A sulfide-based solid electrolyte contains a nickel (Ni) element and a halogen element. For example, a sulfide-based solid electrolyte can include, with respect to 100 parts by mole of a mixture of lithium sulfide (Li.sub.2S) and diphosphorus pentasulfide (P.sub.2S.sub.5), 5 parts by mole to 20 parts by mole of nickel sulfide (Ni.sub.3S.sub.2), and 5 parts by mole to 40 parts by mole of lithium halide.

A piezoelectric device having a high conversion efficiency between electrical energy and mechanical energy is provided. The piezoelectric device has first electrode, a second electrode, and a piezoelectric layer provided between the first electrode and the second electrode, wherein the piezoelectric layer is formed of a ZnO-based material having a wurtzite crystal structure to which a metal that does not cause the piezoelectric layer to exhibit conductivity is added, and wherein a squared value of a electromechanical coupling coefficient in thickness vibration mode is 6.5% or more.

An antimicrobial material including a substrate and an antimicrobial mixed metal oxide, mixed metal sulfide, or mixed metal oxysulfide in and/or on the substrate is described, as well as antimicrobial coating materials and coatings formed therefrom. The antimicrobial material may be constituted in an antimicrobial surface of a surface-presenting substrate, to combat transmission and spread of microbial disease, e.g., disease mediated by microbial pathogens such as bacteria, viruses, and fungi. Antimicrobial mixed metal oxide, mixed metal sulfide, or mixed metal oxysulfide as described may be contacted with microorganisms to effect inactivation thereof.

Provided is a sulfide solid electrolyte material which has a composition that does not contain Ge, while having a smaller Li content than conventional sulfide solid electrolyte materials, and which has both lithium ion conductivity and chemical stability at the same time. A sulfide solid electrolyte which has a crystal structure represented by composition formula (Li.sub.3.45+β−4αSn.sub.α)(Si.sub.0.36Sn.sub.0.09)(P.sub.0.55−βSi.sub.β)S.sub.4 (wherein α≤0.67, β≤0.33 and 0.43<α+β (provided that 0.23<α≤0.4 when β=0.2 and 0.13<α≤0.4 when β=0.3 may be excluded)), or a crystal structure represented by composition formula Li.sub.7+γSi.sub.γP.sub.1−γS.sub.6 (wherein 0.1≤γ<0.3).

Provided is a sulfide solid electrolyte material which has a composition that does not contain Ge, while having a smaller Li content than conventional sulfide solid electrolyte materials, and which has both lithium ion conductivity and chemical stability at the same time. A sulfide solid electrolyte which has a crystal structure represented by composition formula (Li.sub.3.45+β−4αSn.sub.α)(Si.sub.0.36Sn.sub.0.09)(P.sub.0.55−βSi.sub.β)S.sub.4 (wherein α≤0.67, β≤0.33 and 0.43<α+β (provided that 0.23<α≤0.4 when β=0.2 and 0.13<α≤0.4 when β=0.3 may be excluded)), or a crystal structure represented by composition formula Li.sub.7+γSi.sub.γP.sub.1−γS.sub.6 (wherein 0.1≤γ<0.3).

The present invention is able to provide an LGPS-based solid electrolyte characterized by: satisfying a composition of Li.sub.uSn.sub.vP.sub.2S.sub.yX.sub.z (6≤u≤14, 0.8≤v≤2.1, 9≤y≤16, 0<z≤1.6; X represents Cl, Br, or I); and having, in X-ray diffraction (CuKα: λ=1.5405 Å), peaks at least at positions of 2θ=19.80°±0.50°, 20.10°±0.50°, 26.60°±0.50°, and 29.10°±0.50°.

The present invention provides an energy storage device comprising a cathode region or other element. The device has a major active region comprising a plurality of first active regions spatially disposed within the cathode region. The major active region expands or contracts from a first volume to a second volume during a period of a charge and discharge. The device has a catholyte material spatially confined within a spatial region of the cathode region and spatially disposed within spatial regions not occupied by the first active regions. In an example, the catholyte material comprises a lithium, germanium, phosphorous, and sulfur (“LGPS”) containing material configured in a polycrystalline state. The device has an oxygen species configured within the LGPS containing material, the oxygen species having a ratio to the sulfur species of 1:2 and less to form a LGPSO material. The device has a protective material formed overlying exposed regions of the cathode material to substantially maintain the sulfur species within the catholyte material. Also included is a novel dopant configuration of the Li.sub.aMP.sub.bS.sub.c (LMPS) [M=Si,Ge, and/or Sn] containing material.

Disclosed is a plastic semiconductor material and a preparation method thereof. The semiconductor material comprises an argentite-based compound represented by the following formula (I): Ag.sub.2-δX.sub.δS.sub.1-ηY.sub.η(I), in which 0≤δ<0.5, 0≤η<0.5, X is at least one of Cu, Au, Fe, Co, Ni, Zn, Ti, or V, and Y is at least one of N, P, As, Sb, Se, Te, O, Br, Cl, I, or F. The material can withstand certain deformations, similar to organic materials, and has excellent semiconductor properties with adjustable electrical properties, thereby enabling the preparation of high-performance flexible semiconductor devices.

The present invention relates to a nitrogen-doped sulfide-based solid electrolyte for all-solid batteries. The a nitrogen-doped sulfide-based solid electrolyte for all-solid batteries includes a compound with an argyrodite-type crystal structure represented by the following Formula 1:

Li.sub.aPS.sub.bN.sub.cX.sub.d  [Formula 1] wherein 6≤a≤7, 3<b<6, 0<c≤1, 0<d≤2, and each X is the same or different halogen atom selected from the group consisting of chlorine (Cl), bromine (Br), and iodine (I).

The present invention relates to a nitrogen-doped sulfide-based solid electrolyte for all-solid batteries. The a nitrogen-doped sulfide-based solid electrolyte for all-solid batteries includes a compound with an argyrodite-type crystal structure represented by the following Formula 1:

Li.sub.aPS.sub.bN.sub.cX.sub.d  [Formula 1] wherein 6≤a≤7, 3<b<6, 0<c≤1, 0<d≤2, and each X is the same or different halogen atom selected from the group consisting of chlorine (Cl), bromine (Br), and iodine (I).