A carbon capture system includes a hydrogen production module. The hydrogen production module is used to control the amount of hydrogen entering an internal combustion engine to reduce an amount of water vapor generated by the internal combustion engine, thereby increasing the efficiency of the carbon capture device. If too much water vapor is detected in an exhaust of the engine, the amount of hydrogen produced by a hydrogen production module can be increased, thereby reducing the amount of hydrogen entering the engine and reducing the amount of water vapor generated by the engine. A reformer catalyst can be used by the hydrogen production module to remove at least a portion of hydrogen in a fuel stream of the engine.

A system includes a digestion system configured to convert a digestate into a fuel gas, and a fuel cell power system configured to convert the fuel gas into power and heat, and to provide the heat to the digestion system.

The present invention relates to energy storage systems and reactors useful in such systems. Inventive reactors comprise a reaction vessel defining an inner volume and a compensation element, whereby said inner volume is filled with a fixed bed that is essentially free of cavities and that comprises particles of formula (I), FeOx (I), where 0≤x≤1.5; said compensation element is adapted to adjust said inner volume. The reactors are inherently explosion—proof and thus suited for large scale use. The systems are useful for compensating long-term fluctuations observed in production of renewable energy.

Methods and devices and aspects thereof for generating power using PEM fuel cell power systems comprising a rotary bed (or rotatable) reactor for hydrogen generation are disclosed. Hydrogen is generated by the hydrolysis of fuels such as lithium aluminum hydride and mixtures thereof. Water required for hydrolysis may be captured from the fuel cell exhaust. Water is preferably fed to the reactor in the form of a mist generated by an atomizer. An exemplary 750 We-h, 400 We PEM fuel cell power system may be characterized by a specific energy of about 550 We-h/kg and a specific power of about 290 We/kg. Turbidity fixtures within the reactor increase turbidity of fuel pellets within the reactor and improve the energy density of the system.

This invention provides a reversible hydrogen loading and discharging system and a reversible method for loading and discharging hydrogen. The system and the methods of this invention comprise ethylene glycol as a liquid organic hydrogen carrier and at least one transition metal. By reacting ethylene glycol with at least one transition metal; at least one hydrogen molecule and at least one oligoester of ethylene glycol are formed (hydrogen releasing)⋅, and by reacting at least one oligoester of ethylene glycol with at least one transition metal and at least one hydrogen molecule, at least one ethylene glycol is formed (hydrogen loading).

A fuel cell single unit including: a fuel cell element in which an anode layer and a cathode layer are formed so as to sandwich an electrolyte layer; a reducing gas supply path for supplying a gas containing hydrogen to the anode layer; an oxidizing gas supply path for supplying a gas containing oxygen to the cathode layer; and an internal reforming catalyst layer, which has a reforming catalyst for steam-reforming a fuel gas, in at least a part of the reducing gas supply path is provided. An external reformer, which has a reforming catalyst for steam-reforming the fuel gas, is provided upstream of the reducing gas supply path, and the fuel gas partially reformed by the external reformer is supplied to the reducing gas supply path.

An ejector receives steam at a primary inlet and natural gas at a secondary inlet. A computer responds to a signal indicating current in the load of a fuel cell as well as a signal indicating temperature of a steam reformer to move a linear actuator to control a needle that adjusts the size of the steam orifice. Reformate is fed to a separator scrubber which cools the reformate to its dew point indicated by a sensor. From that, a controller generates the fuel/carbon ratio for display and to bias a signal on a line regulating the amount of steam passing through an ejector to the inlet of the reformer. Alternatively, the reformate may be cooled to its dew point by a controllable heat exchanger in response to pressure and temperature signals.

Hydrogen-producing fuel processing systems and related methods. The systems include a hydrogen-producing region configured to produce a mixed gas stream from a feedstock stream, a hydrogen-separation membrane module having at least one hydrogen-selective membrane and configured to separate the mixed gas stream into a product hydrogen stream and a byproduct stream, and an oxidant delivery system configured to deliver an oxidant-containing stream to the hydrogen-separation membrane module in situ to increase hydrogen permeance of the hydrogen-selective membrane. The methods include operating a hydrogen-producing fuel processing system in a hydrogen-producing regime, and subsequently operating the hydrogen-producing fuel processing system in a restoration regime, in which an oxidant-containing stream is delivered to the hydrogen-separation membrane module in situ to expose the at least one hydrogen-selective membrane to the oxidant-containing stream to increase the hydrogen permeance of the at least one hydrogen-selective membrane.

A process and system for generating hydrogen gas are described, in which water is electrolyzed to generate hydrogen and oxygen, and a feedstock including oxygenate(s) and/or hydrocarbon(s), is non-autothermally catalytically oxidatively reformed with oxygen to generate hydrogen. The hydrogen generation system in a specific implementation includes an electrolyzer arranged to receive water and to generate hydrogen and oxygen therefrom, and a non-autothermal segmented adiabatic reactor containing non-autothermal oxidative reforming catalyst, arranged to receive the feedstock, water, and electrolyzer-generated oxygen, for non-autothermal catalytic oxidative reforming reaction to produce hydrogen. The hydrogen generation process and system are particularly advantageous for using bioethanol to produce green hydrogen.

A method of operating a solid oxide cell system comprises generating an electrochemical conversion from one of: (i) water steam H.sub.2O(g); and (ii) a mixture comprising water steam H.sub.2O(g) and carbon dioxide CO.sub.2. A quantity of at least one other substance is added into the one of the water steam H.sub.2O(g) and the mixture comprising water steam H.sub.2O(g) and carbon dioxide CO.sub.2. The at least one other substance comprises a hydrocarbon C.sub.mH.sub.n. The quantity of the at least one other substance is converted into a syngas CO+H.sub.2. An endothermic reforming of the mixed-in hydrocarbons occurs by coupling-in waste heat from the electrochemical conversion. The additional quantity of the at least one substance is added compensate for effects of a degradation of the solid oxide cells of the solid oxide cell system. A total quantity of the hydrogen H.sub.2 generated by the solid oxide cell system is kept constant.