A galleryless steel piston designed to improve thermal efficiency, fuel consumption, and performance of an engine is provided. The piston includes a steel body portion and a thermal barrier layer applied to an upper combustion surface and/or a ring belt to reduce the amount of heat transferred from a combustion chamber to the body portion. The thermal barrier layer has a thermal conductivity which is lower than a thermal conductivity of the steel body portion. The thermal barrier layer typically includes a ceramic material, for example ceria, ceria stabilized zirconia, and/or a mixture of ceria stabilized zirconia and yttria stabilized zirconia in an amount of 90 to 100 wt. %, based on the total weight of the ceramic material. The thermal barrier layer can also have a gradient structure which gradually transitions from 100 wt. % of a metal bond material to 100 wt. % of the ceramic material.

An electrically conductive member of the present disclosure includes a base member containing chromium (Cr), and a first layer provided on a surface of the base member and containing chromium(III) oxide (Cr.sub.2O.sub.3). The first layer also contains titanium (Ti).

This invention relates to a method for manufacturing a part of complex shape (3) by successive deposition of layers according to a technique of 3D additive printing and pressure sintering, comprising the following steps: an initial step of producing a model (1) from a material chosen from a porous or pulverulent material based on a metal alloy, a ceramic, a composite material and a lost material by formation of successive layers deposited according to the digitally controlled 3D additive printing technique, followed by a step of introducing a preform (1) made of porous or pulverulent material to be densified, derived from the model (1), into a mold (2) filled with a sacrificial porous or pulverulent material (13) in addition to the preform (1), the uniaxial densifying pressure sintering (10) then being applied to the mold (2) in order to form the part (3) which is finally extracted from the mold (2).

The present disclosure relates to a precursor solution for the preparation of a ceramic of the BZT-αBXT type, where X is selected from Ca, Sn, Mn, and Nb, and α is a molar fraction selected in the range between 0.10 and 0.90, said solution comprising: 1) at least one barium precursor compound; 2) a precursor compound selected from the group consisting of at least one calcium compound, at least one tin compound, at least one manganese compound, and at least one niobium compound; 3) at least one anhydrous precursor compound of zirconium; 4) at least one anhydrous precursor compound of titanium; 5) a solvent selected from the group consisting of a polyol and mixtures of a polyol and a secondary solvent selected from the group consisting of alcohols, carboxylic acids, ketones, and mixtures thereof; and 6) a chelating agent, as well as method of using the same.

A method of manufacturing an article includes providing a component for an etch reactor. Ion beam sputtering with ion assisted deposition (IBS-IAD) is then performed to deposit a protective layer on at least one surface of the component, wherein the protective layer is a plasma resistant film having a thickness of less than 1000 μm.

A hard material which, when used as a material of a sintered material, makes it possible to obtain a sintered material with excellent abrasion resistance, a sintered material, a cutting tool including the sintered material, a method for manufacturing the hard material and a method for manufacturing the sintered material are provided. The hard material contains aluminum, nitrogen, and at least one element selected from the group consisting of titanium, chromium, and silicon, and has a cubic rock salt structure.

An ink of the formula: 60-80% by weight BaTiO.sub.3 particles coated with SiO.sub.2; 5-50% by weight high dielectric constant glass; 0.1-5% by weight surfactant; 5-25% by weight solvent; and 5-25% weight organic vehicle. Also a method of manufacturing a capacitor comprising the steps of: heating particles of BaTiO.sub.3 for a special heating cycle, under a mixture of 70-96% by volume N.sub.2 and 4-30% by volume H.sub.2 gas; depositing a film of SiO.sub.2 over the particles; mechanically separating the particles; incorporating them into the above described ink formulation; depositing the ink on a substrate; and heating at 850-900° C. for less than 5 minutes and allowing the ink and substrate to cool to ambient in N.sub.2 atmosphere. Also a dielectric made by: heating particles of BaTiO.sub.3 for a special heating cycle, under a mixture of 70-96% by volume N.sub.2 and 4-30% by volume H.sub.2 gas; depositing a film of SiO.sub.2 over the particles; mechanically separating the particles; forming them into a layer; and heating at 850-900° C. for less than 5 minutes and allowing the layer to cool to ambient in N.sub.2 atmosphere.

Disclosed is a technique for suppressing a firing property and a dust generating property while improving bondability, in a thermal spray material for use in a thermite spraying process. The thermal spray material comprises a refractory material powder and a metal Si powder and capable of being sprayed onto a target surface using oxygen or oxygen-containing gas as a carrier gas and melt-adhered to the target surface based on heat generated by combustion of the metal Si powder, wherein the metal Si powder is contained in an amount of 10 to 25 mass % with respect to the entire thermal spray material, and wherein the metal Si powder has a median size of 10 μm or less, and contains a fraction having a particle size of 2 μm or less in an amount of 8 mass % or less with respect to the entire metal Si powder.

Thermal barrier materials are provided that possess low heat capacity and low thermal conductivity, while at the same time, high structural integrity and robustness. In some embodiments, the disclosed coating comprises metal-containing spheres that are sintered or glued together and/or embedded in a matrix. The coating has at least 60% void volume fraction and closed porosity. The coating thickness is from 50 microns to 500 microns, and the metal spheres have an average diameter that is from about 5% to about 30% of the coating thickness. In some embodiments, the metal spheres have an average diameter that is 4-10 times smaller than the coating thickness. Thermal barrier materials with these coatings can be beneficial in engine applications, for example.

A ceramic material which contains yttrium oxide as stabilizers and at least one of the materials erbium oxide or ytterbium oxide provides a phase having sintering stability for a ceramic material for ceramic layers and a ceramic layer system which maintain the mechanical and thermal properties for a long time even when used at high temperatures.