A clean energy system, a renewable energy system or a zero emission energy system (ZEES) to utilize CO.sub.2 waste. The energy system may include a fuel processor, an energy catalytic reactor, and a power generator. The fuel processor may catalytically convert the CH.sub.4 component in the natural gas, biogas or syngas into a reformate including H.sub.2, CO, CO.sub.2 and H.sub.2O species. The energy reactor may convert the reformate in gas form into a liquid fuel. The power generator may generate power using an output of the fuel processor and/or an output of the energy reactor.

In various aspects, systems and methods are provided for integration of molten carbonate fuel cells with a Fischer-Tropsch synthesis process. The molten carbonate fuel cells can be integrated with a Fischer-Tropsch synthesis process in various manners, including providing synthesis gas for use in producing hydrocarbonaceous carbons. Additionally, integration of molten carbonate fuel cells with a Fischer-Tropsch synthesis process can facilitate further processing of vent streams or secondary product streams generated during the synthesis process.

In various implementations, feed streams that include methane are reacted to produce synthesis gas. The synthesis gas may be further processed to produce ultrapure, high-pressure hydrogen streams.

Provided herein is process of obtaining hydrogen from a blue hydrogen production facility that meets a target carbon intensity (CI.sub.T), the process comprising: generating hydrogen from non-renewable feedstock; capturing and sequestering fossil CO.sub.2 derived from the non-renewable feedstock; and at least partially powering hydrogen production with renewable electricity, the renewable electricity being derived from biomass in which biogenic carbon produced therefrom (e.g., carbon dioxide, char and the like) is captured and sequestered; and wherein the use of the renewable electricity in the hydrogen production allows the carbon intensity of the hydrogen produced therefrom to be reduced sufficiently so that the target carbon intensity (CI.sub.T) is achieved.

A process and system for generating hydrogen gas are described, in which water is electrolyzed to generate hydrogen and oxygen, and a feedstock including oxygenate(s) and/or hydrocarbon(s), is non-autothermally catalytically oxidatively reformed with oxygen to generate hydrogen. The hydrogen generation system in a specific implementation includes an electrolyzer arranged to receive water and to generate hydrogen and oxygen therefrom, and a non-autothermal segmented adiabatic reactor containing non-autothermal oxidative reforming catalyst, arranged to receive the feedstock, water, and electrolyzer-generated oxygen, for non-autothermal catalytic oxidative reforming reaction to produce hydrogen. The hydrogen generation process and system are particularly advantageous for using bioethanol to produce green hydrogen.

Hydrogen-fueled gas turbine power system comprising a compressor (22), a combustor (24) and a turbine (26) as well as a fuel supply device (10). The fuel supply device (10) has the form of a hydrogen gas producing reactor system with at least one reactor (12) based on sorption enhanced steam methane reforming (SE-SMR) and/or sorption enhanced water gas shift (SE-WGS) of syngas. The reactor (12) is connected in a closed loop with a regenerator (14) for circulating and regenerating a CO.sub.2 absorber between the reactor (12) and the regenerator (14). Additionally, there is a closed heat exchange loop (21) between the regenerator (14) of the hydrogen gas producing reactor system (10) and the downstream end of the combustor (24) or the upstream end of the turbine (26). A method of its use is also contemplated.

A method of producing hydrogen and sequestering carbon or sulfur includes generating a fluid including at least one of water, steam, hydrogen sulfide, carbon dioxide and heat as a byproduct of a surface facility and injecting the fluid into a subsurface formation. The subsurface formation can include a porous rock, in various forms of porosity such as intragranular, intergranular, fracture porosity. The method can further include heating the fluid to stimulate an exothermic reaction of the fluid with components of the subsurface rock formation and produce a hydrogen reaction product and one or more of sulfur minerals from the hydrogen sulfide or carbon minerals from the carbon dioxide. The fluid can be heated to between about 25 C. and about 500 C. The method can also include extracting the hydrogen produced from the reaction of the fluid with the subsurface rock formation and mineralizing at least one of the sulfur or carbon in the porous rock.

A method of generating hydrogen in a subsurface formation, the method comprising injecting oxidizable metal particles into a subsurface formation comprising subsurface water and a geologic trap, wherein the subsurface water has a temperature of from 18 C. to 400 C. and a pressure of from 500 psi to 10,000 psi, the geologic trap comprises one or both of a structural trap or a stratigraphic trap, the geologic trap substantially prevents vertical migration of the subsurface water out of the subsurface formation, and the oxidizable metal particles react with the subsurface water to form hydrogen, metal oxides, metal hydroxides, or combinations thereof.

A plant for the production of synthetic fuels, in particular jet fuel (kerosene), crude petrol and/or diesel, includes: a) a synthesis gas production unit for the production of a raw synthesis gas from methane, water and carbon dioxide, the synthesis gas production unit having at least one reaction section in which methane, water and carbon dioxide react to form the raw synthesis gas, and at least one heat generation section in which the heat necessary for the reaction of methane and carbon dioxide to produce the raw synthesis gas is generated by burning fuel to form flue gas, b) a separation unit for separating carbon dioxide from the raw synthesis gas produced in the synthesis gas production unit, c) a Fischer-Tropsch unit for the production of hydrocarbons by a Fischer-Tropsch process from the synthesis gas from which carbon dioxide has been separated in the separation unit, and d) a refining unit for refining the hydrocarbons produced in the Fischer-Tropsch unit into synthetic fuels,
the plant further comprising e .sub.1) a separation unit for separating carbon dioxide from the flue gas discharged from the synthesis gas production unit via the flue gas discharge line and/or e .sub.2) a flue gas return line which is connected to the heat generation section of the synthesis gas production unit, wherein i) the carbon dioxide separated from flue gas or the flue gas itself via the flue gas return line and ii) the carbon dioxide separated from the raw synthesis gas are either fed directly to the synthesis gas production unit or first fed to a carbon dioxide compression unit and from there fed to the synthesis gas production unit, with the unit also having an electrolysis unit for separating water into hydrogen and oxygen, wherein the electrolysis unit has a water feed line, an oxygen discharge line and a hydrogen discharge line, and wherein from the oxygen discharge line a line leads into the oxygen-containing gas feed line to the synthesis gas production unit.

A system and method for oxygen transport membrane enhanced Integrated Gasifier Combined Cycle (IGCC) is provided. The oxygen transport membrane enhanced IGCC system is configured to generate electric power and optionally produce a fuel/liquid product from coal-derived synthesis gas or a mixture of coal-derived synthesis gas and natural gas derived synthesis gas.