Apparatus, systems and methods for refining molten glass include a fining chamber having a refractory floor and a sidewall structure that may include a refractory liner, and includes an inlet transition region having increasing width from initial to a final width, and depth decreasing from an initial to final depth. The floor includes a raised curb having width equal to final width of the inlet transition region, curb length less than the length of the inlet transition region, and curb height forming a shallowest depth portion of the fining chamber. The raised curb separates the fining chamber into the inlet transition region and a primary fining region, the primary fining region defined by the refractory floor and sidewall structure. The primary fining region has a constant depth greater than the shallowest depth but less than the depth of the inlet transition region.

A gas branching apparatus that branches and supplies a gas to first to N-th supply targets, includes first to N-th pipes wherein the first to N-th pipes are each branched into first to N-th branch pipes on a downstream end side, and wherein the i-th branch pipes of the respective first to N-th pipes are connected in common to the i-th supply target, and the i-th branch pipes of the respective first to N-th pipes are provided with valves, respectively, where i denotes each of integers of 1 to N.

Submerged combustion glass manufacturing systems and methods include a melter having a floor, a roof, a wall structure connecting the floor and roof, and one or more submerged combustion burners mounted in the floor, roof, and/or wall structure discharging combustion products including water vapor under a level of material being melted in the melter and create turbulent conditions in the material. The floor, roof, or wall structure may include fluid-cooled refractory material and an optional metallic external shell, or the metallic shell may include coolant passages. One or more conduits drain water condensed from the water vapor from regions of refractory material substantially saturated with the water, and/or from burner supports.

A submerged combustion melter and system are disclosed. The submerged combustion melter includes a bottom wall, at least one side wall extending upwardly from the bottom wall, a crown extending inwardly with respect to the at least one side wall and over the bottom wall to establish a melting chamber, an exhaust port configured to exhaust gas from the melting chamber, at least one baffle extending from the at least one side wall to divide the melting chamber into melting sub-chambers that share the exhaust port, at least one inlet configured for introducing a glass batch into the submerged combustion melter, and at least one outlet configured to remove molten glass from the at least one melting chamber.

The present invention relates to a heat exchanger for the supply of oxygen or of a gas mixture containing at least 50% oxygen, the temperature at the outlet of the exchanger not being below 300° C., it preferably being above 400° C., the oxygen or the oxygen-rich gas feeding one or more burners of a glass melting furnace, the heat of the combustion gases being used directly or indirectly to heat the oxygen or the oxygen-rich gas in the exchanger, in which the exchange power is between 20 and 300 kW, preferably between 40 and 250 kW and particularly preferably between 80 and 170 kW.

A prefmer (28) is described and includes a chamber (34) for receiving molten glass exiting a submerged combustion melter. The prefmer (28) also includes a foam breaker (36) and an exit conduit (38). The molten glass holding chamber includes a top portion (42), a bottom portion (40), and an enclosing sidewall (44). The top portion (42) includes an opening to accommodate the foam breaker (36), which is positioned to break the glass bubbles within the chamber. The exit conduit (38) resides within the chamber (34) and is in fluid communication with an outlet (68) in the sidewall (44) The exit conduit (38) is positioned to permit molten glass to flow from the lower section of the chamber to the outlet (68) and to the next stage of processing, typically a finer.

A method of of fining low-density submerged combustion glass includes introducing unfined molten glass produced in a submerged combustion melter into a fining chamber of a fining tank and, further, introducing additive particles into the fining chamber that comprise a glass reactant material and one or more fining agents. The one or more fining agents are released into the molten glass bath upon consumption of the additive particles in the molten glass bath to chemically fine the molten glass bath and the glass reactant material includes one or more materials that integrate into the molten glass bath upon melting. Additionally, the method includes discharging fined molten glass out of the fining chamber of the fining tank. The discharged fined molten glass has a volume percentage of gas bubbles that is less than the volume percentage of gas bubbles in the unfined molten glass introduced into the fining chamber.

Microspheres comprising a plurality of hollow microspheres, each of the plurality of hollow microspheres comprising a plurality of glass walls, and a plurality of hollow spaces, wherein the plurality of glass walls enclosing at least one of the plurality of hollow spaces, wherein the plurality of glass walls comprising a second glass, wherein the second glass comprising a processed first glass melt, wherein the processed first glass melt comprising a melt of a batch and a plurality of redox active group components capable of providing at least one of a plurality of redox reactions and a plurality of events in the second glass.

Combustion burners, burner panels, submerged combustion melters including the panels, and methods of using the same are disclosed. In certain embodiments, the burner includes an annular liquid cooled jacket defining a central longitudinal through passage. An inner conduit is positioned substantially concentrically within an outer conduit, the latter positioned in the through passage, each conduit comprising proximal and distal ends, the conduits configured so that the outer and inner conduits are movable axially. The inner conduit forms a primary passage and the outer conduit forms a secondary passage between the outer conduit and the inner conduit. In one embodiment the outer conduit has an exterior surface configured along at least a portion thereof with threads mating with adjacent threads on an inner surface of the annular liquid cooled jacket. Other embodiments including lock and release dogs or bolt arrangements. The burners promote burner life and melter campaign length.

The invention relates to a method of making a mineral melt, the method comprising providing a circulating combustion chamber which comprises an upper zone, a lower zone and a base zone, injecting primary particulate fuel and particulate mineral material and primary combustion gas into the upper zone of the circulating combustion chamber, thereby at least partially combusting the primary particulate fuel and thereby melting the particulate mineral material to form a mineral melt and generating exhaust gases, injecting into the lower zone of the circulating combustion chamber, through at least one first burner, secondary combustion gas and gaseous fuel and secondary particulate fuel, wherein the secondary combustion gas and gaseous fuel and secondary particulate fuel are injected via a single first burner, wherein the amount of secondary combustion gas injected via each first burner is insufficient for stoichiometric combustion of the total amount of gaseous fuel and secondary particulate fuel injected via that first burner, and injecting tertiary combustion gas into the lower zone of the circulating combustion chamber, through at least one tertiary combustion gas injector, whereby the tertiary combustion gas enables completion of the combustion of the gaseous fuel and the secondary particulate fuel, separating the mineral melt from the hot exhaust gases so that the hot exhaust gases pass through an outlet in the circulating combustion chamber and the mineral melt collects in the base zone. The invention also relates to apparatus suitable for use in the method.