added in step e) is removed in step a), or at least a portion of the heat added in step d) and at least a portion of the heat added in step e) is removed in step a).

Provided is a method for reusing an adsorbent which can stably exhibit purification ability by regenerating a used absorbent, in order to keep the composition of a purified syngas constant. The present invention concerns a method for regenerating a zeolite adsorbent which adsorbs a carbon dioxide gas from a syngas comprising the carbon dioxide gas and reduces the concentration of the carbon dioxide gas in the syngas, comprising: a step of recovering a used zeolite adsorbent; a step of calcining the used zeolite adsorbent at a temperature of 300? C. to 600? C. in an oxygen atmosphere to produce a regenerated zeolite adsorbent; and a step of reusing the regenerated zeolite adsorbent.

A process for producing methanol includes the following steps (a) reacting, via a catalytic partial oxidation (CPO) reaction, a CPO reactant mixture (hydrocarbon, oxygen, and optionally steam) in a CPO reactor to produce syngas including H.sub.2, CO, CO.sub.2, H.sub.2O, and unreacted hydrocarbons; and wherein the CPO reactor includes a CPO catalyst; (b) introducing the syngas to a methanol reactor to produce a methanol reactor effluent stream (methanol, water, hydrogen, carbon monoxide, carbon dioxide, and hydrocarbons); and (c) separating the methanol reactor effluent stream into a crude methanol stream, a hydrogen stream, a CO.sub.2 stream, and a purge gas stream. The crude methanol stream comprises includes methanol and water; wherein the purge gas stream includes carbon monoxide and hydrocarbons; and the CO2 stream includes at least a portion of the CO2 of the methanol reactor effluent stream; and (d) recycling at least a portion of the CO2 stream to the CPO reactor.

A method of producing hydrogen from a hydrocarbon feedstock is provided. Wherein, at least a portion of a fuel stream comprises a superheated ammonia stream. And, at least: a first portion of a hydrogen-rich stream is combined with a shifted syngas stream prior to introduction into a pressure swing adsorber, a second portion of the hydrogen-rich stream is combined with the fuel stream prior to introduction into a steam methane reformer, and/or a third portion of the hydrogen-rich stream is combined with a hydrocarbon containing feedstock stream and a steam stream prior to introduction into a feed pre-heater. Heat integration between the ammonia vaporization and superheating steps is employed to cool process streams to minimize and even eliminate a dedicated cryogenic refrigeration system.

In a process for separating a mixture containing carbon monoxide, hydrogen and carbon dioxide, the mixture cooled in a heat exchanger is contacted by a stream of liquid methanol at a temperature below ?40? C. to produce carbon dioxide enriched methanol and a carbon dioxide depleted gas relative to the cooled mixture, the carbon dioxide depleted gas is cooled in the heat exchanger and is sent to a separation unit to produce a carbon monoxide enriched stream and a hydrogen enriched stream and the streams enriched in carbon monoxide and hydrogen are heated in the heat exchanger by exchanging heat with the mixture.