Random terpolymers are characterized for being tolerant to high concentrations of divalent ions, such as calcium, magnesium, strontium and barium, and that for their application in the reservoir or production rig, treated water, sea water and/or connate water can be used as means of transportation. Furthermore, the terpolymer also can be used to inhibit and disperse mineral scales presents in cooling system and boiler employed in the chemical and oil industry.

Also, random terpolymers of the present invention have the characteristic of complying with environmental standards established internationally and are classified as particularly non-toxic, so it can be used in pipes and equipment of the petrochemical industry and with the use characteristic freshwater and seawater from offshore and onshore facilities.

An apparatus, system and method to remove purified vapor from a contaminated fluid using solar energy is disclosed. The apparatus comprises an inlet wherein contaminated fluid flows in the apparatus through the inlet; at least two outlets wherein a first outlet exits purified vapor and a second outlet wherein contaminated fluid with a portion removed as purified vapor exits the apparatus; an energy source that causes the contaminated fluid to heat to a temperature wherein at least a portion of the contaminated fluid is converted to purified vapor; at least two different flow paths from at least one inlet to the first outlet and second outlet, the first and second flow paths flow through at least a portion of the apparatus wherein differences causes the lighter purified vapor to take a different path than the contaminated fluid exiting the second outlet.

An apparatus, system and method to remove purified vapor from a contaminated fluid using energy. The apparatus comprises an inlet wherein contaminated fluid flows in the apparatus through the inlet; at least two outlets wherein a first outlet exits purified vapor and a second outlet wherein contaminated fluid with a portion removed as purified vapor exits the apparatus; an energy source that causes the contaminated fluid to heat to a temperature wherein at least a portion of the contaminated fluid is converted to purified vapor; at least two different flow paths from at least one inlet to the first outlet and second outlet, the first and second flow paths flow through at least a portion of the apparatus.

In some embodiments, a method may include reducing the microbial load in contaminated water of water recycle loops. These water recycling loops may include pulp and paper mills, cooling towers and water loops, evaporation ponds, feedstock processing systems and/or non-potable water systems. The methods may include providing a peracetate oxidant solution. The peracetate solution may include peracetate anions and a peracid. In some embodiments, the peracetate solution may include a pH from about pH 10 to about pH 12. In some embodiments, the peracetate solution has a molar ratio of peracetate anions to peracid ranging from about 60:1 to about 6000:1. In some embodiments, the peracetate solution has a molar ratio of peracetate to hydrogen peroxide of greater than about 16:1. The peracetate solution may provide bleaching, sanitizing and/or disinfection of contaminated water and surfaces. The peracetate oxidant solution may provide enhanced separation of microbes from contaminated water.

Embodiments provide methods and structures for purification or volume reduction of a brine by an advanced vacuum distillation process (AVMD) to achieve higher flux by passage of vapors through an AVMD distillation unit. In one example, brine is circulated in a tank. The tank may include one or more membrane pouches that are submerged in the circulating brine or placed above the water level of the hot circulating brine. In other embodiments the membrane pouches are outside of the tank that includes the hot circulating brine but still in communication with it. The circulating brine is heated, allowing creation of water vapor. Using a vacuum, the water vapor is drawn through the membrane, where it may be condensed and subjected to further beneficial use. This process can concentrate to levels to generate crystals or solids, which can be separated and utilized.

Some implementations of the present disclosure prevent, reduce or at least slow equipment fouling using passivation as a treatment prior to contacting metallic components with hydrocarbon containing fluid, that is, an environment where fouling occurs. For example, one implementation includes a method of passivating heat exchangers in a SAGD process or system using the compositions and compounds of the present disclosure. The composition may be applied to a component prior to its first inclusion in an online system or following placing the system offline for maintenance. The composition may be used to treat metallic equipment surface(s), for example, via contacting them with a suspension or solution of the composition described herein, prior placing the system online. The method may further include treatment of the process fluid, for example, via injection or batch treatment of the composition with the compositions described herein into the process fluid.

The present invention is related to the process of obtaining random terpolymers based on itaconic acid or its isomers, aconitic acid or their isomers and sodium alkenyl sulphonates, through a polymerization in aqueous solution, via free radicals at acid pH in the range of 1.0 to 3.5 and as initiator a redox system. The random terpolymers are characterized for being tolerant to high concentrations of divalent ions, such as calcium, magnesium, strontium and barium. Their use as inhibitors of mineral scale such as calcium carbonate, calcium sulphate, strontium and barium, and clay dispersing, iron oxides, carbonate and calcium sulfate allows for their application in the reservoir or production rig, treated water, sea water and/or connate water can be used as means of transportation. The terpolymer can be used to inhibit and disperse mineral scales present in cooling system and boiler employed in the chemical and oil industry, and is compliant with environmental standards established internationally. They are classified as non-toxic, and can be used in pipes and equipment in the petrochemical industry and transporting freshwater and seawater from offshore and onshore facilities.

A method of inhibiting carbonate scale in an industrial water system includes the steps of dosing the industrial water system with a water treatment polymer comprising at least 60 mol % of carboxylic acid monomer and a quaternized naphthalimide fluorescent monomer as disclosed herein, and then monitoring the fluorescence of the water system. If both maleic acid and phosphino moieties are included in the water treatment polymer, then the maleic acid is present as no greater than 70 mol % of the water treatment polymer. If the polymer contains a sulfonic acid monomer, the polymer is a fluorescence efficient polymer.

The present invention is a method for removing a biofilm containing a metal and formed in a water system, wherein the biofilm is brought into contact with (a) a compound having a hydroxyl radical generation ability and (b) a reducing agent.

An efficient electrochemical pre-scaling water treatment device is disclosed. The device comprises an enclosed box, wherein anode positioning connecting shafts, anode plates, cathode plates and scrapers are distributed in a length direction of the closed box, the scrapers are fixed to a scraper holder, the anode plates are fixed to the anode positioning connecting shafts, and the cathode plates are fixed to a central shaft; the anode positioning connecting shafts, the scraper holder and the central shaft are fixed on the enclosed box; in the width direction of the enclosed box, a water inlet is provided at a first side of the enclosed box, a water outlet and a sewage outlet are provided at a second side of the enclosed box, and exhaust holes are provided at a top of the enclosed box.