Provided is a process for producing a hydrogen-rich synthesis gas stream having reduced carbon dioxide emission by reacting a carbon-containing input gas stream in at least one synthesis gas production stage to produce a raw synthesis gas steam, producing a converted synthesis gas stream by converting the cooled raw synthesis gas steam in a CO conversion plant which includes at least one CO conversion stage, contacting the cooled converted synthesis gas stream in a carbon dioxide absorption column and discharging a first synthesis gas stream and utilizing at least a portion of the second synthesis gas stream depleted in carbon dioxide as a portion of fuel gas or process gas or forms the fuel gas or process gas.

Methods and systems for processing construction and demolition (C&D) materials to produce a product gas stream and/or electricity are disclosed herein. In some embodiments, the method comprises pre-processing C&D materials to produce a C&D feed, and processing the C&D feed to produce syngas. The C&D feed can comprise untreated wood, treated wood, paper and cardboard, yard waste, plastic, rubber, and/or foam. Processing the C&D feed can comprise gasifying the C&D feed, steam, and oxygen in a gasifier at a temperature of no more than 950 C. and/or a pressure of no more than 200 psi to produce syngas.

An operating method is disclosed for a dehydrogenation reaction system. The method includes providing a system having: an acid aqueous solution tank including an acid aqueous solution; a dehydrogenation reactor including a chemical hydride of a solid state and receiving an acid aqueous solution from the acid aqueous solution tank to react the chemical hydride with the acid aqueous solution to generate hydrogen; and a fuel cell stack receiving hydrogen generated from the dehydrogenation reactor to be reacted with oxygen to generate water and simultaneously to generate electrical energy. The method also includes recycling the water generated from the fuel cell stack to one or all of the acid aqueous solution tank, the dehydrogenation reactor, and a separate water tank. The acid is formic acid and, in in the dehydrogenation reactor, the temperature is in a range of 10 C. to 400 C. and the pressure is in a range of 1 bar to 100 bar.

Steam reforming system having a steam cracker and a steam reformer. The steam cracker includes a steam cracking unit to steam crack a feed stream to produce a stream comprising hydrogen, methane and C2+ hydrocarbons; a heat exchanger for cooling the steam cracking product stream; a separation unit for separating the cooled steam cracking product stream into a gas stream including hydrogen and methane and a liquid stream including methane and C2+ hydrocarbons, a demethanizer which is fed the liquid stream producing a third stream containing at least 95% methane and a fourth stream comprising C2+ hydrocarbons. The steam reformer includes a feed preheater which is fed the third stream and steam to provide a preheated stream and a steam reforming unit arranged for heating the preheated stream to at least 800 C. to steam reforming the heated stream and obtain a product stream containing hydrogen and CO.sub.2.

A process for converting carbon dioxide and hydrogen into a product stream comprising carbon monoxide, water and hydrogen by introducing carbon dioxide, hydrogen and oxygen into a reaction vessel, and performing a reverse water gas shift reaction at elevated temperature, wherein (a) no catalyst is present in vessel (b) gas stream comprising carbon dioxide, a hydrogen and an oxygen rich gas stream are introduced into the vessel in separate feed streams, (c) the hydrogen and oxygen rich gas stream being introduced in close vicinity of each other, via burner comprising coaxial channels wherein gases undergo a combustion reaction, providing the heating energy required for the reverse water-gas shift reaction; and (d) the temperature in vessel is in the range of 1000 to 1500? C. by varying the molar ratio of hydrogen to oxygen. It is useful in reducing the carbon footprint of certain industrial technologies, and in production of synthesis gas.

A method for providing hydrogen gas includes the process steps pre-heating of an at least partially hydrogenated hydrogen carrier material, release of hydrogen gas by at least partial dehydrogenation of the hydrogen carrier material, purification of the released hydrogen gas as well as cooling and conditioning of the at least partially dehydrogenated hydrogen carrier material.

A system for the pyrolysis of a pyrolysis feedstock utilizes a pyrolysis reactor for producing pyrolysis products from the pyrolysis feedstock to be pyrolyzed. An eductor condenser unit in fluid communication with the pyrolysis reactor is used to condense pyrolysis gases. The eductor condenser unit has an eductor assembly having an eductor body that defines a first flow path with a venturi restriction disposed therein for receiving a pressurized coolant fluid and a second flow path for receiving pyrolysis gases from the pyrolysis reactor. The second flow path intersects the first flow path so that the received pyrolysis gases are combined with the coolant fluid. The eductor body has a discharge to allow the combined coolant fluid and pyrolysis gases to be discharged together from the eductor. A mixing chamber in fluid communication with the discharge of the eductor to facilitates mixing of the combined coolant fluid and pyrolysis gases, wherein at least a portion of the pyrolysis gases are condensed within the mixing chamber.

A molten carbonate fuel cell-powered system for capturing carbon dioxide produced by a steam methane reformer system. Tail gas from a pressure swing adsorption system is mixed with exhaust gas from the fuel cell anode, then pressurized and cooled to extract liquefied carbon dioxide. The residual low-CO.sub.2 gas is directed to an anode gas oxidizer, to the anode, to the reformer to be burned for fuel, and/or to the pressure swing adsorption system. Low-CO.sub.2 flue gas from the reformer can be vented to the atmosphere or directed to the anode gas oxidizer. Reduction in the amount of CO.sub.2 reaching the fuel cell allows the fuel cell to be sized according to the power demands of the system and eliminates the need to export additional power output.

The present disclosure provides a process for forming a biogenic carbon-based fuel or a fuel intermediate from biogenic carbon dioxide and hydrogen. At least a portion of the biogenic carbon dioxide and hydrogen is subjected to a reverse water gas shift reaction that produces at least carbon monoxide. The carbon monoxide so produced, the biogenic carbon dioxide and the hydrogen are introduced, together or separately, to a biologic or chemical conversion process to produce the fuel or fuel intermediate.

A process for forming a fuel or a fuel intermediate using three fermentations includes treating a feedstock to obtain a fermentable carbohydrate, conducting a first fermentation to ferment the fermentable carbohydrate to fermentation product, obtaining biogas produced from a second fermentation that includes anaerobic digestion, and conducting a third fermentation to ferment a gas to produce fermentation product, where the gas contains one or more components obtained or derived from the biogas. An aqueous stream containing fermentation product produced in the third fermentation is used within the process.