Improved methods for the removal of heavy metals, in particular cadmium, from an aqueous phosphoric acid containing composition, wherein an organothiophosphorous heavy metal precipitating agent and an ionic polymeric surfactant, particularly a cationic polyacrylamide copolymer surfactant, are both added to a phosphoric acid containing composition, particularly under vigorous mixing conditions, such as between 500 and 700 rpm. The ionic polymeric surfactant promotes the precipitation of the heavy metals. More in particular, the phosphoric acid containing composition is obtained by the acid digestion of phosphate rock, preferably by nitric acid, sulfuric acid, or a combination thereof.

The present disclosure relates to bioremediation systems and methods for wastewater treatment in heavy industry, including the mining industry. A benefit of the systems and methods disclosed herein can include the reduction of heavy metals in wastewater. Another benefit can be the treatment of acidic wastewater to achieve higher pH levels. An additional benefit can be the use of carbon dioxide to raise the pH level of acidic wastewater, or to produce feedstocks for the growth of anaerobic or aerobic microorganisms that are capable of reducing a concentration of heavy metals in wastewater. A benefit of the systems and methods herein can include the treatment of acid mining drainage wastewater, as well as heavy metal removal from other industrial wastewater. Another benefit of the methods and systems disclosed herein can include reduction of excess carbon dioxide from the environment.

Contaminate-sequestering coatings including a network of hydrolyzed silane compounds including a plurality of thiol functional groups, a plurality of fluorinated functionalities, or both are provided. The contaminate-sequestering coatings may sequester one or more per- and polyfluoroalkyl substances (PFAS), heavy metals, biological species or any combination thereof. Methods of functionalizing a substrate surface with contaminate-sequestering functionalities that sequester one or more PFAS, heavy metals, or both are also provided. Methods of removing contaminants from contaminate-containing liquids, and devices including the contaminate-sequestering coatings are also provided.

The present disclosure provides a three-dimensional alkynyl-containing porous aromatic framework polymer and a preparation method and use thereof. The polymer has a structure represented by Formula I:

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The preparation method includes: under a protective atmosphere, mixing tetrakis(p-bromophenyl)methane, 1,3,5-triethynyl benzene, a catalyst and an amine solvent, and subjecting to a Sonogashira-Hagihara coupling reaction to obtain the three-dimensional alkynyl-containing porous aromatic framework polymer having the structure represented by Formula I.

A water purification apparatus includes a water intake configured to receive water to the water purification apparatus, a filter part including a plurality of filters configured to filter the water and generate purified water, a water outlet including a plurality of water outlet ports configured to discharge the purified water, and one or more pipes that define a water purification path configured to guide the water from the water intake through at least one of the plurality of filters to thereby provide the purified water to at least one of the plurality of water outlet ports.

A system for treating printed circuit board wastewater (PCB) includes a production system, a pretreatment system, a biochemical system, a recovery system and a concentrated water treatment system. The production system is configured for producing process water and auxiliary water from tap water. The pretreatment system is configured to pretreat different wastewater samples separately. The biochemical system is configured to decompose the pretreated wastewater. The recovery system is configured to treat wastewater from the pretreatment system and the biochemical system to obtain process water and feed concentrated water to the concentrated water treatment system. The concentrated water treatment system is configured to treat the concentrated water to meet a discharge standard. A treatment method for the PCB wastewater is also provided.

A heterogeneous material (e.g., a metal-organic framework or “MOF”) is useful for removing heavy metals from a liquid (e.g., water). The heterogeneous material may incorporate a group 16-containing heterocycle supported on solid media. Thiophene-containing MOFs, such as ATF-1 and DUT-67, may be used to remove lead from water. It is postulated that the metal is adsorbed via non-covalent interactions. The systems and methods described herein may also be applicable to other heavy metals. Thus, the applications are not limited to drinking water purification. Instead, the systems and methods may be used for a broad variety of other applications, such as nuclear waste remediation.

The present disclosure pertains to a system configured to prepare and use prediction models for controlling contaminants of a liquid. Some embodiments may: sense, via a sensor, a magnified image of a sample of the liquid; identify at least one shape in the image; determine a relative predominance of microscopic life forms within at least a portion of the image; and generate a report indicating any required corrective action based on the identification and the determination.

A wastewater processing method includes introducing wastewater into an upper region of a chamber. The chamber remains at substantially atmospheric pressure. A portion of the wastewater in the chamber is vaporized. Flame is introduced into the chamber and provides for the ignition of a volatile organic compound. The vaporized portion of the wastewater is vented to the atmosphere.

Contaminant-sequestering coatings include a network of hydrolyzed silane compounds including (i) a plurality of fluorinated functionalities, and (ii) a plurality of thiol functional groups are provided. The network of hydrolyzed silane compounds includes a fluorinated silane including (a) a hydrophilic polar head region. The polar head region includes one or multiple units of ethylene glycol (EG) functionality, (b) a fluorine-containing region, and (c) an anchor region including a silicon atom. The contaminant-sequestering coatings may sequester one or more per- and polyfluoroalkyl substances (PFAS), heavy metals, biological species, or any combination thereof.