Patent classifications
C04B2235/605
Ferrite magnet
This ferrite magnet has a ferrite phase having a magnetoplumbite structure, and an orthoferrite phase, and is characterized in that the composition ratios of the total of each metal element A, R, Fe and Me is represented by expression (1) A.sub.1-xR.sub.x(Fe.sub.12-yMe.sub.y).sub.z, (in expression (1), A is at least one element selected from Sr, Ba, Ca and Pb; R is at least one element selected from the rare-earth elements (including Y) and Bi, and includes at least La, and Me is Co, or Co and Zn) and in that the content (m) of the orthoferrite phase is 0<m<28.0 in mol %. The invention makes it possible to achieve a ferrite magnet with increased Br.
Ferrite sintered magnet
The present invention provides a ferrite sintered magnet comprising (1) main phase grains containing a ferrite having a hexagonal structure, (2) two-grain boundaries formed between two of the main phase grains, and (3) multi-grain boundaries surrounded by three or more of the main phase grains. The above ferrite sintered magnet comprises Ca, R, Sr, Fe and Co, with R being at least one element selected from the group consisting of rare earth elements and Bi, and comprising at least La. The number Nm of the above main phase grains and the number Ng of the above multi-grain boundaries in the cross section including the direction of the easy magnetization axis of the above ferrite sintered magnet satisfy the formula (1A):
50%≤Nm/(Nm+Ng)≤65% (1A).
CALCINED FERRITE, AND SINTERED FERRITE MAGNET AND ITS PRODUCTION METHOD
A sintered ferrite magnet having a composition of metal elements of Ca, R, A, Fe and Co, which is represented by the general formula of Ca.sub.1−x−yR.sub.xA.sub.yFe.sub.2n−zCo.sub.z, wherein R is at least one of rare earth elements indispensably including La; A is Sr and/or Ba; x, y, z and n represent the atomic ratios of Ca, R, A, Fe and Co; 2n represents a molar ratio expressed by 2n=(Fe+Co)/(Ca+R+A); and x, y, z and n meet the conditions of 0.15≤x≤0.35, 0.05≤y≤0.40, (1−x−y)>y, 0<z≤0.18, and 7.5≤(2n−z)<11.0.
Calcined ferrite, and sintered ferrite magnet and its production method
A sintered ferrite magnet having a composition of metal elements of Ca, R, A, Fe and Co, which is represented by the general formula of Ca.sub.1-x-yR.sub.xA.sub.yFe.sub.2n-zCo.sub.z, wherein R is at least one of rare earth elements indispensably including La; A is Sr and/or Ba; x, y, z and n represent the atomic ratios of Ca, R, A, Fe and Co; 2n represents a molar ratio expressed by 2n=(Fe+Co)/(Ca+R+A); and x, y, z and n meet the conditions of 0.15≤x≤0.35, 0.05≤y≤0.40, (1-x-y)>y, 0<z≤0.18, and 7.5≤(2n-z)<11.0.
FERRITE SINTERED MAGNET AND METHOD FOR MANUFACTURING FERRITE SINTERED MAGNET
A ferrite magnet includes: a hexagonal ferrite main phase; and a second phase. The second phase is an oxide phase containing: an element A which is at least one selected from the group consisting of Ca, Sr, Ba, Bi, and rare earth elements; a transition metal element T including at least Fe; and an element G which is at least one selected from the group consisting of Si, Al, B, F, K, Na, Li, P, and S. When the total number of atoms of the element A, the transition metal element T, and the element G in the second phase is set to 100 at %, the element A occupies 30 to 80 at %, the element G occupies 15 to 40 at %, and the transition metal element T occupies less than 4 at %.
CALCINED FERRITE, AND SINTERED FERRITE MAGNET AND ITS PRODUCTION METHOD
A sintered ferrite magnet having a composition of metal elements of Ca, R, A, Fe and Co, which is represented by the general formula of Ca.sub.1-x-yR.sub.xA.sub.yFe.sub.2n-zCo.sub.z, wherein R is at least one of rare earth elements indispensably including La; A is Sr and/or Ba; x, y, z and n represent the atomic ratios of Ca, R, A, Fe and Co; 2n represents a molar ratio expressed by 2n=(Fe+Co)/(Ca+R+A); and x, y, z and n meet the conditions of 0.15≤x≤0.35, 0.05≤y≤0.40, (1-x-y)>y, 0<z≤0.18, and 7.5≤(2n-z)<11.0.
FERRITE SINTERED MAGNET
A ferrite sintered magnet including ferrite grains having a hexagonal crystal structure. The ferrite grains satisfy 0.56≤W≤0.68 where W is an average value of circularities of the ferrite grains in a cross section parallel to an axis of easy magnetization.
FERRITE SINTERED MAGNET
A ferrite sintered magnet including 0.010 mass % or more and 0.090 mass % or less of Mg in terms of MgO.
FERRITE SINTERED MAGNET
The present invention provides a ferrite sintered magnet comprising ferrite crystal grains having a hexagonal structure, wherein the ferrite sintered magnet comprises metallic elements at an atomic ratio represented by formula (1). In formula (1), R is at least one element selected from the group consisting of Bi and rare-earth elements, and R comprises at least La. In formula (1), w, x, z and m satisfy formulae (2) to (5). The above-mentioned ferrite sintered magnet further has a coefficient of variation of a size of the crystal grains in a section parallel to a c axis of less than 45%.
Ca.sub.1-w-xR.sub.wSr.sub.xFe.sub.zCo.sub.m(1)
0.360w=0.420(2)
0.110x0.173(3)
8.51z9.71(4)
0.208m0.269(5)
FERRITE SINTERED MAGNET, FERRITE PARTICLE, BONDED MAGNET AND ROTATING ELECTRIC MACHINE
This ferrite sintered magnet comprises ferrite phases having a magnetoplumbite type crystal structure. This magnet comprises an element R, an element M, Fe, Co, B, Mn and Cr, the element R is at least one element selected from rare earth elements including Y, the element M is at least one element selected from the group consisting of Ca, Sr and Ba, with Ca being an essential element, and when an atomic composition of metallic elements is represented by R.sub.1-xM.sub.xFe.sub.m-yCo.sub.y, x, y and m satisfy formulae:
0.2x0.8(1)
0.1y0.65(2)
3m<14(3).
Additionally, a content of B is 0.1 to 0.4% by mass in terms of B.sub.2O.sub.3, a content of Mn is 0.15 to 1.02% by mass in terms of MnO, and a content of Cr is 0.02 to 2.01% by mass in terms of Cr.sub.2O.sub.3.