A method of making a self-supporting inorganic sheet, including: electrostatically depositing a dry inorganic powder on a surface to form an inorganic layer on the surface; and sintering the resulting inorganic layer to form a self-supporting sintered inorganic sheet. The method can additionally include, for example, separating of the self-supporting sintered inorganic sheet from the surface, optionally contacting the separated sintered inorganic sheet with a coupling agent, infiltrating the separated sintered inorganic sheet with a polymer with or without contacting with a coupling agent, or a combination thereof. Also disclosed is a sheet article made by the method.