The present invention discloses a lignin-based hierarchical porous carbon with high specific surface area and preparation method and application thereof. The present invention employs maleic anhydride, acrylic acid, and hypophosphorous acid to modify a lignin, then performs a cross-linking reaction with a glutaraldehyde-triethanolamine condensate to prepare a lignin graft-copolymerized by phosphino carboxylic acid copolymer, and then dropwise adding a soluble calcium salt solution and a soluble carbonate solution into the lignin graft-copolymerized by phosphino carboxylic acid copolymer dispersion successively, co-precipitates to prepare a lignin/nano CaCO.sub.3 complex, finally obtains a lignin-based hierarchical porous carbon with high specific surface area through carbonizing at a high temperature. The preparation method of the present invention may enable nano CaCO.sub.3 to be uniformly and stably dispersed in a three-dimensional network structure of the lignin graft-copolymerized by phosphino carboxylic acid copolymer, realizing full and uniform complexation of the lignin with nano CaCO.sub.3.

The disclosure provides a repairing material for emergency treatment of a black and odorous surface water environment and its preparation method, belonging to the fields of environmental science and engineering technology. The preparation method of the disclosure specifically includes the following steps: (1) uniformly stirring activated carbon, calcium chloride, ammonia water solution, polyethylene glycol and water in a stirrer, then dropwise adding hydrogen peroxide, and after the completion of the dropwise adding, obtaining a calcium peroxide repairing material solution; (2) adding a sodium hydroxide solution to the calcium peroxide repairing material solution obtained in step (1) until a pH reaches 11.5, thereby obtaining a suspension; (3) centrifuging the suspension in step (2) to obtain a solid; and (4) washing the solid in step (3) with distilled water until a final pH of residual water reaches 8.4, and then drying the obtained precipitate to obtain the repairing material. The repairing material of the disclosure has good treatment effect and high efficiency.

A method of degrading 1,4-dioxane in the wastewater produced during the manufacture of alkyl ether sulfates is disclosed. The method includes the steps of (a) mixing from 100 to 10,000 ppm, preferably 1,000 to 4,000 ppm of ozone with the wastewater; (b) introducing H.sub.2O.sub.2 into the wastewater in an amount of 0.01 to 10, preferably 0.1 to 0.5 molar equivalents of H.sub.2O.sub.2 to ozone, and (c) mixing the ozone, H.sub.2O.sub.2, and wastewater to generate hydroxyl radicals reactive with the 1,4-dioxane, without the addition of a metal catalyst. The hydroxyl radicals react with the 1,4-dioxane and degrade it into carbon dioxide, water and/or carbonate. The method is effective to reduce a concentration of 1,4-dioxane in the wastewater from a range of about 10 ppm to about 1000 ppm of dioxane down to less than 5 ppb of 1,4-dioxane after treatment. The method is also effective for removing hydrocarbon species that may be present in the wastewater.

An alkaline aqueous ferric iron salt solution is disclosed. Generally, the alkaline aqueous ferric iron salt solution comprises ferric ions (Fe.sup.3+), potassium ions (K.sup.+), carbonate ions (CO.sub.3.sup.2−), bicarbonate ions (HCO.sub.3.sup.−), hydroxide ions (OH.sup.−), optionally nitrate ions (NO.sub.3.sup.−). Further, a molar ratio of the potassium ions to the ferric ions is generally at least 5.0. The ferric iron is complexed with carbonate, bicarbonate or both to form a water-soluble complex that is anionic in nature and highly soluble in the alkaline aqueous ferric iron salt solution at pH above 8.5, and a pH of the alkaline aqueous ferric iron salt solution is at least 8.5.

A method and enhancements for the decontamination of water containing one or more PFAS contaminants includes introducing a foaming agent into the water, and injecting a gas through a diffuser and into the water so as to form a plurality of bubbles in the water, the one or more PFAS contaminants accumulating on the plurality of bubbles. The plurality of bubbles is allowed to rise, forming a foam at the surface of the water. The resulting foam is then collected and transported away from the surface of the water, where it condenses into a liquid and is treated to regulatory standards.

A treatment system and method for cephalosporin wastewater are disclosed. The treatment system includes: a flocculation and sedimentation device, an alkali reaction tank, a PAC reaction tank, a PAM reaction tank, a wastewater heat exchanger, a wastewater heater and an oxidation reactor that are connected with each other in sequence, wherein the wastewater heat exchanger is provided with a material inlet, a material outlet, a heat source inlet and a heat source outlet. An oxidized water from the oxidation reactor enters the wastewater heat exchanger from the heat source inlet, the heat source outlet is connected with a product canister, the product canister is connected with a membrane filtration device to realize concentration treatment of a landfill leachate, the material inlet is connected with the PAM reaction tank, and the material outlet is connected with the wastewater heater. An outer side of the oxidation reactor is provided with a micro-interfacial generation system for dispersing and breaking a gas into bubbles. The treatment system of the prevent invention improves the contact of reaction phase interfaces after arranging the micro-interfacial generation system, which ensures a good wastewater treatment effect under relatively mild operating conditions.

The present invention relates to a bio-assisted method for treatment of spent caustic by treating with haloalkaliphilic consortium of bacteria capable of reducing or transforming sulphides, thiols, mercaptants and other sulphur containing compounds, phenols, hydrocarbons, naphthenic acids and their derivatives in spent caustic.

A membrane sorbent is described, which comprises 1-6 wt % silicon carbide nanoparticles dispersed in a polymer matrix. The polymer matrix may comprise polysulfone and polyvinylpyrrolidone. The membrane sorbent is used for separating oil from a contaminated water mixture. The silicon carbide nanoparticles of the membrane sorbent may be made from rice husk ash.

Methods for removing a soluble heavy metal-sulfur complex from a process solution comprise contacting the process solution with an oxidant to oxidize the heavy metal-sulfur complex and form an oxidized complex precipitate, or with an acid to acidify the heavy metal-sulfur complex and form an acidified complex precipitate, and removing the precipitate from the process solution to provide a heavy metal-reduced solution. The method is advantageous for removing heavy metals such as mercury, cadmium, barium, iron, vanadium and/or manganese from process solutions, for example originating from natural gas production, petroleum production, water treatment or mining.

A method of reducing activity of sulfur and/or nitrogen metabolizing bacteria is provided. The method includes adding a composition of an alkali metal salt of chlorite and/or an alkali metal salt of chlorate and hydrogen peroxide to process water of a cooling tower and increasing a concentration of the composition from about 0 ppm to about 300 ppm in about 1 to about 100 minutes. The method results in significant savings of caustic and reduces sulfur and/or nitrogen metabolizing bacteria in the process water.