A liquid treatment device that achieves an effective treatment by forcibly contacting a swirl flow of a hydrogen peroxide-containing treated liquid with a liquid to be treated that has been processed to contain copper ions or iron ions includes a rod-like first electrode, a plate-like second electrode formed of a copper- or iron-containing metal, and a first treatment vessel that causes a liquid to swirl and generate a gas phase in a swirl flow of the liquid. A pulse voltage is applied to the generated gas phase to generate a plasma. The second electrode serves as an anode, and reaches inside of a supply section for a liquid to be treated. The liquid to be treated containing the generated copper ions or iron ions is forcibly brought into contact with hydrogen peroxide generated by the plasma. In this way, the Fenton's reaction effectively takes place, and the liquid treatment performance improves.

A method for preparing a Fenton-like catalytic material with dual reaction centers includes the following steps: (1) placing a nitrogen-containing compound in a muffle furnace for calcination, then dissolving the product in deionized water to form a suspension solution; (2) dissolving aluminum nitrate nonahydrate, copper nitrate trihydrate and glucose in deionized water to form a solution; (3) adding the suspension solution in a dropwise manner to the solution, then performing a closed hydrothermal reaction, washing with water, centrifuging and drying to obtain a solid; and (4) placing the prepared solid in a muffle furnace for calcination to obtain the Fenton-like catalytic material. The catalytic material presents a complete ball-flower shaped mesoporous structure, has a large specific surface area, and can expose more catalytic active sites, so that H.sub.2O.sub.2 is reduced at the electron-rich center as much as possible to generate hydroxyl radicals during the reaction.

The present disclosure discloses a sludge composite conditioner based on iron-containing sludge pyrolysis residue as well as a preparation method and use thereof. The sludge composite conditioner comprises iron-containing sludge pyrolysis residue and an oxidant used in combination with the iron-containing sludge pyrolysis residue, in which the iron-containing sludge pyrolysis residue is pyrolysis residue obtained by dewatering iron-containing sludge to obtain an iron-containing sludge cake and then pyrolyzing the iron-containing sludge cake, the iron-containing sludge being obtained from an advanced oxidation technology involving an iron-containing reagent. In the present disclosure, through improvements of the subsequent overall treatment process, the reuse mode and specific reaction condition parameters of the respective subsequent treatment process steps of the iron-containing sludge cake, the problem of sludge cake treatment and disposal at the end of the existing sludge treatment and disposal technology can be effectively solved compared with the prior art, and then the iron-containing sludge cake is utilized to form a composite conditioner for deep dewatering of sludge, which is recycled as a sludge conditioner for sludge treatment, thereby realizing the full utilization of resources.

A catalyst including an amorphous matrix of a metallic glass including iron and phosphorous; wherein when the catalyst performs a catalytic reaction with a reactant, the metallic glass catalyst activates at least some of the reactant, and at least a portion of the catalyst at a surface of the metallic glass matrix transforms to a surface layer including a material property different from that of the metallic glass matrix being covered by the surface layer; and wherein the surface layer is arranged to maintain an amorphous structure of the metallic glass matrix and to facilitate the catalytic reaction to occur at the surface layer.

A method for deeply processing highly contaminated wastewater having salts and volatile organic compounds includes the steps of: performing mechanical vapor recompression on the wastewater to form a first concentrate liquid and a first condensing liquid; performing drying on the first concentrate liquid to form a waste solid and a second condensing liquid; performing reverse osmosis on the first condensing liquid and the second condensing liquid to form a filtrate and a second concentrate liquid; performing Fenton's oxidation on the second concentrate liquid to form an oxidized liquid; and performing mechanical vapor recompression, drying, reverse osmosis, and Fenton's oxidation as above on the oxidized liquid in sequence. Additionally, active carbon adsorption is optionally performed on the filtrate to form a re-filtrate.

This invention provides for a continuous process for treating a contaminated fluid. The process comprising introducing an oxidizing agent to the contaminated fluid feed, and contacting the contaminated fluid feed with an oxidizing agent activator, wherein the oxidizing agent activator is immobilized on a replaceable permeable reaction barrier.

A droplet-impingement, flow-assisted electro-Fenton (DFEF) catalyst, system, and method can degrade to trace level organic materials, such as -blockers in water. A silica/carbon-x % iron composite (RHS/C-x % Fe) can be made, e.g., from rice husks and iron ions into heterogeneous catalysts of varied iron content. The DFEF approach can improve oxygen saturation, mass transfer of -blockers at the cathode, and continuous electrogeneration of hydroxyl radicals (.OH) in solution and at boron-doped anode surfaces. A central composite design (CCD) can reduce costs and increase efficiency. Beta-blockers can be completely degraded within 15 minutes, following pseudo first-order kinetics with rate constants of 0.19 to 2.7210.sup.2 (acebutolol) and 0.16 to 2.5410.sup.2 (propranolol) at increasing catalyst concentration. Beta-blocker degradation can be mostly by .OH.sub.bulk rather than .OH.sub.adsorbed for anodic oxidation (AO) at BDD electrode. The degradation efficiency of -blockers can be: DFEF>FEF>BEF>AO.

Methods of treating water having organic contaminants are disclosed. The methods include performing a first treatment on the water effective to oxidize a predetermined amount of the organic contaminant and electrochemically treating the water. The methods include introducing a hydrogen peroxide (H.sub.2O.sub.2) containing reagent into the water, allowing the H.sub.2O.sub.2 containing reagent to react with the organic contaminant for a reaction time effective to oxidize a predetermined amount of the organic contaminant, and electrochemically treating the water. Systems for treating water are also disclosed. The systems include an electrochemical cell, a source of an H.sub.2O.sub.2 containing reagent upstream from the electrochemical cell, and a controller operable to regulate a reaction time of the H.sub.2O.sub.2 containing reagent in the water and a potential applied to the electrochemical cell.

Copper-boron-ferrite (CuBFe) composites may be prepared and immobilized on graphite electrodes in a silica-based sol-gel, e.g., from rice husks. Different bimetallic loading ratios can produce fast in-situ electrogeneration of reactive oxygen species, H.sub.2O.sub.2 and .OH, e.g., via droplet flow-assisted heterogeneous electro-Fenton reactor system. Loading ratios of, e.g., 10 to 30 wt. % Fe.sup.3+ and 5 to 15% wt. Cu.sup.2+, can improve the catalytic activities towards pharmaceutical beta blockers (atenolol and propranolol) degradation in water. Degradation efficiencies of at least 99.9% for both propranolol and atenolol in hospital wastewater were demonstrated. Radicals of .OH in degradation indicate a surface mechanism at inventive cathodes with correlated contributions of iron and copper. Copper and iron can be embedded in porous graphite electrode surface and catalyze the conversion of H.sub.2O.sub.2 to .OH to enhance the degradation. Inventive cathodes can be stable catalytically after 20 or more cycles under neutral and acidic conditions.

The present description relates to a method and a system for generating a Fenton reagent. Particularly, the description relates to a method and a system for oxidizing contaminants from wastewater. The Fenton reagent can react with various organic compounds and metallic elements. The method of producing an in-situ Fenton reagent comprises: providing an aqueous solution comprising at least one contaminant; providing at least one column comprising i) an inlet and an outlet separated by a flow chamber, and ii) a mass of iron fibre in the flow chamber between the inlet and the outlet; providing at least one dispenser retaining a hydrogen peroxide generating solid and permitting passage of the aqueous solution through the dispenser; optionally acidifying the solution upstream of the at least one column, and passing the aqueous solution through the at least one column.