Provided herein are compositions, methods, and systems related to 3D printing a reactive vaterite cement composition, comprising feeding a composition comprising reactive vaterite cement through a 3D printing machine; printing a 3D printed reactive vaterite cement product; and curing the 3D printed reactive vaterite cement product by transforming reactive vaterite cement in the 3D printed reactive vaterite cement product to aragonite and/or calcite during and/or after the curing.

Methods use a catalytic composition built up from a ceramic material including a catalytic material and a first inorganic binder and a second inorganic binder and a catalytic structure made thereof. Preferably, the structure is made by a colloidal ceramic shaping technique. The structure is used for catalytic or ion exchange applications. The catalytic structures have excellent mechanical, physicochemical and catalytic properties.

A molding material in a powder-fixing lamination method includes an aggregate and a powdery precursor of a binder that binds the aggregate mutually. The aggregate is a casting sand, and the powdery precursor contains a hardening component and a hardening accelerating component. A molded product is manufactured using the molding material.

A composition, in particular for use as a printable and/or extrudable mass, comprises or consists of: 10-99.99 vol. % of a high-porosity material, whereby the high-porosity material is an aerogel and/or a xerogel, 0.001-5.0 vol. % of an organic binding promoter and, optionally, balance to 100 vol. % of further components.

Suggested is a solid formed with Si, Al, Ca, O and at least one of Na and K, characterized in that in the .sup.27Al-MAS-NMR spectra of the solid compared to the .sup.27Al-MAS-NMR spectrum of calcium aluminate, an additional signal is present which has a chemical shift which lies between that of the main peak of calcium aluminate and that peak of calcium aluminate which is closest to the main peak in the higher field. 2.

The present application relates to an additive component comprising a component A and a component B, wherein component A comprises at least one hardening retarder selected from glyoxylic acid, salts thereof, condensation or addition products of glyoxylic acid or salts thereof, and mixtures thereof, and component B comprises at least one hardening accelerator selected from calcium-silicate-hydrate, calcium formate, calcium nitrate, calcium chloride, calcium hydroxide, lithium carbonate, lithium sulfate, potassium sulfate, sodium sulfate, ground gypsum, and combinations thereof, in 3D printing of a construction material composition.

A porous ceramic structure intended to form the reinforcement of a ceramic matrix composite component, the structure having a connected porosity delimited by an internal surface which includes a plurality of first points, each first point being associated with a second point aligned with this first point along a normal to the internal surface taken at the first point, the structure being divisible into a plurality of unit volumes of a size less than or equal to 5 mm3 in each of which: a characteristic pore length, corresponding to the maximum of the distance separating each first point from its associated second point, is less than or equal to 0.5 mm; and a porosity ratio is greater than or equal to 50%.

A ceramic slurry for forming a ceramic article includes a binder, a first plurality of ceramic particles having a first morphology, a second plurality of ceramic particles having a second morphology that is different from the first morphology; and a photoinitiator. A method for using this slurry for fabricating ceramic articles is presented as well.

This invention relates to three-dimensional printing. This invention in particularly relates to a method of fabricating a three-dimensional object using a support edifice and also using a mold material with structural additives. The support edifice is fabricated in the same crafting material as the final three-dimensional object in the same manner as the printing of the final three-dimensional object (mold and crafting in a layer by layer manner). This method enables the support edifice to also transform during post processing in the same manner as the final three-dimensional object, thus supporting the object until finished. The system for fabricating the object comprises a dual printhead comprising a first dispensing nozzle for depositing the filament material in a flowable fluid form and a second dispensing nozzle for depositing the crafting medium, which is in a paste form. The printhead can also include a heating system or a drying apparatus. The three-dimensional imaging process for making objects, preferably metal objects or ceramic objects, on a layer-by-layer basis under the control of a data processing system is disclosed. The printing of the three-dimensional object such as heavy objects or an object having different parts having a very thin gap or space. It is important to use different processing steps and/or material to print such three-dimensional objects. The present invention provides a solution by printing a support edifice comprising a special structural additive for the mold, and further the support edifice can be printed simultaneously while printing the mold and crafting-paste material on a layer-by-layer basis. The mold material is mixed with the structural additive. The structural additive is useful for prohibiting either fusing of the object with the support edifice, or in alternative embodiments, the fusing of one part of an object with another part of an object.

The present invention relates to a paste comprising amorphous calcium carbonate (ACC) doped with divalent alkaline-earth metal ions, e.g., magnesium ions, or transition metal ions: a dry three-dimensional model made of such a paste, e.g., by 3D-printing process such as robocasting 3D-printing process; and a process for the preparation of said paste.