Patent classifications
C01B2203/061
PROCESS AND PLANT FOR PRODUCING METHANOL FROM SUBSTOICHIOMETRIC SYNTHESIS GAS
Proposed is a process for producing methanol from synthesis gas by means of multi-stage, for example two-stage, heterogeneously catalyzed methanol synthesis, wherein the methanol product formed in every synthesis stage is separated by condensation and the remaining residual gas is supplied to the downstream synthesis stage or after separation of a purge stream recycled to the first synthesis stage as a recycle stream. According to the invention after each synthesis stage the residual gas streams have separated from them a respective purge stream, from which, using one or more hydrogen recovery apparatuses, hydrogen is separated and recycled to the first synthesis stage. The ratio of the individual purge streams and their total molar flow may optionally be varied to allow better control of the reaction in the individual synthesis stages and to allow reaction to the advancing deactivation of the catalysts present therein.
GASIFICATION OF DENSIFIED TEXTILES AND SOLID FOSSIL FUELS TO PRODUCE ORGANIC COMPOUNDS
Densified textile aggregates are co-fed with a fuel into a partial oxidation gasifier. High solids concentrations in the feedstock composition can be obtained without significant impact on the feedstock composition stability and pumpability. A consistent quality of syngas can be continuously produced, including generation of carbon dioxide and a carbon monoxide/hydrogen ratio while stably operating the gasifier and avoiding the high tar generation of fluidized bed or fixed bed waste gasifiers and without impacting the operations of the gasifier. The syngas quality, composition, and throughput are suitable for produce a wide range of chemicals.
METHOD FOR OPERATING A CHEMICAL PLANT
A chemical plant and operating method therefor; the chemical plant comprises a steam turbine having a shaft, a first pressure turbine stage and a second pressure turbine stage, each being arranged on the shaft and being connected in series in terms of the steam process; steam for driving the steam turbine is obtained from a reactor plant, said reactor plant producing a hydrogen-containing substance from a carbon-containing energy-carrier stream; the steam is heated in an overheating step before being supplied to the second pressure turbine stage; the steam turbine has a third pressure turbine stage which is arranged on the shaft and which is connected between the first pressure turbine stage and the second pressure turbine stage in terms of the steam process; and the steam passes through the overheating step after exiting the third pressure turbine stage.
PRODUCTION OF RENEWABLE FUELS AND ENERGY BY STEAM/CO2 REFORMING OF WASTES
This invention relates to a power recovery process in waste steam/CO.sub.2 reformers in which a waste stream can be made to release energy without having to burn the waste or the syngas. This invention in some embodiments does not make use of fuel cells as a component but makes use of exothermic chemical reactors using syngas to produce heat, such as Fischer-Tropsch synthesis. It also relates to control or elimination of the emissions of greenhouse gases in the power recovery process of this invention with the goal of producing energy in the future carbonless world economy.
PRODUCTION OF SYNTHESIS GAS AND OF METHANOL
A system having a catalytic partial oxidation (CPO) reactor to produce, from a CPO reactant mixture, a CPO reactor effluent characterized by a hydrogen to carbon monoxide (H2/CO) molar ratio and a M ratio defined as (H2−CO2)/(CO+C=2). The system includes a water-gas shift (WGS) reactor configured to produce a hydrogen enriched reactor effluent from at least a portion of the CPO reactor effluent, wherein the hydrogen enriched reactor effluent is characterized by a H2/CO molar ratio that is greater than the H2/CO molar ratio of the CPO reactor effluent. The system includes a CO2 separator operable to remove a portion of the CO2 from the hydrogen enriched reactor effluent to yield the syngas, wherein the syngas is characterized by a M ratio that is greater than the M ratio of the CPO reactor effluent and of the hydrogen enriched reactor effluent. Processes for producing the syngas and producing methanol therefrom are also provided.
METHANOL PRODUCTION SYSTEM AND METHANOL PRODUCTION METHOD
A methanol production system of the present disclosure includes: a reformer including a reaction furnace configured to reform methane in a raw material gas to produce a reformed gas containing CO and H.sub.2; a reduced-gas generator configured to reduce CO.sub.2 to produce a reduced gas containing CO; and a methanol-containing gas generator configured to produce a methanol-containing gas which contains methanol from a reformed gas produced in the reaction furnace and a reduced gas produced in the reduced-gas generator.
Blends of low carbon and conventional fuels with improved performance characteristics
The present invention provides a blended fuel and methods for producing the blended fuel, wherein a low carbon fuel derived from a renewable resource such as biomass, is blended with a traditional, petroleum derived fuel. A blended fuel which includes greater than 10% by volume of low carbon fuel has an overall improved lifecycle greenhouse gas content of about 5% or more compared to the petroleum derived fuel. Also, blending of the low carbon fuel to the traditional, petroleum fuel improves various engine performance characteristics of the traditional fuel.
Chemical plant with a reforming section and a process for producing a chemical product
The invention relates to a chemical plant comprising a reforming section arranged to receive a feed gas comprising hydrocarbons and provide a synthesis gas, wherein the reforming section comprises: an electrically heated reforming reactor housing a first catalyst, said electrically heated reforming reactor being arranged for receiving said feed gas and generating a first synthesis gas; and an autothermal reforming reactor downstream said electrically heated reforming reactor, said autothermal reforming reactor housing a second catalyst, said autothermal reforming reactor being arranged for receiving said first synthesis gas and outputting a second synthesis gas, wherein said reforming section is arranged to output said output synthesis gas comprising said second synthesis gas. The invention also relates to a process for producing a chemical product from a feed gas comprising hydrocarbons, in a chemical plant according to the invention.
POLYMERS, ARTICLES, AND CHEMICALS MADE FROM HIGH CONCENTRATED RECYCLE DERIVED SYNGAS
High concentrations of recycle polymer are gasified in a partial oxidation gasifier to make a syngas useful to make a variety of chemicals and polymers, such as cellulose ester. Polymers such as cellulose esters can be made that are obtained from sustainable sources, recycle sources, and are biodegradable. Circularity in the manufacture of textiles and/or plastics made from the fibers of such cellulose esters can now be achieved. The process of making such a syngas from high concentrations of recycle polymer (e.g. textiles and/or plastics) includes campaigning for the production of syngas.
GREEN METHANOL PRODUCTION
Steam reforming, water separation, and hydrogen separation by membrane can be performed sequentially on a mixture of steam and a hydrocarbon. A hydrogen-rich permeate stream from the hydrogen membrane can be used as fuel for combustion heating, leaving a retentate mixture of a prescribed ratio of hydrogen to oxides of carbon. The retentate can be compressed and synthesized to methanol in a methanol synthesis reactor. The synthesized methanol can be separated into a methanol-rich stream and a tail gas stream containing the remaining outlet gas from the synthesis reactor. The methanol-rich stream can be refined. The tail gas stream can be divided into a methanol loop recycle stream, an SMR recycle stream, and a nitrogen purge stream. The methanol loop recycle stream is compressed and recycled to the methanol synthesis reactor. The SMR recycle stream is recycled as feedstock to the reformer. The nitrogen purge stream is combusted in a burner. Carbon dioxide may be separated from combustion products and sequestered.